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The influence of linking group in exterior point on mesogenic properties of the basket moulded molecules: calix[4]arene

Pinkesh G. Sutariya、Alok Pandya、V. A. Rana 等 4 位作者2012-12-13Liquid Crystals

Novel basket-shaped molecules having calix[4]arene as central rigid core possessing azomaterial in outer space unit in the lengthening arm were synthesised and characterised by elemental analysis and different spectroscopic methods such as Fourier Transform Infrared (FT-IR), electron spin ionization (ESI)-MASS, 1H nuc…

Liquid Crystal Research AdvancementsMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Directed/localized growth of multiwalled carbon nanotubes catalyzed by cobalt nanoclusters

Alexander B. Smetana、Shanèe Pacley、John Boeckl 等 5 位作者2012-12-13Journal of Materials Chemistry C

Tip based lithography was used to print arbitrary patterns of cobalt oxide nanoclusters from single features to large repeatable arrays over square millimeter areas. Cobalt ions were mixed with a P2VP-PEO block-copolymer and were delivered in sub-micron sized droplets to a surface. These droplets were heat treated at…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsNanotechnology research and applications

Measurement of stress–strain behaviour of human hair fibres using optical techniques

J. Lee、Hyock‐Ju Kwon2012-12-13International Journal of Cosmetic Science

Many studies have presented stress-strain relationship of human hair, but most of them have been based on an engineering stress-strain curve, which is not a true representation of stress-strain behaviour. In this study, a more accurate 'true' stress-strain curve of human hair was determined by applying optical techniq…

Optical measurement and interference techniquesDyeing and Modifying Textile FibersTextile materials and evaluations

Nanostructure Transitions and Their Relation to Mechanical Properties in Polyethylene/Polyamide 6 Microfibrillar Composites as Revealed by SAXS/Straining Studies

Nadya Dencheva、Zlatan Denchev、Norbert Stribeck 等 7 位作者2012-12-13Macromolecular Materials and Engineering

Abstract Microfibrillar composites (MFC) with a matrix of high‐density polyethylene (HDPE) and reinforcements of polyamide 6 (PA6) are tensile tested while collecting 2D small‐angle X‐ray scattering patterns. The scattering of the isotropic matrix is separated from that of the oriented fibrils and the chord distributi…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Doping effects of Co and Cu on superconductivity and magnetism in Fe 1+ y Te 0.6 Se 0.4 single crystals

Zhitao Zhang、Zhaorong Yang、Li Li 等 7 位作者2012-12-13Journal of Physics Condensed Matter

We report on the investigation of Co and Cu substitution effects on superconductivity and magnetism in Fe(1+y)Te(0.6)Se(0.4) single crystals. The parent Fe(1.01)Te(0.59)Se(0.41) shows a nodeless bulk superconductivity as revealed in heat capacity measurement, which is gradually suppressed by either Co or Cu doping. It…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Electrochemical Studies of Catalyst Free Carbon Nanotube Electrodes

Tingting Wang、Hemanthi D. Manamperi、Wei Yue 等 7 位作者2012-12-13Electroanalysis

Abstract A novel catalyst free carbon nanotube (CNT) electrode was fabricated by a Carbo Thermo Carbide Conversion (CTCC) method. The morphology and nanostructure of the CNT electrodes were characterized by transmission electron microscopy (TEM) and Raman spectroscopy. Electrochemical characterization using potassium…

Carbon Nanotubes in CompositesSupercapacitor Materials and FabricationConducting polymers and applications

Synthesis of Maleimide‐Functionalyzed HPMA‐Copolymers and in vitro Characterization of the aRAGE‐ and Human Immunoglobulin (huIgG)–Polymer Conjugates

Kristof Tappertzhofen、Verena V. Metz、Mario Hubo 等 7 位作者2012-12-13Macromolecular Bioscience

Herein the synthesis of antibody-polymer conjugates, with a quite narrow dispersity based on the polymer HPMA, are reported. These conjugates are synthesized by coupling antibodies to maleimide-functionalized poly(N-(2-hydroxypropyl)-methacrylamide) (poly-HPMA) copolymers derived through reversible addition-fragmentat…

RNA Interference and Gene DeliveryClick Chemistry and ApplicationsDendrimers and Hyperbranched Polymers

Study of Rigid Cross-Linked PVC Foams with Heat Resistance

Aihua Shi、Guangcheng Zhang、Chenhui Zhao2012-12-13Molecules

Three heat resistant cross-linked PVC foam plastics were prepared and their performances were compared with universal cross-linked PVC structural foam. The results show that these three heat resistant foams have higher glass transition temperatures (close to 100 °C) than universal structural foam (83.2 °C). Compared w…

Polymer composites and self-healingPolymer Foaming and CompositesPolymer Science and PVC

Catastrophic Inflammatory Death of Monocytes and Macrophages by Overtaking of A Critical Dose of Endocytosed Synthetic Amorphous Silica Nanoparticles/Serum Protein Complexes

Chiara Fedeli、Francesco Selvestrel、Regina Tavano 等 6 位作者2012-12-13Nanomedicine

AIMS: We tested whether phagocytic monocytes/macrophages are more susceptible than nonphagocytes to nanoparticle (NP) toxicity. MATERIALS & METHODS: We compared in vitro cell death and proinflammatory cytokine production in human monocytes, macrophages, lymphocytes and HeLa cells due to synthetic amorphous silica (SiO…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsImmunotherapy and Immune Responses

Accelerated maturation of Tk‐subtilisin by a Leu→Promutation at the C‐terminus of the propeptide, which reduces the binding of the propeptide to Tk‐subtilisin

Ryo Uehara、Yasunori Ueda、Dong‐Ju You 等 5 位作者2012-12-13FEBS Journal

T k‐subtilisin, a subtilisin homologue (Gly70‐Gly398) from T hermococcus kodakarensis , is matured from its precursor, P ro‐ T k‐subtilisin [ T k‐subtilisin in a pro form ( G ly1‐ G ly398)], by autoprocessing and degradation of propeptide [ T k‐propeptide, a propeptide of T k‐subtilisin ( G ly1‐ L eu69)]. The scissile…

Bacterial Genetics and BiotechnologyRNA and protein synthesis mechanismsEnzyme Structure and Function

Influence of point defects on grain boundary mobility in bcc tungsten

Valery Borovikov、Xian-Zhu Tang、Danny Pérez 等 6 位作者2012-12-13Journal of Physics Condensed Matter

Atomistic computer simulations were performed to study the influence of radiation-induced damage on grain boundary (GB) sliding processes in bcc tungsten (W), the divertor material in the ITER tokamak and the leading candidate for the first wall material in future fusion reactors. In particular, we calculated the aver…

Microstructure and mechanical propertiesFusion materials and technologiesNuclear Materials and Properties

Comparison between ZnO films grown by plasma-assisted atomic layer deposition using H2O plasma and O2 plasma as oxidant

Yumi Kawamura、Nozomu Hattori、Naomasa Miyatake 等 4 位作者2012-12-13Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Zinc oxide (ZnO) thin films have attracted significant attention for application in thin film transistors (TFTs) due to their specific characteristics, such as high mobility and transparency. In this paper, the authors fabricated TFTs with ZnO thin films as channel layers deposited by plasma-assisted atomic layer depo…

ZnO doping and propertiesThin-Film Transistor TechnologiesGa2O3 and related materials

XRD and EDXRF Analysis of Anatase Nano-TiO<sub>2</sub> Synthesized from Mineral Precursors

E.M. Mahdi、Mohd Hamdi Abdul Shukor、M. S. Meor Yusoff 等 4 位作者2012-12-13Advanced materials research

This work details the characterization of anatase nanoTiO 2 particles synthesized from Malaysian mineral precursors using the XRD and EDXRF. The properties that were analyzed were its crystallite sizes, relative crystallinity, phases, and chemical composition. It was determined that the crystallite size was quite smal…

TiO2 Photocatalysis and Solar CellsElectronic and Structural Properties of OxidesX-ray Diffraction in Crystallography

Characterization of the Hydrochlorothiazide: β-Cyclodextrin Inclusion Complex. Experimental and Theoretical Methods

Renée Onnainty、Esteban M. Schenfeld、Mario A. Quevedo 等 6 位作者2012-12-13The Journal of Physical Chemistry B

Hydrochlorothiazide (HCT) is one of the most commonly prescribed antihypertensive drugs. In an attempt to gain an insight into the physicochemical and molecular aspects controlling the complex architecture of native β-cyclodextrin (β-CD) with HCT, we performed multiple-temperature-pH isothermal titration calorimetric…

Drug Solubulity and Delivery SystemsCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Enhanced emission of Mn^2+ via Ce^3+→Mn^2+ energy transfer in α-Sr_2P_2O_7

Dejian Hou、Chunmeng Liu、Xiaojun Kuang 等 4 位作者2012-12-13Optics Express

Mn(2+) doped and Ce(3+)-Mn(2+) co-doped α-Sr(2)P(2)O(7) phosphors were prepared by a traditional high-temperature solid-state reaction route. The UV-vis excitation and emission spectra for all samples were investigated. Luminescence of Mn(2+) is assigned to from two different sites, which is similar to that of Ce(3+).…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsRadiation Detection and Scintillator Technologies

Reversible actuating and writing behaviours of a head-to-side connected main-chain photochromic liquid crystalline polymer

Dae‐Yoon Kim、Sang‐Ah Lee、Hyong Jong Choi 等 6 位作者2012-12-13Journal of Materials Chemistry C

A photochromic liquid crystalline (LC) polymer {4-butoxy-2′-(4-hex-5-enyloxy)-4′-(4-hex-5-enyl-oxybenzyloxy)azobenzene, abbreviated as PLCP} was newly synthesized via the acrylic diene metathesis polymerization (H. J. Choi, et al., J. Mater. Chem., 2009, 19, 7124). Utilizing the combined techniques of differential sca…

Liquid Crystal Research AdvancementsPhotochromic and Fluorescence ChemistryAdvanced Materials and Mechanics

A Static Contact Angle Algorithm for Silicone Rubber Aging Experiments

Zhiniu Xu2012-12-13IEEE Transactions on Power Delivery

To improve the accuracy of the static contact angle measurement in the silicone rubber aging experiments, a high accurate contact angle algorithm in combination with the circle fitting algorithm and ellipse fitting algorithm is proposed. The influence of the water drop volume and noise on the calculation accuracies of…

High voltage insulation and dielectric phenomenaOptical measurement and interference techniquesImage and Object Detection Techniques

Alcohol and Thiol Adsorption on (Oxy)hydroxide and Carbon Surfaces: Molecular Dynamics Simulation and Desorption Experiments

Jeffery A. Greathouse、David Hart、Margaret Ochs2012-12-13The Journal of Physical Chemistry C

Classical molecular dynamics simulations were used to investigate the interaction of methyl, ethyl, and n-propyl alcohols and thiols with the hydroxylated basal surfaces of aluminum hydroxide and iron oxyhydroxide, as well as a model graphite surface. Comparisons were made to concurrently run desorption experiments in…

Mesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and ApplicationsCovalent Organic Framework Applications

3,5-Bis(acetaldehyde) substituted BODIPY

Mykola P. Shandura、Viktor P. Yakubovskyi、Yuriy P. Kovtun2012-12-13Organic & Biomolecular Chemistry

Two versions of a facile and efficient synthetic approach to 3,5-bis(acetaldehyde) substituted BODIPY have been developed and this compound has been used to obtain, in high yields, a variety of 3,5-divinyl BODIPY derivatives (vinylacetates, enamines, vinyl chlorides, and some multiple-functionalized products). As show…

Molecular Sensors and Ion DetectionNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

3,14‐Bis(p‐nitrophenyl)‐17,17‐dipentyltetrabenzo[a,c,g,i]‐fluorene: A New Fluorophore Displaying Both Remarkable Solvatochromism and Crystalline‐Induced Emission

Y. Ueda、Yusuke Tanigawa、Chitoshi Kitamura 等 9 位作者2012-12-13Chemistry - An Asian Journal

A series of 17,17-dialkyl-3,14-diaryltetrabenzofluorenes were efficiently prepared by using Suzuki-Miyaura cross-coupling reactions of the corresponding 3,14-dibromo derivatives. Studies of the unique fluorescence properties of these compounds showed that they display intense blue to yellow fluorescence with high quan…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials