Materials Literature
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We reported that per-6-folic acid (FA)-appended β-cyclodextrin (β-CyD) possessing two caproic acids between FA and a β-CyD molecule as a spacer (Fol-c2-β-CyD) could be useful as a promising antitumor drug carrier. However, the effects of the cavity size and the spacer length on the carrier ability are not still known.…
A supercritical carbon dioxide (SCC) process of dispersion of multi-walled carbon nanotubes (MWCNTs) into epoxy resin has been developed to achieve MWCNT/epoxy composites (CECs) with improved mechanical, thermal, and electrical properties. The synthesis of CECs has been executed at a MWCNT (phr) concentration ranging…
Two novel bismaleimide monomers containing 1,3,4-oxadiazole and asymmetric structure, i.e., 2-[4-(4-maleimidophenoxy)phenyl]-5-(4-maleimidophenyl)-1,3,4-oxadiazole (p-Mioxd) and 2-[3-(4-maleimidophenoxy)phenyl]-5-(4-maleimidophenyl)-1,3,4-oxadiazole (m-Mioxd), were designed and synthesized. The chemical structures of…
It is well known that the Sb–Te binary system has a large number of incommensurately or commensurately modulated structures between Sb and Sb2Te3 compounds. These structures, which are long‐period trigonal stacking structures, possess their own modulation period γ, according to their composition in the thermal equilib…
Together we shine: Fluorescence color change of 4-[bis(4-methylphenyl)amino]benzaldehyde (BMABA) could be induced by vigorous stirring and heating of the suspension. This is attributed to a morphological change of the particles from an amorphous state to a crystalline state; therefore, BMABA is identified as a new agg…
Surface segregation of Pt is investigated in nanoporous metals formed by dealloying of Ag-Au-Pt alloys. By exposing freshly-dealloyed nanostructures to surprisingly low temperatures in the presence of laboratory air, the Pt segregates to the surface of the ligaments thanks to its preferential interaction with oxygen;…
Fast phase transitions under lack of local thermalization between successive elementary steps of the physical process are treated analytically. Non-Markovian master equations are derived for fast processes, which do not have enough time to reach energy or momentum thermalization during rapid phase change or freezing o…
The material design of type-VIII clathrate Si46 is presented based on first principles. The structural, electronic, elastic, vibrational, and thermodynamic properties of this hypothetical material are presented. Our results predict that type-VIII clathrate Si46 is an indirect semiconductor with a bandgap of 1.24 eV. T…
Understanding the long-term effects and possible toxicity of nanoceria, a widely utilized commercial metal oxide, is of particular importance as it is poised for development as a therapeutic agent based on its autocatalytic redox behavior. We show here evidence of acute and subacute adverse hepatic responses, after a…
The molecular orbital calculations have been carried out to investigate the structure and stability of (E) / (Z) isomers of some azobenzene derivatives containing maleimide groups. A special attention has been devoted to the compound (E)-1, (E)-1-(4-(phenyldiazenyl)phenyl)-1H-pyrrole-2,5-dione, for which the available…
Solving pharmaceutical crystal structures from powder diffraction data is discussed in terms of the methodologies that have been applied and the complexity of the structures that have been solved. The principles underlying these methodologies are summarized and representative examples of polymorph, solvate, salt and c…
Die richtige Wellenlänge muss es sein: Photolabile Moleküleinheiten, die durch Licht unterschiedlicher Wellenlänge gespalten werden, können für die unabhängige Freisetzung verschiedener Farbstoffe/Proteine aus einem einzigen beladenen Speicherhydrogel genutzt werden (siehe Schema). Dadurch konnten die Proteine nachein…
CK2 is a protein kinase essential for cell viability whose activity is altered in several cancers. Its mechanisms of regulation differ from those common to other eukaryotic protein kinases and are not entirely established yet. Here we present crystal structures of the monomeric form of the α2β2 holoenzyme that allow r…
In this study, a series of thiol-ene networks having glass transition temperatures ranging from -30 to 60 °C were synthesized utilizing several multifunctional thiols and two trifunctional alkenes. Thermomechanical properties were determined using dynamic mechanical analysis, and impact properties were determined usin…
Periodically nanopatterned Si structures have been prepared by using a nanosphere lithography technique. The formed nanopatterned structures exhibit good anti‐reflection and enhanced optical absorption characteristics. The mean surface reflectance weighted by AM1.5 solar spectrum (300–1200 nm) is as low as 5%. By depo…
In this study, the jute/polypropylene nonwoven reinforced composites were prepared using film stacking method. The surface of jute fibers was modified using alkali treatment. These alkali treated jute fiber nonwoven composites were analyzed for their tensile and flexural properties. Increasing the amount of jute fiber…
Using molecular mechanics simulations, we investigated the true pre-stress/pre-strain state of graphene in free standing indentation and the effect of the pre-strain (ε0) on the free standing indentation response of graphene is also considered. We found that there is essentially no effective pre-tension in graphene du…
ABSTRACT A series of highly thermostable epoxy foams with diglycidyl ether of bisphenol‐A and bisphenol‐S epoxy resin (DGEBA/DGEBS), 4,4′‐diaminodiphenyl sulfone (DDS) as curing agent have been successfully prepared through a two‐step process. Dynamic and steady shear rheological measurements of the DGEBA/DGEBS/DDS re…
Researches on the armor systems composed of composite materials with ceramic frontal face and polymer-based back-support are continuously developing further. This study, which mainly covers the impact behavior of ceramic composite armors, is a two-stage research. The first stage involves the investigation of component…
The catalytic properties of ruthenium (Ru) are fairly well known. Nevertheless its shape-controlled synthesis (especially as compared to other noble metals) is still elusive. In this review, we present recent advances in the synthesis of Ru nanomaterials, in particular, spherical nanoparticles, one dimensional nanostr…