Materials Literature
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We demonstrate the self-assembling and size-selective synthesis of uniform and highly dispersed Ni or NiO nanoparticles with diameters below 12 nm embedded in ordered mesoporous carbon or polymer frameworks. Self-assembly is induced by evaporation of the solvent from a mixture of metal-containing liquid crystalline (L…
Abstract This study aimed to find out the primary factors influencing the diameter of electrospun nanofibers of nylon‐6,6 using artificial neural networks (ANNs). Four variables, namely, polymer concentration, working distance, injection rate, and applied voltage were considered as input parameters and the nanofibers…
UNLABELLED: Residual O(2) in a package headspace can be removed by an O(2)-absorbing sachet, which can be harmful if swallowed by the consumer, or by a chemically-active plastic packaging film, which is difficult to recycle. An edible, O(2)-absorbing film would avoid these disadvantages. The objective of our research…
Using chemical solution approach on Pt/Ti/SiO 2 /Si substrates (1 − x ) Ba ( Zr 0.2 Ti 0.8 )O 3 – x ( Ba 0.7 Ca 0.3 ) TiO 3 (BZT–BCT) ferroelectric thin films were prepared for the first time. Dense and crack‐free films with perovskite structure were obtained from appropriately produced precursor solution through a mu…
Abstract This article investigates the transport behavior of three aromatic organic solvents, viz. benzene, toluene, and p ‐xylene in natural rubber nanocomposite membranes containing cellulose nanofibres (CNFs) and cellulose nanowhiskers (CNWs) isolated from bamboo pulp. The solvent molecules act as molecular probes…
The nonlinear properties and electrical stability of ZnO varistors were improved with B 2 O 3 additive using nano‐coating method. The microstructural morphology and nonlinear electrical properties with increasing B 2 O 3 contents were studied using SEM and C – V measurements. The influence of B 2 O 3 on grains and gra…
Das rechnergestützte Design tetraradikalischer S1-Zustände wurde experimentell durch Synthese und anschließende Charakterisierung einschließlich Phosphoreszenzmessungen, Gebrauch von Einfangmolekülen und Zellkultur-Untersuchungen bestätigt. Dies führte zu einer Reihe orthogonaler Bodipy-Chromophor-Dimere mit bemerkens…
The performance of popular Hartree-Fock-based effective core potentials in Hartree-Fock and density functional calculations of 3d transition metals has been evaluated by basis-set convergence studies for ten cases: the equilibrium bond dissociation energy (De) for dissociation of ground-state Ti2 to ground and excited…
The two Flag/MaSp 2 silk proteins produced recombinantly were based on the basic consensus repeat of the dragline silk spidroin 2 protein (MaSp 2) from the Nephila clavipes orb weaving spider. However, the proline-containing pentapeptides juxtaposed to the polyalanine segments resembled those found in the flagelliform…
Abstract Mesoporous silica nanoparticles (MSNs) are of growing interest for the development of novel probes enabling efficient tracking of cells in vivo using magnetic resonance imaging (MRI). The incorporation of Gd 3+ paramagnetic ions into highly porous MSNs is a powerful strategy to synthesize “positive” MRI contr…
Flexural strength, elastic modulus, and hardness were used to characterize the mechanical properties of ZrB 2 –SiC composites that contained varying SiC particle sizes. Dense ZrB 2 –SiC composites consisting of 70 vol% ZrB 2 and 30 vol% α‐SiC were produced via hot pressing. This series of composites had maximum SiC pa…
An anthracene unit was successfully fused to the zigzag edge of a boron dipyrromethene (BODIPY) core by an FeCl(3)-mediated oxidative cyclodehydrogenation reaction. Meanwhile, a dimer was also formed by both intramolecular cyclization and intermolecular coupling. The anthracene-fused BODIPY monomer 7a and dimer 7b sho…
Motivated by recent Fermi-surface and transport measurements on LaNiO${}_{3}$, we study the Mott metal-insulator transitions of perovskite nickelates, with the chemical formula $R$NiO${}_{3}$, where $R$is a rare-earth ion. We introduce and study a minimal two-band model, which takes into account only the e${}_{g}$ ban…
A straightforward functionalization strategy for the direct attachment of single-stranded oligonucleotides (ssDNA) to quantum dot (qdot) interfaces is described. The approach takes advantage of a histidine-mediated phase transfer protocol that results in qdots with high colloidal stability in aqueous buffers. The weak…
Dense ceramic composites with ferroelectric BaTiO 3 and metal Cu were prepared via the solid‐state reaction route at 1280°C in nitrogen atmosphere. The frequency and temperature dependence of impedance, resistance, and dielectric permittivity of BaTiO 3 / x Cu in the range of 10 −1 –10 6 Hz have been investigated, res…
We study the mechanisms of the homogeneous crystal nucleation from the supercooled liquid to the crystal phase in the Gaussian core model for colloidal suspensions with the aim to find optimal reaction coordinates. We introduce a set of novel collective variables based on the local structure of particles. By applying…
A treatment of the Temkin model was developed for describing the adsorption of CO on gold. In this presentation, it is made clear that the Temkin thermodynamic model is an extension of the Langmuir model that incorporates a linear variation of the adsorption enthalpy. It is also stressed that the Temkin model can be i…
The initial employment of 2-(hydroxymethyl)pyridine in 4f metal chemistry has afforded a new family of Ln(III)(9) clusters with a sandglass-like topology and dual physical properties; the Dy(III) member shows single-molecule magnetism behavior, while the Eu(III) analogue exhibits intense red photoluminescence.
Abstract The objective of this study is to develop an advanced stab and/or ballistic proof material composed of shear thickening fluid (STF) and Kevlar composite fabric. In this study, we prepared STF using sphere silica and fumed silica as silica particles and ethylene glycol and polyethylene glycol (PEG 200) as medi…
Plasmonic nanoparticle research has become increasingly active due to potential uses in biomedical applications. However, little is known about the intracellular effects these nanoparticles have on mammalian cells. The aim of this work is to investigate whether silver nanoparticles (AgNPs) conjugated with nuclear and…