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The Effect of Epoxidized Natural Rubber and Two Kinds of Organoclay upon Molecular Interaction, Structure and Mechanical Properties of (Styrene-Butadiene Rubber/Acrylonitrile-Butadiene Rubber/Organoclay) Nanocomposites

Alireza Monfared、Azam Jalali‐Arani、N. Mohammadi2013-12-27Journal of Macromolecular Science Part B

Epoxidized natural rubber (ENR50) and two different kinds of organoclay (C30B and C15A) were used in blends of styrene-butadiene rubber (SBR) and acrylonitrile butadiene rubber (NBR) and their effects upon interaction between phases, morphology, and mechanical properties of the blends were investigated. The compounds…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesTribology and Wear Analysis

Smart Nanorods for Highly Effective Cancer Theranostic Applications

Yinlong Yang、Xiujuan Zhang、Caitong Yu 等 7 位作者2013-12-27Advanced Healthcare Materials

Combination of chemotherapy and photothermal therapy is considered to be a promising strategy for the next generation of cancer treatments. However, it has been limited by difficulties in obtaining high drug payload chemo-photothermal agents, and thus complete destruction of tumor without recurrence has never been ach…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranostics

Nanostructured hybrid material based on highly mismatched III – V nanocrystals fully embedded in silicon

Mohamed Benyoucef、Tariq AlZoubi、Johann Peter Reithmaier 等 5 位作者2013-12-27physica status solidi (a)

InAs quantum dots were directly grown on (100) planar silicon surfaces and embedded in a defect‐free silicon matrix after a multi‐step silicon overgrowth and annealing process performed by molecular beam epitaxy. Detailed high‐resolution transmission electron microscope investigations allow to follow within several st…

Semiconductor Quantum Structures and DevicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Preparation of High Surface Area Ce/La/Cu and Ce/La/Ni Ternary Metal Oxides as Catalysts for the SO2 Reduction by CH4

Seyyed Ebrahim Mousavi、H. Ale Ebrahim、M. Edrissi2013-12-27Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry

In this work, CeO2–La2O3–CuO and CeO2–La2O3–NiO catalysts were prepared based on the Taguchi L16 experimental design method. The synthesized catalysts were characterized by Scanning electron microscopy, BET, XRD, N2 adsorption isotherm, and BJH pore size distributions. The maximum obtained surface areas for these cata…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesIndustrial Gas Emission Control

Cerium-Doped Yttrium Aluminum Garnet Hollow Shell Phosphors Synthesized via the Kirkendall Effect

Min Jeong Kim、Jong Hoon Park、Keel Yong Lee 等 9 位作者2013-12-27ACS Applied Materials & Interfaces

We report, for the first time, the synthesis of the Y3Al5O12:Ce(3+) hollow phosphor particles with a uniform size distribution via the Kirkendall effect, characterized by using a combination of in situ X-ray diffraction and high-resolution transmission electron microscopy analyses as a function of calcination temperat…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsMicrowave Dielectric Ceramics Synthesis

Calculated formation and reaction energies of 3d transition metal oxides using a hierarchy of exchange-correlation functionals

Jun Yan、Jens K. Nørskov2013-12-27Physical Review B

The formation and oxidation reaction energies of 16 transition metal oxides (TMOs) are benchmarked against experiments with an increasing complexity of the exchange-correlation (xc) functionals: PBE, PBE + $U$ with a single $U$ for each transition metal element, PBE0 (25% exact exchange included), EXX (100% exact exch…

Machine Learning in Materials ScienceHeusler alloys: electronic and magnetic propertiesElectronic and Structural Properties of Oxides

Phase diagram of a reentrant gel of patchy particles

Sándalo Roldán-Vargas、Frank Smallenburg、Walter Kob 等 4 位作者2013-12-27The Journal of Chemical Physics

We study the phase diagram of a binary mixture of patchy particles which has been designed to form a reversible gel. For this we perform Monte Carlo and molecular dynamics simulations to investigate the thermodynamics of such a system and compare our numerical results with predictions based on the analytical parameter…

Hydrogels: synthesis, properties, applicationsBlock Copolymer Self-AssemblyPickering emulsions and particle stabilization

Effect of Annealing on Magnetostrictive Properties of Fe–Co Alloy Thin Films

T. Nakajima、Teruaki Takeuchi、I. Yuito 等 9 位作者2013-12-27MATERIALS TRANSACTIONS

The effect of the annealing temperature on the magnetostrictive properties of Fe–Co alloy thin films on quartz glass was systematically investigated. The saturation magnetostriction was 56 ppm for the Fe32Co68-sputtered thin film quenched from 673 K, and it increased to 159 ppm with increasing annealing temperature up…

Magnetic properties of thin filmsMetallic Glasses and Amorphous AlloysMagnetic Properties and Applications

Stabilization of metastable tetragonal phase in a rhombohedral magnetoelectric multiferroic BiFeO3–PbTiO3

Ashoka Siddaramanna、V. Kothai、Chandan Srivastava 等 4 位作者2013-12-27Journal of Physics D Applied Physics

The phase formation behaviour of the magnetoelectric multiferroic 0.8BiFeO 3 –0.2PbTiO 3 was studied as a function of heat treatment at different temperatures of a sol–gel derived powder. While under ordinary synthesis conditions this composition exhibits antiferromagnetic ordering and a rhombohedral structure; the so…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsUnderwater Acoustics Research

In situ Surface Tailoring with Zwitterionic Carboxybetaine Moieties on Self-Assembled Thin Film for Antifouling Biointerfaces

Chun‐Jen Huang、Ying Chang2013-12-27Materials

A novel biointerface bearing zwitterionic carboxybetaine moieties was developed for effective resistance to nonspecific adsorption of proteins and blood cells. Self-assembled thin films (SAFs) of (N,N-dimethylaminopropyl) trimethoxysilane were formed as mattress layers by either vapor or solution deposition. Subsequen…

Advanced Sensor and Energy Harvesting MaterialsPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Structure–Property Relationships for a Series of Poly(ester amide)s Containing Amino Acids

Abdolrasoul Soleimani、S. Drappel、Rina Carlini 等 5 位作者2013-12-27Industrial & Engineering Chemistry Research

Poly(ester amide)s (PEAs) composed of variable diols, dicarboxylic acids, and α-amino acids were synthesized and characterized to elucidate structure–property relationships. The PEAs were synthesized using both solution and interfacial approaches to obtain varying molecular weights (MWs) and polydispersities. Studies…

biodegradable polymer synthesis and propertiesSynthesis and properties of polymersBiopolymer Synthesis and Applications

Activation of a Carbon Support Through a Two‐Step Wet Oxidation and Highly Active Ruthenium–Activated Carbon Catalysts for the Hydrogenation of Benzene

Ying Li、Guojun Lan、Guoquan Feng 等 7 位作者2013-12-27ChemCatChem

Abstract A two‐step liquid oxidation approach was developed for the activation of carbon materials. Following nitric acid treatment and subsequent liquid oxidation by a mild oxidant such as H2O2, the number of surface acidic functional groups was increased without destroying the physical structures of the carbon mater…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesNanomaterials for catalytic reactions

Structural Determination and Imaging of Charge Ordering and Oxygen Vacancies of the Multifunctional Oxides REBaMn2O6‐χ (RE = Gd, Tb)

David Ávila‐Brande、Graham King、Esteban Urones‐Garrote 等 6 位作者2013-12-27Advanced Functional Materials

Charge ordering and oxygen vacancy ordering are revealed in REBaMn2O6‐δ (RE = Gd, Tb) oxides with perovskite‐related structures. Electron diffraction and transmission electron microscopy results indicate a modulation of the crystal structure. The average oxidation state of Mn and the oxygen stoichiometry are determine…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Effects of Poly(vinyl butyral) as a Macromolecular Nucleating Agent on the Nonisothermal Crystallization and Mechanical Properties of Biodegradable Poly(butylene succinate)

Biao Yang、Hongkai Ni、Jijun Huang 等 4 位作者2013-12-27Macromolecules

To improve the crystallization and mechanical properties of poly(butylene succinate) (PBS), a series of poly(vinyl butyral) (PVBs) with various degrees of polymerization, have been synthesized as macromolecular nucleating agents. Nonisothermal crystallization kinetics of PBS nucleated by the PVBs has been examined via…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing Technologies

Argon plasma treatment on metal substrates and effects on diamond‐like carbon (DLC) coating properties

Abdul Wasy、G. Balakrishnan、Seunghun Lee 等 7 位作者2013-12-27Crystal Research and Technology

The diamond like carbon coatings (DLC) of 400 nm thickness was deposited by filtered cathodic vacuum arc system. The argon plasma etched and non‐etched tungsten carbide‐cobalt (WC‐Co) and stainless steel (SUS) were used as substrates. The chromium was deposited as an interlayer for diamond like carbon coatings on the…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchAdvanced materials and composites

Stimuli‐Responsive Nanocomposite: Potential Injectable Embolization Agent

Huanfu Zhou、Lin Huang、Hao‐Jan Sun 等 6 位作者2013-12-27Macromolecular Rapid Communications

Liver cancer remains a significant medical problem and one promising therapeutic approach is to embolize the tumor. One emerging embolization strategy is to use thermoresponsive materials that can be injected but gel at the tumor site. It is now reported on thermoresponsive nanocomposites generated by grafting poly(N-…

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical Applications

Bimodal/Broad Polyethylene Prepared in a Disentangled State

Wei Li、Chao Guan、Jie Xu 等 7 位作者2013-12-27Industrial & Engineering Chemistry Research

Disentangled broad/bimodal polyethylene with an inverted distribution of short chain branches (SCBs) was synthesized with a supported hybrid catalyst. Poly[styrene- co -(acrylic acid)]- (PSA-) coated SiO 2 particles were used to support the hybrid catalysts. The PSA was coated on SiO 2 -supported VCl 3 catalyst. Then,…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesSynthetic Organic Chemistry Methods

The Non‐Ergodic Nature of Internal Conversion

Theis I. Sølling、Thomas S. Kuhlman、Anne B. Stephansen 等 5 位作者2013-12-27ChemPhysChem

The absorption of light by molecules can induce ultrafast dynamics and coupling of electronic and nuclear vibrational motion. The ultrafast nature in many cases rests on the importance of several potential energy surfaces in guiding the nuclear motion-a concept of central importance in many aspects of chemical reactio…

Photochemistry and Electron Transfer StudiesPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Synthesis of GeSe4glass by mechanical alloying and sintering

Elena Petracovschi、Mathieu Hubert、Jean‐Luc Adam 等 5 位作者2013-12-27physica status solidi (b)

The possibility to synthesize GeSe4 glass by mechanical alloying followed by sintering has been demonstrated. X-ray diffraction (XRD) and differential scanning calorimetry (DSC) analysis have been performed on the powder as a function of milling duration in order to follow the amorphization process of raw metallic ger…

Glass properties and applicationsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Influence of Screw Profile Employed During Melt Mixing on the Micro‐scale Dispersion of MWCNT s in Poly(propylene)

Beatriz Mayoral、Graham E. Garrett、Tony McNally2013-12-27Macromolecular Materials and Engineering

The relationship between MWCNT dispersion and agglomerate size with the screw profile employed during mixing of MWCNTs and a PP in a twin‐screw extruder is investigated. Five screw configurations are designed based on an initial concept of forward conveying and kneading block elements and varying a number of other ele…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties