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X-ray Couette shear cell for nonequilibrium structural studies of complex fluids under flow

Robert J. Plano、Cyrus R. Safinya、E. B. Sirota 等 4 位作者1993-05-01Review of Scientific Instruments

We have designed and constructed a sealed, temperature-controlled Couette-type shear cell which allows us to carry out in situ synchrotron x-ray scattering studies of the nonequilibrium structures of complex fluids under flow, probing lengths ranging from the nanometer to the semimacroscopic micron scale. The sealed d…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Cellulose acetate propionate and poly(tetramethylene glutarate) blends

Charles M. Buchanan、Steve C. Gedon、Alan W. White 等 4 位作者1993-05-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCellulose acetate propionate and poly(tetramethylene glutarate) blendsCharles M. Buchanan, Steve C. Gedon, Alan W. White, and Matthew D. WoodCite this: Macromolecules 1993, 26, 11, 2963–2967Publication Date (Print):May 1, 1993Publication History Published online1 May 2002Pub…

Advanced Cellulose Research Studies

Investigation of S/sub 2/F/sub 10/ production and mitigation in compressed SF/sub 6/-insulated power systems

D. R. James、I. Sauers、Guy D. Griffin 等 9 位作者1993-05-01IEEE Electrical Insulation Magazine

The Cooperative Research and Development Agreement (CRADA), established to study the production and mitigation of S/sub 2/F/sub 10/ (disulfur decafluoride), one of a number of toxic by-products formed in electric discharges in the insulating gas SF/sub 6/, is described. The particular concern about S/sub 2/F/sub 10/ i…

High voltage insulation and dielectric phenomenaVacuum and Plasma ArcsElectrostatic Discharge in Electronics

Bis(dimethylviolurato)(phenanthroline)cobalt(II), a low-spin octahedral cobalt(II) complex. Crystal structure of [Co(dmvi)2phen].2CHCl3

Juan Faus、Miguel Julve、Francisco Lloret 等 4 位作者1993-05-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBis(dimethylviolurato)(phenanthroline)cobalt(II), a low-spin octahedral cobalt(II) complex. Crystal structure of [Co(dmvi)2phen].2CHCl3Juan Faus, Miguel Julve, Francisco Lloret, and M. Carmen MunozCite this: Inorg. Chem. 1993, 32, 10, 2013–2017Publication Date (Print):May 1,…

Organometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesMagnetism in coordination complexes

Calibration of an electron back‐scattering pattern set‐up

Niels Christian Krieger Lassen、Jørgen Bilde-Sørensen1993-05-01Journal of Microscopy

Summary The determination of lattice orientations from electron back‐scattering patterns (EBSPs) in a scanning electron microscope (SEM) requires accurate knowledge of the position of the pattern centre and the source point to screen distance. This paper outlines a new procedure that enables the determination of these…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Anisotropic Chemical Etching of Copper Foil: I . Electrochemical Studies in Acidic Solutions

Maria Georgiadou、Richard C. Alkire1993-05-01Journal of The Electrochemical Society

Etching of thick copper foil masked except for a single rectangular opening having an aspect ratio (width:depth) of 5:1 or 1:1 was investigated in the presence of controlled laminar flow across the width of the pattern opening. In a solution of , copper was found to form a surface film spontaneously at the "corrosion…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsCopper Interconnects and Reliability

Transient and Load-Following Characteristics of a Fully Integrated Single-Cell Thermionic Fuel Element

Mohamed S. El‐Genk、Huimin Xue、Christopher S. Murray1993-05-01Nuclear Technology

A thermionic transient analysis model is developed to simulate transient and steady-state operations of a fully integrated, single-cell thermionic fuel element (TFE). The responses of the TFE to a step input in reactivity and changes in the cesium pressure or in the size of the interelectrode gap, the coolant temperat…

Advanced Battery Materials and TechnologiesAdvanced Thermoelectric Materials and DevicesHydrogen Storage and Materials

Synthesis and structural characterization of the [AuTe7]3- anion: a planar species with an unprecedented coordination mode

Mohammad A. Ansari、John C. Bollinger、James A. Ibers1993-05-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and structural characterization of the [AuTe7]3- anion: a planar species with an unprecedented coordination modeMohammad A. Ansari, John C. Bollinger, and James A. IbersCite this: J. Am. Chem. Soc. 1993, 115, 9, 3838–3839Publication Date (Print):May 1, 1993Publicat…

Crystal Structures and PropertiesNanocluster Synthesis and ApplicationsInorganic Chemistry and Materials

Recent advances in photosensitive polyimides

Hellmut Ahne、R. Leuschner、Roland Rubner1993-05-01Polymers for Advanced Technologies

Abstract The state of the art of photosensitive polyimides is reviewed with respect to the incorporation of photosensitivity into both polyimide precursors and soluble polyimides, for patterning in positive and negative modes. This paper emphasizes, in particular, the discussion of the performance of commercially avai…

Synthesis and properties of polymersSilicone and Siloxane ChemistryPhotopolymerization techniques and applications

Effect of atomic hydrogen and oxygen on diamond growth

Biwu Sun、Xiaopin Zhang、Qinzhe Zhang 等 4 位作者1993-05-01Journal of Applied Physics

High-resolution electron energy loss spectroscopy has been used to investigate the effect of atomic hydrogen and oxygen on diamond growth. For a totally desorbed diamond (100) surface, atomic hydrogen corrodes carbon atoms on the surface first, then saturates the dangling bonds of sp3 hybridized carbon atoms on the ne…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Magnetic field evaluation for thick annular conductors

B. Azzerboni、E. Cardelli、Marco Raugi 等 5 位作者1993-05-01IEEE Transactions on Magnetics

The three-dimensional integration of the Biot-Savart law for conductors in annular sector shape, in which only a constant-density theta -directed current flows, is reported. The expressions obtained allow a quick and accurate evaluation of the components of the vector potential of the stationary magnetic field and of…

Physics of Superconductivity and MagnetismMagnetic Properties and ApplicationsMagneto-Optical Properties and Applications

Electrochemistry and spectroelectrochemistry of substituted tetrabenzotriazaporphine

Yu‐Hong Tse、Alok Goel、Mougang Hu 等 6 位作者1993-05-01Canadian Journal of Chemistry

The spectral and electrochemical properties of tetrabenzo[5,10,15]triazaporphine (TBTAP) and its magnesium derivatives having a long alkyl chain attached to the meso carbon have been studied. Both metal-free and metallated species show typical metal-free phthalocyanine-like spectra. Two reduction and two oxidation red…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesPorphyrin Metabolism and Disorders

Vapor-Phase Oxidation of Ethyl Lactate to Pyruvate over Various Oxide Catalysts

Shigeru Sugiyama、Naoya Shigemoto、Naoki Masaoka 等 7 位作者1993-05-01Bulletin of the Chemical Society of Japan

Abstract Oxidation of ethyl lactate to pyruvate was carried out in vapor-phase over various oxides. MoO3 showed a higher selectivity than that of the other single oxide examined. Binary oxides containing molybdenum such as Fe2O3–MoO3 and TeO2–MoO3 showed high selectivities to pyruvate over 90% at 300 °C with high lact…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Light-scattering study of a surface-induced phase transition in alkane fluids

C. J. Hughes、J. C. Earnshaw1993-05-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The surfaces of normal liquid alkanes (chain lengths between 15 and 18 carbon atoms) have been studied by light scattering from thermally excited capillary waves. These fluids have recently been reported to exhibit a surface-induced phase transition at temperatures (${\mathit{T}}_{\mathit{k}}$) near, but distinct from…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesAdvanced Thermodynamics and Statistical Mechanics

Reactive rubbers as toughening agents for thermoset polyester resins. Molecular analysis by FTIR and fracture behavior of the resulting blends

E. Martuscelli、Pellegrino Musto、G. Ragosta 等 5 位作者1993-05-01Journal of Polymer Science Part B Polymer Physics

Abstract A reactive rubber obtained by isocyanation of hydroxyl‐terminated polybutadiene was used as toughening agent for an unsaturated polyester resin. Both the isocyanation and the successive reaction between the modified rubber and the polyester were investigated by Fourier‐transform infrared spectroscopy (FTIR).…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesEpoxy Resin Curing Processes

Decay kinetics of CsI: Tl luminescence excited in the A absorption band

M. Nikl、J. Hlinka、E. Mihóková 等 6 位作者1993-05-01Philosophical Magazine B

Luminescence emission, including decay kinetics, has been investigated for CsI: Tl excited in the A absorption band of Tl+, in the temperature range 4–300 K. Three emission bands have been identified and ascribed to transitions from non-equivalent minima on the adiabatic potential surface of the excited state of isola…

Advanced Chemical Physics StudiesLuminescence Properties of Advanced MaterialsQuantum optics and atomic interactions

Biaxial effect at an isotropic-nematic interface

Zheng Yu Chen1993-05-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

A numerical solution is obtained for the generalized Onsager problem for the isotropic-nematic interface of rigid rods, which accounts for the biaxial effect that was ignored in previous calculations. It is found that the biaxial effect on interfacial tension is indeed weak, as previously expected. The biaxiality beco…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsPickering emulsions and particle stabilization

Synthesis and electrochemical properties of 1,4-dithiafulvenyl-substituted bianthrone molecules with potential application as molecular switches

Mikkel Joergensen、Knud Lerstrup、Peter Frederiksen 等 8 位作者1993-05-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and electrochemical properties of 1,4-dithiafulvenyl-substituted bianthrone molecules with potential application as molecular switchesMikkel Joergensen, Knud Lerstrup, Peter Frederiksen, Thomas Bjoernholm, Peter Sommer-Larsen, Kjeld Schaumburg, Kay Brunfeldt, and K…

Molecular Junctions and NanostructuresOrganic and Molecular Conductors ResearchOrganic Chemistry Cycloaddition Reactions

Monte Carlo evaluation of the influence of the interaction cross sections on the secondary-electron-emission yields from polycrystalline aluminum targets

Alain Dubus、J.C. Dehaes、J.P. Ganachaud 等 5 位作者1993-05-01Physical review. B, Condensed matter

The aim of this paper is to show that different assumptions for the interaction cross sections of low-energy electrons in polycrystalline aluminum targets lead to very different calculated values of secondary-electron yields, either in backscattering or in transmission. We emphasize the importance of the description o…

X-ray Spectroscopy and Fluorescence AnalysisNuclear Physics and ApplicationsElectron and X-Ray Spectroscopy Techniques

Diamond grown on single-crystal beryllium oxide

Alberto Argoitia、John C. Angus、Long Wang 等 5 位作者1993-05-01Journal of Applied Physics

Diamond has been grown on single-crystal beryllium oxide by hot-filament chemical-vapor deposition. The diamond particles were characterized by Raman spectroscopy, and the morphology and microstructure investigated by scanning electron microscopy and plan-view and cross-sectional transmission electron microscopy. Diam…

Metal and Thin Film MechanicsHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research