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300 K Ferromagnetic Magnetic Circular Dichroism in Co2+-doped ZnO Activated by Shallow Donors

Kevin R. Kittilstved、Jialong Zhao、William K. Liu 等 5 位作者2005-07-05arXiv

Cobalt-doped ZnO (Co2+:ZnO) films were studied by magnetic circular dichroism (MCD) spectroscopy. A broad 300 K ferromagnetic MCD signal was observed between 1.4 and 4.0 eV after introducing shallow donor states by exposure of paramagnetic Co2+:ZnO films to zinc vapor. The new sub-bandgap ferromagnetic MCD intensity i…

Materials Science

Vibrational effects in the linear conductance of carbon nanotubes

M Gheorghe、R Gutiérrez、N Ranjan 等 6 位作者2005-07-05Europhysics Letters (EPL)

We study the influence of structural lattice fluctuations on the elastic electron transport in single-wall carbon nanotubes within a density-functional-based scheme. In the linear-response regime, the linear conductance is calculated via configurational averages over the distorted lattice. Results obtained from a froz…

Carbon Nanotubes in CompositesMolecular Junctions and NanostructuresAdvanced Physical and Chemical Molecular Interactions

Variational study of triangular lattice spin-1∕2model with ring exchanges and spin liquid state inκ−(ET)2Cu2(CN)3

Olexei I. Motrunich2005-07-05arXiv

We study triangular lattice spin-$1∕2$ system with antiferromagnetic Heisenberg and ring exchanges using variational approach focusing on possible realization of spin-liquid states. Trial spin liquid wave functions are obtained by Gutzwiller projection of fermionic mean-field states and their energetics is compared ag…

Organic and Molecular Conductors ResearchPhysics of Superconductivity and MagnetismMagnetism in coordination complexes

Martensitic transitions and the nature of ferromagnetism in the austenitic and martensitic states ofNi−Mn−Snalloys

Thorsten Krenke、M. Acet、E. F. Wassermann 等 6 位作者2005-07-05OpenAlex

Structural and magnetic transformations in the Heusler-based system ${\mathrm{Ni}}_{0.50}{\mathrm{Mn}}_{0.50\ensuremath{-}x}{\mathrm{Sn}}_{x}$ are studied by x-ray diffraction, optical microscopy, differential scanning calorimetry, and magnetization. The structural transformations are of austenitic-martensitic charact…

Shape Memory Alloy TransformationsTitanium Alloys Microstructure and PropertiesHeusler alloys: electronic and magnetic properties

Resonant enhancement of third‐order nonlinear optical property in J‐like aggregates of a cyanine dye

Zhongyu Li、Zhaohui Jin、Kazuo Kasatani 等 5 位作者2005-07-04physica status solidi (b)

Abstract The wavelength dependence of the third‐order optical nonlinearity and response of the J‐like aggregates of a cyanine dye called NK‐3261 in a neat film were measured by the femtosecond degenerate four‐wave mixing (DFWM) technique under resonant conditions. The temporal profile of the DFWM signal of NK‐3261 J‐l…

Nonlinear Optical Materials ResearchNonlinear Optical Materials StudiesProtein Interaction Studies and Fluorescence Analysis

Novel Chiral (Salen)MnIII Complexes Containing a Calix[4]arene Unit as Catalysts for Enantioselective Epoxidation Reactions of (Z)‐Aryl Alkenes

Maria E. Amato、Francesco P. Ballistreri、Andrea Pappalardo 等 6 位作者2005-07-04European Journal of Organic Chemistry

Abstract New asymmetric (salen)Mn III and UO 2 complexes containing a calix[4]arene unit in the ligand framework were synthesized. The UO 2 complexes were characterized by 1 H‐, 13 C‐, 2D TOCSY and T‐ROESY NMR spectroscopy. Furthermore, the structure of one UO 2 complex was determined by single‐crystal X‐ray analysis.…

Lanthanide and Transition Metal ComplexesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Synthesis of a Bisphthalocyanine and Its Nonlinear Optical Properties

Mário J. F. Calvete、Danilo Dini、Steven R. Flom 等 6 位作者2005-07-04European Journal of Organic Chemistry

Abstract The synthesis and the nonlinear optical properties of an axially substituted binuclear InCl/InCl phthalocyanine 1 with an unsymmetrical substitution pattern are described. The preparation of this new type of binuclear phthalocyanine has been carried out through a multi‐step synthetic strategy, which was speci…

Porphyrin and Phthalocyanine ChemistryNonlinear Optical Materials StudiesNonlinear Optical Materials Research

Synthesis and Characterisation of Monodisperse Zirconia Particles

J. Widoniak、S. Eiden‐Assmann、G. Maret2005-07-04European Journal of Inorganic Chemistry

Abstract Monodisperse spherical ZrO 2 particles were prepared by controlled hydrolysis of zirconium tetraalkoxide in alcoholic solution. Ageing the reaction solution at 60 °C for 4 h yields particles with sizes in the range between 200 and 2000 nm. The influence of various ions and surfactants on the final product was…

Catalysis and Hydrodesulfurization StudiesMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Phase-field models for free-boundary problems

Thierry Biben2005-07-04European Journal of Physics

Phase-field models are very attractive in view of their numerical simplicity. With only a few lines of code, one can model complex physical situations such as dendritic growth. From this point of view, they constitute very interesting tools for teaching purposes at graduate level. The main difficulty with these models…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaFluid Dynamics and Thin Films

New Organic Dispersions of Conducting Polymers Using Polymeric Ionic Liquids as Stabilizers

Rebeca Marcilla、Estíbalitz Ochoteco、Cristina Pozo‐Gonzalo 等 6 位作者2005-07-04Macromolecular Rapid Communications

Abstract Summary: Polypyrrole (PPy), polyaniline (PANI), and poly(ethylenedioxythiophene) (PEDOT) aqueous dispersions were prepared by polymerizing the corresponding monomer in the presence of a polymeric ionic liquid (PIL), poly(1‐vinyl‐3‐ethylimidazolium bromide). By addition of bispentafluoroethanesulfonimide lithi…

Conducting polymers and applicationsElectrochemical sensors and biosensorsAnalytical Chemistry and Sensors

Influence of 2‐Aminopyridine on the Formation of Molybdates under Hydrothermal Conditions

K. Pavani、Arunachalam Ramanan2005-07-04European Journal of Inorganic Chemistry

Abstract The hydrothermal reaction of an aqueous ammonium heptamolybdate solution with first‐row transition metal salts in the presence of 2‐aminopyridine at around 180 °C and under autogenous pressure yields several molybdates, such as the 1D chains in (C 5 N 2 H 7 ) 4 Mo 8 O 26 ( 1 ), zero‐dimensional (C 5 N 2 H 7 )…

Polyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and Characterization

Ferromagnetism and possible heavy fermion behavior in single crystals of NdOs$_4$Sb$_{12}$

P. -C. Ho、W. M. Yuhasz、N. P. Butch 等 11 位作者2005-07-04arXiv

Single crystals of the filled-skutterudite compound NdOs$_4$Sb$_{12}$ have been investigated by means of electrical resistivity, magnetization, and specific heat measurements. The NdOs$_4$Sb$_{12}$ crystals have the LaFe$_4$P$_{12}$-type cubic structure with a lattice parameter of 9.3 Å. Possible heavy-fermion behavio…

Materials ScienceStrongly Correlated Electrons

Effect of La Doping on Microstructure and Critical Current Density of MgB2

Chandra Shekhar、Rajiv Giri、R S Tiwari 等 6 位作者2005-07-04arXiv

In the present study, La-doped MgB_2 superconductors with different doping level (Mg1-xLaxB2; x=0.00, 0.01, 0.03 & 0.05) have been synthesized by solid-state reaction route at ambient pressure. Effect of La doping have been investigated in relation to microstructural characteristics and superconducting properties, par…

Materials ScienceSuperconductivity

Design and Application of Self‐Assembled Low Molecular Weight Hydrogels

Maaike de Loos、Ben L. Feringa、Jan H. van Esch2005-07-04OpenAlex

Abstract Over the past years, the gelation of aqueous solutions by low molecular weight (LMW) compounds has become an area of increasing interest, owing to developments in the field of LMW organogelators. Until recently, LMW hydrogelators were found only by serendipity, nowadays rational design as well as application…

Supramolecular Self-Assembly in MaterialsHydrogels: synthesis, properties, applicationsCarbohydrate Chemistry and Synthesis

Poly(lactide) Stereocomplexes: Formation, Structure, Properties, Degradation, and Applications

Hideto Tsuji2005-07-04OpenAlex

Poly(lactide)s [i.e. poly(lactic acid) (PLA)] and lactide copolymers are biodegradable, compostable, producible from renewable resources, and nontoxic to the human body and the environment. They have been used as biomedical materials for tissue regeneration, matrices for drug delivery systems, and alternatives for com…

biodegradable polymer synthesis and propertiesBiopolymer Synthesis and ApplicationsAdvanced Polymer Synthesis and Characterization

Identifying and Engineering Ion Pairs in Adenylate Kinases

Euiyoung Bae、George N. Phillips2005-07-03Journal of Biological Chemistry

Molecular dynamics simulations were performed to study thermal stabilization of proteins via electrostatic interactions of ion pairs. Dynamic motions of four ion pairs previously proposed to be important in thermal stability of adenylate kinase from the thermophile Bacillus stearothermophilus were monitored during the…

Protein Structure and DynamicsMass Spectrometry Techniques and ApplicationsEnzyme Structure and Function

Hydrothermal Deposition of 〈001〉 Oriented Epitaxial Pb(Zr,Ti)O3 Films under Varying Hydrodynamic Conditions

Wojciech L. Suchanek、Małgorzata M. Łencka、L. E. McCandlish 等 8 位作者2005-07-02Crystal Growth & Design

The influence of the hydrodynamic effects of fluid flow on the hydrothermal deposition of 〈001〉 oriented epitaxial Pb(Zr 0.7 Ti 0.3 )O 3 (PZT) thin films onto single-crystal SrTiO 3 (100) substrates was investigated. The films were grown at 150 °C from lead acetate, zirconyl chloride, and titanium dioxide precursors a…

Microwave Dielectric Ceramics SynthesisElectronic and Structural Properties of OxidesFerroelectric and Piezoelectric Materials

Fibrous Assemblies and Water Gelation in Mixtures of Lysine with Sodium Alkyl Sulfates

Yamaira I. González、Eric W. Kaler2005-07-02Langmuir

Thermoresponsive, pH-sensitive fibrous structures and gels are formed in aqueous mixtures of the amino acid lysine with oppositely charged sodium alkyl sulfate surfactants. The formation of these assemblies depends on the chain length of the surfactant, which is varied between 8 and 16, the chirality and degree of pro…

Surfactants and Colloidal SystemsSupramolecular Self-Assembly in MaterialsLipid Membrane Structure and Behavior

Effect of Acoustic Standing Wave in a Bubble Column

Joline M. Fan、Zhe Cui2005-07-02Industrial & Engineering Chemistry Research

Experiments using nickel magnetostrictive oscillators as transducers that generate acoustic standing waves in a bubble column were conducted in this study. The acoustic frequencies employed are 16 and 20 kHz with power up to 400 W. The column is operated at a constant room temperature, with the heat generated from aco…

Microfluidic and Bio-sensing TechnologiesUltrasound and Cavitation PhenomenaFluid Dynamics and Mixing