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Synthesis and characterization of silicones containing cyanopropyl groups and their use in dielectric elastomer actuators

Carmen Racleş、Maria Cazacu、Beatrice Fischer 等 4 位作者2013-09-19Smart Materials and Structures

Polydimethylsiloxanes (PDMS) have recently been used as dielectric elastomer materials in electromechanical actuators. When they are soft enough, electric fields can change their shape. However, due to their low dielectric permittivity, large electric fields are required to induce a change. The approach presented here…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsDielectric materials and actuators

Hybrid Bimetallic Metal–Organic Frameworks: Modulation of the Framework Stability and Ultralarge CO2 Uptake Capacity

Xiaokai Song、Minhak Oh、Myoung Soo Lah2013-09-19Inorganic Chemistry

A series of isostructural hybrid bimetallic metal-organic frameworks (MOFs), Ni(x)M(1-x)-ITHDs [M = Zn(II), Co(II)], have been prepared via a conventional solvothermal reaction in the presence of varying mole ratios of Ni(II)/Zn(II) or Ni(II)/Co(II) mixed metal ions. While a critical amount of the doped Ni(II) ion (mo…

Metal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Conducting Polymer Electrodes for Electroencephalography

P. Leleux、J. Badier、Jonathan Rivnay 等 7 位作者2013-09-19Advanced Healthcare Materials

Conducting polymer electrodes are developed on a flexible substrate for electroencephalography applications. These electrodes yield higher quality recordings than dry electrodes made from metal. Their performance is equivalent to commercial gel-assisted electrodes, paving the way for non-invasive, long-term monitoring…

Electrochemical sensors and biosensorsConducting polymers and applicationsNeuroscience and Neural Engineering

Electrolyte‐Gated Organic Field‐Effect Transistor for Selective Reversible Ion Detection

Kerstin Schmoltner、Johannes Kofler、Andreas Klug 等 4 位作者2013-09-19Advanced Materials

An ion-sensitive electrolyte-gated organic field-effect transistor for selective and reversible detection of sodium (Na(+) ) down to 10(-6) M is presented. The inherent low voltage - high current operation of these transistors in combination with a state-of-the-art ion-selective membrane proves to be a novel, versatil…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Welding and weldability of candidate ferritic alloys for future advanced ultrasupercritical fossil power plants

S. A. David、John Siefert、Zhili Feng2013-09-19Science and Technology of Welding & Joining

Fossil fuels continue to be the primary source of energy in the world. The worldwide demand for clean and affordable energy will continue to grow, and a strong emphasis has been placed on increasing the efficiency and reducing the carbon footprint of new and existing fossil fired power plants. Throughout Asia, Europe…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsHigh Temperature Alloys and Creep

Dielectric elastomer actuators used for pneumatic valve technology

Metin Giousouf、Gábor Kovács2013-09-19Smart Materials and Structures

Dielectric elastomer actuators have been investigated for applications in the field of pneumatic automation technology.We have developed different valve designs with stacked dielectric elastomer actuators and with integrated high voltage converters.The actuators were made using VHB-4910 material and a stacker machine…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsDielectric materials and actuators

Circular Magnetoplasmonic Modes in Gold Nanoparticles

Francesco Pineider、Giulio Campo、Valentina Bonanni 等 8 位作者2013-09-19Nano Letters

The quest for efficient ways of modulating localized surface plasmon resonance is one of the frontiers in current research in plasmonics; the use of a magnetic field as a source of modulation is among the most promising candidates for active plasmonics. Here we report the observation of magnetoplasmonic modes on collo…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchCharacterization and Applications of Magnetic Nanoparticles

Novel chitosan‐TiO2 nanohybrid: Preparation, characterization, antibacterial, and photocatalytic properties

Yuvaraj Haldorai、Jae‐Jin Shim2013-09-19Polymer Composites

In this report, chitosan (CS) encapsulated titanium dioxide (TiO2) nanohybrid was prepared by chemical precipitation method. Fourier transform infrared spectroscopy (FT‐IR) and X‐ray diffraction (XRD) confirmed the formation of nanohybrid. Transmission electron microscopy (TEM) analysis showed the immobilization of Ti…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesNanoparticles: synthesis and applications

Sulfur/Carbon Nanotube Composite Film as a Flexible Cathode for Lithium–Sulfur Batteries

Kangke Jin、Xufeng Zhou、Liangzhong Zhang 等 6 位作者2013-09-19The Journal of Physical Chemistry C

A flexible composite film composed of carbon nanotubes (CNTs) and sulfur as the cathode for lithium–sulfur (Li–S) batteries is prepared by coating an ultrathin sulfur nanolayer on a preprepared CNT film through a simple two-step heating process. The sulfur–CNT composite film with an areal density of ∼5 mg cm –2 has a…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesElectromagnetic wave absorption materials

Self-sensing dielectric elastomer actuators in closed-loop operation

Samuel Rosset、Benjamin O’Brien、Todd Gisby 等 6 位作者2013-09-19Smart Materials and Structures

Because of their large output strain, dielectric elastomer actuators (DEAs) have been proposed for tunable optics applications such as tunable gratings. However, the inherent viscoelastic drift of these actuators is an important drawback and closed-loop operation of DEAs is a prerequisite for any accurate real-world a…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsDielectric materials and actuators

Synthetic fibers and thermoplastic short‐fiber‐reinforced polymers: Properties and characterization

Christoph Unterweger、Oliver Brüggemann、Christian Fürst2013-09-19Polymer Composites

Among the synthetic fibers, glass fibers (GF) are most widely used in thermoplastic short‐fiber‐reinforced polymers (SFRP), as they offer good strength and stiffness, impact resistance, chemical resistance, and thermal stability at a low price. Carbon fibers (CF) are applied instead of GF, when highest stiffness is re…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

GeOx/Reduced Graphene Oxide Composite as an Anode for Li‐Ion Batteries: Enhanced Capacity via Reversible Utilization of Li2O along with Improved Rate Performance

Dongping Lv、Mikhail L. Gordin、Ran Yi 等 8 位作者2013-09-19Advanced Functional Materials

A self‐assembled GeOx/reduced graphene oxide (GeOx/RGO) composite, where GeOx nanoparticles are grown directly on reduced graphene oxide sheets, is synthesized via a facile one‐step reduction approach and studied by X‐ray diffraction, transmission electron microscopy, energy dispersive X‐ray spectroscopy, electron ene…

Advancements in Battery MaterialsGraphene research and applicationsAdvanced Battery Materials and Technologies

Linear versus Dendritic Molecular Binders for Hydrogel Network Formation with Clay Nanosheets: Studies with ABA Triblock Copolyethers Carrying Guanidinium Ion Pendants

Shingo Tamesue、Masataka Ohtani、Kuniyo Yamada 等 8 位作者2013-09-19Journal of the American Chemical Society

ABA-triblock copolyethers 1a-1c as linear polymeric binders, in combination with clay nanosheets (CNSs), afford high-water-content moldable supramolecular hydrogels with excellent mechanical properties by constructing a well-developed crosslinked network in water. The linear binders carry in their terminal A blocks gu…

Hydrogels: synthesis, properties, applicationsConducting polymers and applicationsPolymer composites and self-healing

Simultaneous Etching and Doping of TiO2 Nanowire Arrays for Enhanced Photoelectrochemical Performance

Yongcheng Wang、Yueyu Zhang、Jing Tang 等 8 位作者2013-09-19ACS Nano

We developed a postgrowth doping method of TiO2 nanowire arrays by a simultaneous hydrothermal etching and doping in a weakly alkaline condition. The obtained tungsten-doped TiO2 core-shell nanowires have an amorphous shell with a rough surface, in which W species are incorporated into the amorphous TiO2 shell during…

Advanced Photocatalysis TechniquesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Room-Temperature Synthesis of Flower-Like BiOX (X═Cl, Br, I) Hierarchical Structures and Their Visible-Light Photocatalytic Activity

Lang Chen、Rui Huang、Miao Xiong 等 10 位作者2013-09-19Inorganic Chemistry

A simple method for facile synthesis of three-dimensional (3D) bismuth oxyhalide (BiOX, X═Cl, Br, I) hierarchical structures at room temperature has been developed. Under the influence of L-lysine surfactant, the bismuth and halogen (Cl, Br, I) sources hydrolyze and self-assemble into flower-like hierarchical architec…

Advanced Photocatalysis TechniquesPerovskite Materials and ApplicationsGa2O3 and related materials

Molecular Doping Enhances Photoconductivity in Polymer Bulk Heterojunction Solar Cells

Yuan Zhang、Huiqiong Zhou、Jason Seifter 等 8 位作者2013-09-19Advanced Materials

Addition of low concentrations (<1:100, dopant:donor) of a fluorinated p-type dopant, F4-TCNQ leads to a considerable enhancement of the photocurrent in PCDTBT:PC70 BM bulk heterojunction solar cells. As a result, the power conversion efficiency increases from 6.41% to 7.94 %.

Organic Electronics and PhotovoltaicsThin-Film Transistor TechnologiesConducting polymers and applications

π-Electron Conjugation in Two Dimensions

Rico Gutzler、Dmitrii F. Perepichka2013-09-19Journal of the American Chemical Society

Organic oligomers and polymers with extended π-conjugation are the fundamental building blocks of organic electronic devices. Novel routes are being explored to create tailor-made organic materials, and recent progress in organic chemistry and surface chemistry has led to the synthesis of planar 2D polymers. Here we s…

Molecular Junctions and NanostructuresLuminescence and Fluorescent MaterialsSurface Chemistry and Catalysis

Graphene-based nanocomposites for energy storage and conversion in lithium batteries, supercapacitors and fuel cells

Nasir Mahmood、Chenzhen Zhang、Han Yin 等 4 位作者2013-09-19Journal of Materials Chemistry A

Due to their unique properties, together with their ease of synthesis and functionalization, graphene-based materials have been showing great potential in energy storage and conversion. These hybrid structures display excellent material characteristics, including high carrier mobility, faster recombination rate and lo…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Ultrahigh humidity sensitivity of graphene oxide

Hengchang Bi、Kuibo Yin、Xiao Xie 等 8 位作者2013-09-19Scientific Reports

Humidity sensors have been extensively used in various fields, and numerous problems are encountered when using humidity sensors, including low sensitivity, long response and recovery times, and narrow humidity detection ranges. Using graphene oxide (G-O) films as humidity sensing materials, we fabricate here a micros…

Graphene research and applicationsGas Sensing Nanomaterials and SensorsAnalytical Chemistry and Sensors

Recent progress in the development of near-infrared fluorescent probes for bioimaging applications

Zhiqian Guo、Sookil Park、Juyoung Yoon 等 4 位作者2013-09-19Chemical Society Reviews

Near-infrared (NIR) fluorescent dyes have emerged as promising modalities for monitoring the levels of various biologically relevant species in cells and organisms. The use of NIR probes enables deep photon penetration in tissue, minimizes photo-damage to biological samples, and produces low background auto-fluorescen…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors