Materials Literature
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PURPOSE OF REVIEW: Although the production and use of engineered nanomaterials (ENMs) is rapidly increasing, we lack sufficient knowledge regarding their capacity to induce and/or promote allergic disease. As novel ENMs are being developed and used for biomedical applications, such as drug delivery, it will be critica…
The ring-opening polymerization (ROP) of trimethylene carbonate (TMC) using imidodiphosphoric acid (IDPA) as the organocatalyst and benzyl alcohol (BnOH) as the initiator has been investigated. The polymerization proceeded without decarboxylation to afford poly(trimethylene carbonate) (PTMiC) with controlled molecular…
Silicon is a critical element for diatom growth; however our understanding of the molecular mechanisms involved in intracellular silicon responses are limited. In this study, an iTRAQ-LC-MS/MS quantitative proteomic approach was coupled with an established synchrony technique to reveal the global metabolic silicon-res…
Lung cancer ranks among the most common malignancies, and is the leading cause of cancer-related mortality worldwide. Chemotherapy for lung cancer can be made more specific to tumor cells, and less toxic to normal tissues, through the use of ligand-mediated drug delivery systems. In this study, we investigated the tar…
Carbon nanoparticles with large surface areas were produced by the reduction of carbon disulfide with metallic lithium at 500 °C. The carbon nanoparticles account for about 80% of the carbon product. The carbon nanoparticles were characterized by X-ray powder diffraction, field emission scanning electron microscopy, t…
High Resolution Image Download MS PowerPoint Slide Planar biomimetic membranes based on amphiphilic block copolymers represent artificial systems designed to mimic natural membranes but with improved stability and robustness to support applications in domains such as medicine and technology. Here we present methods to…
Engineering polymer systems for improved drug delivery , Engineering polymer systems for improved drug delivery , کتابخانه مرکزی دانشگاه علوم پزشکی تهران
This study provides a facile approach to improving the dispersion of graphene in polymer matrix through a synergetic effect between two kinds of two-dimensional (2D) nanofillers. The nanohybrid based on graphene and boehmite (AlOOH) was synthesized by decorating AlOOH nanoplatelets on the graphene nanosheets. The grap…
The aim of this study was to investigate physical and mechanical properties of graphene oxide (GO)/polyethersulfone (PES) nanocomposite films. The films were produced by solution casting method. The mechanical properties of composite films were evaluated by tensile test. A significant enhancement in the mechanical pro…
In this study, atmospheric pressure non-thermal plasma treatment of electrospun poly(L-lactic acid) scaffolds is used to improve scaffold hydrophilicity and to introduce carboxyl groups on scaffold surface. Thermo-mechanical properties, morphology, hydrophilicity, and water uptake of the plasma-treated scaffolds are s…
We report on the observation of the hysteretic transition of a commensurate charge modulation in ${\mathrm{IrTe}}_{2}$ from transport and scanning tunneling microscopy (STM) studies. Below the transition (${T}_{C}\ensuremath{\approx}275\text{ }\text{ }\mathrm{K}$ on cooling), a $q=1/5$ charge modulation was observed,…
Thermoelectric effects in zigzag graphene nanoribbons with parallel alignment of the edge spin polarizations are investigated theoretically. Spin and charge thermopower, electrical and heat conductance, and charge and spin thermoelectric efficiency are calculated numerically for pristine nanoribbons as well as for nan…
The first photoactivated doped quantum dot vector for metal-ion release has been developed. A facile method for doping copper(I) cations within ZnS quantum dot shells was achieved through the use of metal-dithiocarbamates, with Cu(+) ions elucidated by X-ray photoelectron spectroscopy. Photoexcitation of the quantum d…
The garnet structure is a promising nuclear waste form because it can accommodate various actinide elements. Yttrium iron garnet, Y 3 Fe 5 O 12 (YIG), is a model composition for such substitutions. Since cerium (Ce) can be considered an analogue of actinide elements such as thorium (Th), plutonium (Pu), and uranium (U…
We review and discuss methods for including the role of point defects in calculations of the free energy, composition and phase stability of elements and compounds. Our principle aim is to explain and to reconcile, with examples, the perspectives on this problem that are often strikingly different between exponents of…
Polycrystalline tungsten-substituted CaMn1−xWxO3−δ (0.00 ≤ x ≤ 0.05) powders were synthesized from a polymeric precursor, pressed and sintered to high density. The impact of tungsten substitution on the crystal structure, thermal stability, phase transition, electronic and thermal transport properties is assessed. Tun…
Abstract We show that higher alcohols can be produced with high selectivity from syngas over three‐dimensionally ordered macroporous Cu–Fe catalyst. The catalyst was developed by using a glyoxylate route colloidal crystal template method. The high intrinsic activity was ascribed to three factors. First, the unique ord…
The influence of trivalent dopants (rare-earths, RE) on the structure, composition and electrochemical reactivity of UO 2 has been investigated using scanning electron microscopy (SEM/XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy and cyclic voltammetry (CV). This was achieved by comparing the behavi…
The NIR and IR spectroscopic properties of the cyanide-bridged complex, trans-[Ru(dmap)4 {(μ-CN)Ru(py)4 Cl}2 ](3+) (py=pyridine, dmap=4-dimethylaminopyridine) provide strong evidence that this trimetallic ion behaves as a Class III mixed-valence species, the first example reported of a cyanide-bridged system. This has…
The polymer dynamics of homogeneous C 60 –polystyrene mixtures in the molten state are studied via molecular simulations using two interconnected levels of representation for polystyrene nanocomposites: (a) A coarse-grained representation, in which each polystyrene repeat unit is mapped into a single “superatom” and e…