Materials Literature
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The geometry of mononuclear copper(II) superoxide complexes has been shown to determine their ground state where side-on bonding leads to a singlet ground state and end-on complexes have triplet ground states. In an apparent contrast to this trend, the recently synthesized (HIPT3tren)Cu(II)O2(•-) (1) was proposed to h…
A fluorene-bridged squaraine dimer (SD-FLU-SD) was designed with the purpose of combining various chromophores in one molecule and enhancing its two-photon absorption properties using intra- and interchromophore transitions. Linear and nonlinear absorption properties of SD-FLU-SD were investigated with the goals of un…
Summary Large surface areas covered with man‐made materials are subject to pedogenetic evolution. However, pedogenetic processes in the resulting Technosols are seldom fully assessed. This work was conducted to identify and characterize the processes occurring on deposits of industrial technogenic materials. A former…
Functional scaffolds that could mimic cells' natural growth state in vitro are crucial for meeting the requirements of complex biological systems. However, the compact macrostructure and poor cell survival macro-environment of biomaterials are still two major challenges limiting their practical applications in bone ti…
An analytical method for diffraction of a plane electromagnetic wave at a periodically modulated graphene sheet is presented. Both interface corrugation and a periodic change in the optical conductivity are considered. Explicit expressions for reflection, transmission, absorption and transformation coefficients in arb…
The excitation of the surface plasmon resonances on a graphene strip and a disk in free space is studied numerically as a 2D and 3D electromagnetic wave-scattering problem, respectively. The associated mathematical model is based on the Maxwell equations with resistive boundary conditions on the surface of a zero-thic…
OBJECTIVES: Collagen barrier membranes are used in guided bone regeneration/guided tissue regeneration because of their excellent bio- and cytocompatibility. However, they are considered to have limitations in clinical outcome because of rapid and unpredictable degradation profiles. The aim of this study was to invest…
Direct production of hydrogen from water and sunlight requires stable and abundantly available semiconductors with well positioned band edges relative to the water red-ox potentials. We have used density functional theory (DFT) calculations to investigate 300 oxides and oxynitrides in the Ruddlesden–Popper phase of th…
In this study, the response of different filler loadings (5–20 wt%) of zinc oxide nanoparticles reinforced ultra-high molecular weight polyethylene on the mechanical, tribological and antibacterial performances were attempted. The compression, tensile and micro-hardness properties of the nano-zinc oxide/ultra-high mol…
Using calibrated FRET, we show that the simultaneous occupancy of both rings of GroEL by ATP and GroES occurs, leading to the rapid formation of symmetric GroEL:GroES2 "football" particles regardless of the presence or absence of substrate protein (SP). In the absence of SP, these symmetric particles revert to asymmet…
The complex kinetics of Pi and ADP release by the chaperonin GroEL/GroES is influenced by the presence of unfolded substrate protein (SP). Without SP, the kinetics of Pi release are described by four phases: a "lag," a "burst" of ATP hydrolysis by the nascent cis ring, a "delay" caused by ADP release from the nascent…
We study the variation of the dielectric response of ionic aqueous solutions as function of their ionic strength. The effect of salt on the dielectric constant appears through the coupling between ions and dipolar water molecules. On a mean-field level, we account for any internal charge distribution of particles. The…
To explore the binding mechanism of phthalate plasticizers with digestive proteases, their effects on conformation and activity of pepsin by multispectroscopic approach and molecular modeling were investigated. Fluorescence spectra combined with UV-vis and circular dichroism (CD) spectra measurements indicated that th…
Modification of nanoscale surface topography is inherent to low-energy ion beam erosion processes and is one of the most important fields of nanotechnology. In this report a comprehensive study of surface smoothing and self-organized pattern formation on Ge(100) by using different noble gases ion beam erosion is prese…
The selective synthesis and in situ characterization of aqueous Al-containing clusters is a long-standing challenge. We report a newly developed integrated platform that combines (i) a selective, atom-economical, step-economical, scalable synthesis of Al-containing nanoclusters in water via precision electrolysis with…
Belite calcium sulfoaluminate (BCSA) cements are low-CO 2 building materials. However, their hydration behavior and its effect on mechanical properties have still to be clarified. Here, we report a full multitechnique study of the hydration behavior up to 120 days of nonactivated and activated BCSA laboratory-prepared…
First measurements of the self-dynamics of liquid water in the GPa range are reported. The GPa range has here become accessible through a new setup for the Paris-Edinburgh press specially conceived for quasielastic neutron scattering studies. A direct measurement of both the translational and rotational diffusion coef…
Summary Because of the important role of soil organic carbon ( SOC ) in nutrient cycling and global climate changes, there has been an interest in understanding how different fertilizer practices affect the SOC preservation and promotion. The results from this study showed that long‐term application of manure (21 year…
The protonation–reduction of a dioxygen adduct with [LCu(I)][B(C6F5)4], cupric superoxo complex [LCu(II)(O2(•–))]+ (1) (L = TMG3tren (1,1,1-tris[2-[N(2)-(1,1,3,3-tetramethylguanidino)]ethyl]amine)) has been investigated. Trifluoroacetic acid (HOAcF) reversibly associates with the superoxo ligand in ([LCu(II)(O2(•–))]+…
Herein, we present a detailed study of the structure-function relationship in the organic photovoltaic (OPV) blend film composed of N,N'-bis(1-ethylpropyl)-perylene-3,4,9,10-tetracarboxylic diimide (EP-PDI) and the low energy gap copolymer of poly[4,8-bis-substituted-benzo[1,2-b:4,5-b']dithiophene-2,6-diyl-alt-4-subst…