Materials Literature
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This paper describes the first material to show the well-known light-induced excited spin-state trapping (LIESST) effect, the metastable excited state of which relaxes at a temperature approaching its thermal spin-crossover. Cooling polycrystalline [FeL(2)][BF(4)](2).x H(2)O (L=2,6-bis[3-methylpyrazol-1-yl]pyridine; x…
Abstract Different density rigid polyurethane foams (RPUF) filled with various expandable graphite loadings were fabricated by cast molding. The flame retardant properties of these composites were assessed by limiting oxygen index and horizontal and vertical burning tests. The results showed that the flame retardant e…
Microelectronics are built from materials whose electrons interact strongly and can exhibit properties as a group that are not seen in any one particle.
Graphite is a layered material showing a strong anisotropy. Among the unconventional properties reported by experiments, the electronic transport along the c-axis, which has direct implications in order to build graphitic devices, remains a controversial topic. We study the influence of inelastic scattering on the ele…
Single-wall carbon nanohorns (SWNHs) are a new class of material that is closely related to single-wall carbon nanotubes. Here, we describe the synthesis and characterization of a series of SWNHs functionalized with ethylene glycol chains and porphyrins. Functionalization of carbon nanohorns has been achieved using tw…
We present a brief review on spin transverse force, which exerts on the spin as the electron is moving in an electric field. This force, analogue to the Lorentz force on electron charge, is perpendicular to the electric field and spin current carried by the electron. The force stems from the spin-orbit coupling of ele…
Activation energies and reaction paths for diffusion and nucleation of mono- and divacancy defects in hexagonal boron nitride layers are theoretically investigated. Migration paths are derived using the nudged elastic band method combined with density-functional-based techniques. We find a different behavior for migra…
Abstract Alginate is an interesting natural biopolymer for many of its merits and good biological properties. This paper investigates the electrospinning of sodium alginate (NaAlg), NaAlg/PVA‐ and NaAlg/PEO‐ blended systems. It was found in this research that although NaAlg can easily be dissolved in water, the aqueou…
Isothermal polarization and depolarization currents in polystyrene doped with DR1 chromophore molecules have been measured and analyzed in order to study the electrical relaxation of the poled order in this guest-host system. It has been shown that the superposition principle is applicable to the polymer system under…
We describe the development of artificial neural networks (ANN) for the prediction of the properties of ceramic materials. The ceramics studied here include polycrystalline, inorganic, non-metallic materials and are investigated on the basis of their dielectric and ionic properties. Dielectric materials are of interes…
Two modifications of the Thermally Stimulated Depolarization Current method are proposed to improve resolution and sensitivity of the method by connecting either a real capacitor, or an additional resistor in series with the sample. It is shown experimentally that high sensitivity of the TSDC method with an air gap ca…
Leakage current measurements were performed on epitaxial, single-crystal quality $\mathrm{Pb}(\mathrm{Zr},\mathrm{Ti}){\mathrm{O}}_{3}$ films with thicknesses in the $50--300\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$ range. It was found that the voltage behavior of the leakage current has a minor dependence on thickness,…
ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTPreparation of Homogeneous Dispersions of Tunicate Cellulose Whiskers in Organic SolventsOtto van den Berg, Jeffrey R. Capadona, and Christoph WederView Author Information Department of Macromolecular Science and Engineering, Case Western Reserve University, 2100 Adelbert Road,…
Packaging waste accounted for 78.81 million tons or 31.6% of the total municipal solid waste (MSW) in 2003 in the USA, 56.3 million tons or 25% of the MSW in 2005 in Europe, and 3.3 million tons or 10% of the MSW in 2004 in Australia. Currently, in the USA the dominant method of packaging waste disposal is landfill, f…
Silver nanobars with rectangular side facets and an average aspect ratio of 2.7 have been synthesized by modifying the concentration of bromide added to a polyol synthesis. Subsequent rounding of nanobars transformed them into nanorice. Due to their anisotropy, nanobars and nanorice exhibit two plasmon resonance peaks…
We study from first principles the magnetism in graphene induced by single carbon atom defects. For two types of defects considered in our study, the hydrogen chemisorption defect and the vacancy defect, the itinerant magnetism due to the defect-induced extended states has been observed. Calculated magnetic moments ar…
Abstract On the Identity of a so‐called Ammonium Carbonate Sample Commercial samples of so‐called “ammionum carbonate” are shown to contain ammonium carbamate rather than ammonium carbonate. In fact samples may contain varying quantities of α‐ and β‐(NH 4 )(CO 2 NH 2 ), of which only the α‐phase is reported in the lit…
Abstract A novel heterospin complex containing both Ni II and nitroxide radical ligands: [Ni(salox) 2 (NIT4Py) 2 ] ( 1 ) (salox = salicylaldoxime, NIT4Py = 2‐(4′‐pyridyl)‐4,4,5,5‐ tetramethyl‐imidazoline‐1‐oxyl‐3‐oxide) has been synthesized and structurally characterized. The structure consists of neutral Ni(salox) 2…
In the title compound, [Cu(C44H28N4)], the copper ion is located at the center of the centrosymmetric and perfectly planar porphyrin ring.
Frozen solutions of the single molecule magnet ${\mathrm{Mn}}_{12}\mathrm{Piv}$ ($\mathrm{Piv}=\text{pivalate}$ or trimethylacetate) are studied by magnetization and magnetic resonance investigations. ac magnetic susceptibility measurements show that the system is stable in solution. Interestingly, the barrier and pre…