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Photopolymerizable Synthons from Glycerol Derivatives

Ali Mhanna、Faten Sadaka、Gilles Boni 等 8 位作者2013-11-05Journal of the American Oil Chemists Society

Abstract Photopolymerizable monomers based on monoglycerides were prepared by a convenient two‐step procedure. The first one consists of the synthesis of highly pure monoglycerides by an organocatalyzed solvent‐free route. This process was carried out by condensation of bio‐sourced carboxylic acids (i.e. butyric, deca…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisPhotopolymerization techniques and applications

CO 2 laser irradiation of raw and bleached cotton fabrics, with focus on water and dye absorbency

Majid Montazer、Ghazaleh Chizari Fard、Tina Harifi2013-11-05Coloration Technology

In this research, the effect of carbon dioxide laser irradiation on various properties of raw and bleached cotton fabrics, including fabric weight, bending rigidity, wetting, and air permeability, as well as dyeing, was examined and compared. The experiments were carried out at three different laser powers ranging fro…

Surface Modification and SuperhydrophobicityDyeing and Modifying Textile FibersTextile materials and evaluations

Effect of the conditions of preparing mixed oxide catalyst of Mo-V-Te-Nb-O composition on its activity in the oxidative dehydrogenation of ethane

Е. Д. Финашина、A.V. Kucherov、Л. М. Кустов2013-11-05Russian Journal of Physical Chemistry A

It is shown that catalytic activity of mixed oxide catalyst of Mo-V-Te-Nb-O composition in oxidative dehydrogenation (OD) of ethane is determined to a substantial degree by the Nb-to-(C 2 O 4 ) 2− ratio in niobium-containing precursors. A pH value of 2.8 to 3.0 for a mixture is optimal when conducting the hydrothermal…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

An optimized frequency-dependent multiphysics model for an ionic polymer–metal composite actuator with ethylene glycol as the solvent

Riccardo Caponetto、Viviana De Luca、Salvatore Graziani 等 4 位作者2013-11-05Smart Materials and Structures

IPMCs are electroactive polymers which can be used both as sensors and as actuators. The modeling of IPMC transducers is an open issue relevant to the development of effective applications. A multiphysics model of IPMC actuators is here implemented. It integrates the description of the electrical, mechanical, chemical…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsDielectric materials and actuators

[3+2] Cycloaddition of Aziridines and Alkenes Catalyzed by a Cationic Manganese Porphyrin

Takuya Kurahashi、Seijiro Matsubara、Takuya Ozawa2013-11-05Synlett

A formal [3+2] cycloaddition between aziridines and alkenes to give the corresponding pyrrolidines was successfully carried out in the presence of a cationic manganese porphyrin catalyst. The use of the porphyrin catalyst allowed, for the first time, styrene derivatives to react with aziridines.

Porphyrin and Phthalocyanine ChemistryCyclopropane Reaction MechanismsSynthesis and Catalytic Reactions

Gas-Phase Synthesis of Phenyl Oxoborane (C6H5BO) via the Reaction of Boron Monoxide with Benzene

Dorian S. N. Parker、Beni B. Dangi、Nadia Balucani 等 6 位作者2013-11-05The Journal of Organic Chemistry

Organyl oxoboranes (RBO) are valuable reagents in organic synthesis due to their role in Suzuki coupling reactions. However, organyl oxoboranes (RBO) are only found in trimeric forms (RBO3) commonly known as boronic acids or boroxins; obtaining their monomers has proved a complex endeavor. Here, we demonstrate an olig…

Boron and Carbon Nanomaterials ResearchOrganoboron and organosilicon chemistryBoron Compounds in Chemistry

Vibrational Dynamics of Filled Skutterudites LaT4X12 (T = Fe, Ru, Os, X = As, Sb)

Michael Marek Koza、D. T. Adroja、N. Takeda 等 5 位作者2013-11-05Journal of the Physical Society of Japan

We report on the vibrational properties of the lanthanum filled skutterudite compounds LaRu4Sb12, LaOs4Sb12, and LaOs4As12 studied by inelastic neutron scattering. The experimental data are backed up by ab initio lattice dynamics calculations of the complete series of lanthanum filled skutterudites La\(T_{4}X_{12}\) w…

Rare-earth and actinide compoundsAdvanced Condensed Matter PhysicsIron-based superconductors research

Anomalous resistance overshoot in the integer quantum Hall effect

E. M. Kendirlik、S. Sirt、Sırrı Batuhan Kalkan 等 7 位作者2013-11-05Scientific Reports

In this work we report on experiments performed on smooth edge-narrow Hall bars. The magneto-transport properties of intermediate mobility two-dimensional electron systems are investigated and analyzed within the screening theory of the integer quantized Hall effect. We observe a non-monotonic increase of Hall resista…

Graphene research and applicationsQuantum and electron transport phenomenaAdvancements in Semiconductor Devices and Circuit Design

Shear-Jamming in Two-Dimensional Granular Materials with Power-Law Grain-Size Distribution

Agnieszka Herman2013-11-05Entropy

Although substantial progress has been made in recent years in research onsheared granular matter, relatively few studies concentrate on the behavior of materials withvery strong polydispersity. In this paper, shear deformation of a two-dimensional granularmaterial composed of frictional disk-shaped grains with power-…

Material Dynamics and PropertiesLandslides and related hazardsGranular flow and fluidized beds

Hydration Dynamics for Vanadia/Titania Catalysts at High Loading: A Combined Theoretical and Experimental Study

Anna E. Lewandowska、Mónica Calatayud、Frederik Tielens 等 4 位作者2013-11-05The Journal of Physical Chemistry C

Periodic DFT calculations are used to simulate the early stages of hydration of dehydrated high-loading vanadia/titania catalysts. The hydration of molecularly dispersed vanadia is studied by successive additions of water molecules to initially dehydrated models. Special attention is paid to the formation and transfor…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Temperature dependence of stacking faults in catalyst-free GaAs nanopillars

Joshua Shapiro、Andrew Lin、Christian Rätsch 等 4 位作者2013-11-05Nanotechnology

Impressive opto-electronic devices and transistors have recently been fabricated from GaAs nanopillars grown by catalyst-free selective-area epitaxy, but this growth technique has always resulted in high densities of stacking faults. A stacking fault occurs when atoms on the growing (111) surface occupy the sites of a…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesNanowire Synthesis and Applications

Synthesis, Crystal Structure, and Theoretical Calculation of the Cd(II) Complex with 2-Aminobenzothiazole

Xingchen Yan、Yuhua Fan、Caifeng Bi 等 7 位作者2013-11-05Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry

A novel complex, [CdL2(CH3COO)2] (1), was synthesized and characterized by IR, elemental analysis, and X-ray diffraction single-crystal analysis. Its crystal structure was compared with a previously reported complex, [ZnL2(CH3COO)2] (2). Complex (1) crystallizes in orthorhombic, space group Pna2(1) with a = 8.8821 (7)…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Stable microwave-assisted magnetization switching for nanoscale exchange-coupled composite grain

Terumitsu Tanaka、Shota Kashiwagi、Furomoto Yoshitoki 等 5 位作者2013-11-05Nanoscale Research Letters

Magnetization mechanisms of nanoscale magnetic grains greatly differ from well-known magnetization mechanisms of micrometer- or millimeter-sized magnetic grains or particles. Magnetization switching mechanisms of nanoscale exchange-coupled composite (ECC) grain in a microwave field was studied using micromagnetic simu…

Magnetic properties of thin filmsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites

Computed Molecular Depth Profile for C60 Bombardment of a Molecular solid

Robert J. Paruch、Barbara J. Garrison、Zbigniew Postawa2013-11-05Analytical Chemistry

Molecular dynamics (MD) simulations have been performed for 10 keV C60 bombardment of an octane molecular solid at normal incidence. The results are analyzed using the steady-state statistical sputtering model (SS-SSM) to understand the nature of molecular motions and to predict a depth profile of a δ-layer. The octan…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Artificial Neural Network-Based Model for Calculating the Flow Composition Influence of Solid Oxide Fuel Cell

J. Milewski、Konrad Świrski2013-11-05Journal of Electrochemical Energy Conversion and Storage

The paper presents use of an artificial neural network (ANN) for predicting the thermal-flow behavior of a solid oxide fuel cell with no algorithmic solution merely by utilizing available experimental data. The error backpropagation algorithm was used for an ANN training procedure.

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsFault Detection and Control Systems

Osmotic Dehydration of Bamboo Shoots Enhanced by Centrifugal Force and Pulsed Vacuum Using Salt as Osmotic Agent

Laxmikant S. Badwaik、Moharana Choudhury、Kshirod Kumar Dash 等 5 位作者2013-11-05Journal of Food Processing and Preservation

Osmotic dehydration of bamboo shoots was carried out using salt as osmotic agent. Experiments were designed according to central composite rotatable design and response surface methodology was used to determine the optimum processing conditions. The effect of temperature, time and salt concentration on water loss (WL)…

Natural Fiber Reinforced CompositesPolysaccharides and Plant Cell WallsBamboo properties and applications

Thermal lensing inNm-cut monoclinic Tm:KLu(WO4)2laser crystal

Pavel Loiko、S M Vatnik、I A Vedin 等 6 位作者2013-11-05Laser Physics Letters

The thermal lensing effect is characterized in slab-shaped monoclinic Tm:KLu(WO 4 ) 2 crystal cut for light propagation along the N m optical indicatrix axis (the light polarization is E ∥ N p ). The optical power of the thermal lens was measured directly by a modified probe beam technique. Alternatively, it was calcu…

Luminescence Properties of Advanced MaterialsPhotorefractive and Nonlinear OpticsSolid State Laser Technologies

Deburring Effect of Plasma Produced by Nanosecond Laser Ablation

Yun Zhou、Yibo Gao、Benxin Wu 等 5 位作者2013-11-05Journal of Manufacturing Science and Engineering

This paper presents an interesting nanosecond (ns) laser-induced plasma deburring (LPD) effect (from microchannel sidewalls) discovered by the authors, which has been rarely reported before in the literature. Fast imagining study has been performed on plasma produced by ns laser ablation of the bottom of microchannels…

Diamond and Carbon-based Materials ResearchAdvanced Surface Polishing TechniquesAdvanced Machining and Optimization Techniques

Electrophoretically deposited thin film electrolyte for solid oxide fuel cell

Dulal Das、Rajendra N. Basu2013-11-05Advances in Applied Ceramics Structural Functional and Bioceramics

Thin films of 8 mol% yttria stabilised zirconia (YSZ) electrolyte have been deposited on non-conducting porous NiO–YSZ anode substrates using electrophoretic deposition (EPD) technique. Deposition of such oxide particulates on non-conducting substrates is made possible by placing a conducting steel plate on the revers…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsElectrophoretic Deposition in Materials Science

Improvements in carbon fibre reinforced composites by inkjet printing of thermoplastic polymer patterns

Yi Zhang、Jonathan Stringer、Richard S. Grainger 等 5 位作者2013-11-05physica status solidi (RRL) - Rapid Research Letters

Abstract A thermoplastic polymer solution was inkjet printed in a pre‐defined hexagonal pattern onto carbon fibre reinforced epoxy resin (CFRP), leading to a significant increase in strength, stiffness and toughness of the final aerospace grade compo‐site system. The approach consisted of depositing low‐viscosity poly…

Surface Modification and SuperhydrophobicityAdditive Manufacturing and 3D Printing TechnologiesNanomaterials and Printing Technologies