Materials Literature
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We studied chemical reactions between ultrathin metal films (Al, Cr, Fe, Mo) and single-crystal oxides (SrTiO3 (100), TiO2 (110)) with X-ray photoelectron spectroscopy (XPS). The work function of the metal and the electron density in the oxide strongly influence the reaction onset temperature (T(RO)), where metal oxid…
A series of six new dyads consisting of a zinc or magnesium porphyrin appended to a platinum terpyridine acetylide complex via a para-phenylene bisacetylene spacer are described. Different substituents on the 4' position of the terpyridinyl ligand were explored (OC7H15, PO3Et2, and H). The ground-state electronic prop…
Cobalt-filled apoferritin (Co-ferritin) was, for the first time, used as a wet catalyst for the synthesis of single-walled carbon nanotubes (SWNTs) with narrow diameter distribution. Co-ferritins were spin-coated and converted to cobalt nanoparticles by calcination. Using chemical vapor deposition, suspended networks…
Four various mesoporous silicas (MCM-48, SBA-15, MCF, and MSU) were modified by the molecular designed dispersion method using Fe(acac)3, Cr(acac)3, and Cu(acac)2 complexes. The deposition was performed at the same concentration of the metal acetylacetonate (acac) complex in a toluene solution. All as-synthesized samp…
Thiol-functionalized mesostructured silica with anhydrous compositions of (SiO(2))(1)(-)(x)()(LSiO(1.5))(x)(), where L is a mercaptopropyl group and x is the fraction of functionalized framework silicon centers, are effective trapping agents for the removal of mercuric(II) ions from water. In the present work, we inve…
Photolabile coumarinylmethyl esters of biomolecules (caged compounds) are new tools for studying spatial and time-dependent aspects of signal transduction in living cells. Herein we describe a fluoresence spectroscopic method for the determination of the rate constants of the photolysis steps of such caged compounds u…
Manganese and molybdenum mixed oxides in a thin film form were deposited anodically on a platinum substrate by cycling the electrode potential between 0 and +1.0 V vs Ag/AgCl in aqueous manganese(II) solutions containing molybdate anion (MoO(4)2-). A possible mechanism for the film formation is as follows. First, elec…
Carbon nanotubes play a fundamental role in the rapidly developing field of nanoscience and nanotechnology because of their unique properties and high potential applictions. In this article, the different synthesis method of CNTs are reviewed. From the industrial point of view, the chemical vapor depostion method has…
The development of functionalized polymers that can elicit specific biological responses is of great interest in the biomedical community, as well as the development of methods to fabricate these biologically functionalized polymers. For example, the generation of fibrous matrices with biological properties and fiber…
An in situ polycondensation approach was applied to functionalize multiwalled carbon nanotubes (MWNTs), resulting in various linear or hyperbranched polycondensed polymers [e.g., polyureas, polyurethanes, and poly(urea-urethane)-bonded carbon nanotubes]. The quantity of the grafted polymer can be easily controlled by…
This work reports the design of polymer micelles with cross-linked ionic cores that display high stability. Block ionomer complexes were utilized as a micellar template for the synthesis of the cross-linked micelles. Such micelles represent hydrophilic nanospheres of core-shell morphology. The core comprises a network…
Electron paramagnetic resonance (EPR), X-ray photoelectron spectroscopy (XPS), and density functional theory (DFT) calculations are combined for the first time in an effort to characterize the paramagnetic species present in N-doped anatase TiO2 powders obtained by sol-gel synthesis. The experimental hyperfine couplin…
SiO x thin films with different stoichiometry degree were obtained by plasma-enhanced chemical vapor deposition on crystalline silicon substrates from SiH4 and N2O gas mixtures. Two twin sets of samples were irradiated by 380 keV Ar+ ions at a fluence of 5×1016ions∕cm2 at room temperature and at 500 °C, respectively,…
Some metallic alloys such as Nitinol (NiTi) exhibit the shape memory effect, which is suitable for generating force and displacement when the alloy changes phase during a heating and cooling cycle. These shape memory alloys are often formed into one-dimensional wires, tubes, and ribbons that are preloaded by bias spri…
Abstract Thiosilicates of the Rare‐Earth Elements: III. KLa[SiS 4 ] and RbLa[SiS 4 ] – A Structural Comparison Pale yellow, platelet shaped, air‐ and water resistant single crystals of KLa[SiS 4 ] derived from the reaction of lanthanum (La) and sulfur (S) with silicon disulfide (SiS 2 ) in a molar ratio of 2 : 3 : 1 w…
The crystallization of amorphous Mg-bearing silicate grains into Mg2SiO4 and its temperature dependence were clarified by observing the grains in situ while heating in a transmission electron microscope. The crystallization started from the grain surface at 800 °C. Before the crystallization at the grain surface, the…
Abstract We report the monomer reactivity ratios for copolymers of glycidyl methacrylate (GMA) and a reactive monomer, 2‐[(5‐methylisoxazol‐3‐yl)amino]‐2‐oxo‐ethyl methacrylate (IAOEMA), using the Fineman–Ross method, the Kelen–Tüdös method, and a nonlinear error invariablemodel method with the computer program RREVM.…
Meso- and (1S, 2S)-diphenyl-1,2-ethanediammonium (DPEDA2+) complexed with [18]crown-6 were introduced into [Ni(dmit)2]-based magnetic salts as countercations. The configurational difference of DPEDA2+ modulated the crystal structure and magnetic behavior of the salts. A two-dimensional (2D) Heisenberg antiferromagneti…
Vitronectin (Vn) is an adhesive protein in the plasma serum and plays an important role in cell attachment, spreading, and proliferation. The interactions between protein bovine vitronectin layers adsorbed onto a silica probe and a mica surface have been investigated with the use of atomic force microscopy (AFM). Adso…
We have significantly improved the energy resolution of a vacuum ultraviolet isochromat spectrometer for inverse photoemission spectroscopy. The detector is based on a Geiger–Müller counting tube with acetone as filling gas and a CaF2 entrance window working as an energy selective optical bandpass at a mean energy of…