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Connection between Thermodynamics and Dynamics of Simple Fluids in Highly Attractive Pores

William P. Krekelberg、Daniel W. Siderius、Vincent K. Shen 等 5 位作者2013-10-25Langmuir

Using molecular simulations, we investigate the structural and diffusive dynamics properties of a model fluid in highly absorptive cylindrical pores. At subcritical temperatures, self-diffusivity displays three distinct regimes as a function of average pore density ρ: (1) a decrease in self-diffusivity with increasing…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesCarbon Dioxide Capture Technologies

High rate capacity retention of binder-free, tin oxide nanowire arrays using thin titania and alumina coatings

Tu Quang Nguyen、Arjun Thapa、Venkat Kalyan Vendra 等 6 位作者2013-10-25RSC Advances

This paper reports the use of thin titania or alumina coatings on tin oxide nanowire arrays for high cyclability electrodes for lithium-ion batteries. We demonstrate that such coatings can significantly reduce irreversible capacity loss associated with the formation of a solid electrolyte interface and improve the cap…

Advancements in Battery MaterialsZnO doping and propertiesSemiconductor materials and devices

Silica coating of the pore walls of a microporous polycaprolactone membrane to be used in bone tissue engineering

Bermali Demirdögen、Clara Eugenia Plazas Bonilla、Sara Trujillo 等 7 位作者2013-10-25Journal of Biomedical Materials Research Part A

Polycaprolactone/silica microporous hybrid membranes were produced in two steps: A microporous polycaprolactone membrane with an interconnected porosity of 80% was obtained via a freeze extraction procedure, then silica was formed by a sol-gel reaction inside the micropores using tetraethyl orthosilicate, TEOS, as sil…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Living-Engineered Valves for Transcatheter Venous Valve Repair

Benedikt Weber、Jérôme Robert、Agnieszka Książek 等 13 位作者2013-10-25Tissue Engineering Part C Methods

BACKGROUND: Chronic venous insufficiency (CVI) represents a major global health problem with increasing prevalence and morbidity. CVI is due to an incompetence of the venous valves, which causes venous reflux and distal venous hypertension. Several studies have focused on the replacement of diseased venous valves usin…

Cardiac Valve Diseases and TreatmentsElectrospun Nanofibers in Biomedical ApplicationsDiagnosis and Treatment of Venous Diseases

The role of Homer1c in metabotropic glutamate receptor-dependent long-term potentiation

Kenneth J. O’Riordan、Hilary Gerstein、Rikki Hullinger 等 4 位作者2013-10-25Hippocampus

Group I metabotropic glutamate receptors (mGluR1/5) play a role in synaptic plasticity and they demonstrate direct interactions with the neuronal Homer1c protein. We have previously shown that Homer1c can restore the plasticity deficits in Homer1 knockout mice (H1-KO). Here, we investigated the role of Homer1c in mGlu…

Neuroscience and Neuropharmacology ResearchMemory and Neural MechanismsPhotochromic and Fluorescence Chemistry

Post-Buckling Analysis of Functionally Graded Three-Dimensional Beams Under the Influence of Temperature

Şeref Doğuşcan Akbaş、Turgut Kocatürk2013-10-25Journal of Thermal Stresses

In this study, post-buckling behavior of functionally graded beams under the influence of temperature loading is investigated by using total Lagrangian finite element model of three-dimensional continuum approximations. Material properties of the beam are both temperature-dependent and position-dependent. In this stud…

Composite Structure Analysis and OptimizationStructural Load-Bearing AnalysisNonlocal and gradient elasticity in micro/nano structures

Bulk evidence for a time-reversal symmetry broken superconducting state in URu 2 Si 2

Gang Li、Q. Zhang、Daniel Rhodes 等 11 位作者2013-10-25Physical Review B

URu${}_{2}$Si${}_{2}$ is claimed to be a chiral $d$-wave superconductor with a ${k}_{z}({k}_{x}\ifmmode\pm\else\textpm\fi{}i{k}_{y})$ time-reversal symmetry broken orbital component for the Cooper pair wave function, which contains both nodal points and lines of nodes. To study the magnetic response of such an unconve…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Development of poly( N -isopropylacrylamide)/alginate copolymer hydrogel-grafted fabrics embedding of berberine nanosuspension for the infected wound treatment

He Xu、Xudong Yuan、Baode Shen 等 10 位作者2013-10-25Journal of Biomaterials Applications

In the present study, a novel hydrogel-grafted fabrics embedding of berberine nanosuspension was developed for the treatment of infected wound. Hydrogel-grafted fabric was prepared by graft copolymerization of N-isopropylacrylamide and alginate using ceric ammonium nitrate as initiator. Berberine nanosuspension was pr…

Hydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical ApplicationsWound Healing and Treatments

Effects of disorder on Coulomb-assisted braiding of Majorana zero modes

Ion Cosma Fulga、Bernard van Heck、Michele Burrello 等 4 位作者2013-10-25Physical Review B

Majorana zero modes in networks of one-dimensional topological superconductors obey non-Abelian braiding statistics. Braiding manipulations can be realized by controlling Coulomb couplings in hybrid Majorana-transmon devices. However, strong disorder may induce accidental Majorana modes, which are expected to have det…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Design of Olanzapine/Lutrol Solid Dispersions of Improved Stability and Performances

Cristina Cavallari、Adamo Fini、G. C. Ceschel2013-10-25Pharmaceutics

Eleven solid dispersions containing olanzapine, with carriers of different composition (Lutrol® F68, Lutrol® F127, Gelucire® 44/14), were prepared and examined by thermal (differential scanning calorimetry (DSC); thermomicroscopy (HSM)) and X-ray diffraction (XRD) analysis, both as fresh or aged (one year) samples. Dr…

Drug Solubulity and Delivery SystemsAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

Decolorization of Crystal Violet by ultrasound/heterogeneous Fenton process

Hui Zhang、Hong Gao、Chun Cai 等 5 位作者2013-10-25Water Science & Technology

Activated-carbon-supported iron oxides were prepared and used as a catalyst in an integrated ultrasound/heterogeneous Fenton process for the decolorization of Crystal Violet. A synergistic effect was observed when ultrasound was combined with the heterogeneous Fenton process. The decolorization efficiency increased wi…

Advanced oxidation water treatmentUltrasound and Cavitation Phenomena

Optimization Studies of Photocatalytic Tungsten-Doped Titania Coatings Deposited by Reactive Magnetron Co-Sputtering

Marina Ratova、Glen West、Peter Kelly2013-10-25Coatings

In this article we investigate the structural and photocatalytic properties of W-doped titanium dioxide coatings. TiO2-W thin films were deposited onto glass slides by reactive magnetron co-sputtering. The properties of the films were analyzed using such techniques as XRD, Raman spectroscopy, EDX, TEM, and surface pro…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

Achiral Metastable Crystals of Sodium Chlorate Forming Prior to Chiral Crystals in Solution Growth

Hiromasa Niinomi、Tomoya Yamazaki、Shunta Harada 等 9 位作者2013-10-25Crystal Growth & Design

Chiral symmetry breaking in NaClO 3 crystallization from an aqueous solution with perturbations has been of great interest. To understand the mechanism, several models focusing on the early stage of the crystallization have been proposed. However, they are ambiguous because the early stage has been barely explored dir…

Spectroscopy and Quantum Chemical StudiesOrigins and Evolution of LifeCrystallization and Solubility Studies

Pressure Dependence of Acoustic Properties of Liquid Ethanol by using High-pressure Brillouin Spectroscopy

Jae‐Hyeon Ko、Minseok Jeong、Byoung Wan Lee 等 9 位作者2013-10-25한국광학회지

Brillouin spectroscopy has been widely used for the investigation of acoustic properties of condensed matters in the hypersonic region. A high-pressure Brillouin spectrometer was set up by combining a diamond anvil cell and a tandem multi-pass Fabry-Perot interferometer. It was successfully applied to liquid ethanol,…

Material Dynamics and PropertiesSpectroscopy and Quantum Chemical StudiesMechanical and Optical Resonators

“Donor–Acceptor” Oligogermanes: Synthesis, Structure, and Electronic Properties

Kirill V. Zaitsev、Andrey A. Kapranov、Andrei V. Churakov 等 8 位作者2013-10-25Organometallics

A series of oligogermanes, (Me 3 Si) 3 GeGeCl 3, (C 6 F 5 ) 3 GeGePh 3, (C 6 F 5 ) 3 GeGe( p -Tol) 3, and (C 6 F 5 ) 2 Ge[Ge( p -Tol) 3 ] 2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and…

Synthesis and characterization of novel inorganic/organometallic compoundsSilicone and Siloxane ChemistryOrganometallic Compounds Synthesis and Characterization

Pattern-integrated interference lithography: Vector modeling and 1D, 2D, and 3D device structures

Matthieu C. R. Leibovici、Thomas K. Gaylord2013-10-25Journal of Vacuum Science & Technology B Nanotechnology and Microelectronics Materials Processing Measurement and Phenomena

Multibeam interference lithography (MBIL) represents a versatile, wafer-scale, rapid, and cost-effective fabrication technique for periodic-based microstructures. However, integrating arbitrary and nonperiodic functional elements within an MBIL-defined lattice typically requires an additional time-consuming step. To a…

Photonic Crystals and ApplicationsOptical Coatings and GratingsNanofabrication and Lithography Techniques

Bright Cathodoluminescent Thin Films for Scanning Nano-Optical Excitation and Imaging

David M. Kaz、Connor G. Bischak、Craig L. Hetherington 等 12 位作者2013-10-25ACS Nano

Demand for visualizing nanoscale dynamics in biological and advanced materials continues to drive the development of subdiffraction optical probes. While many strategies employ scanning tips for this purpose, we instead exploit a focused electron beam to create scannable nanoscale optical excitations in an epitaxially…

Quantum Dots Synthesis And PropertiesMolecular Junctions and NanostructuresNear-Field Optical Microscopy

Realizing vertical light coupling and splitting in nano-plasmonic multilevel circuits

Mohamed H. El Sherif、Osman Ahmed、Mohamed H. Bakr 等 4 位作者2013-10-25Optics Express

We present a novel technique for vertical coupling of light guided by nanoscale plasmonic slot waveguides (PSWs). A triangularly-shaped plasmonic slot waveguide rotator is exploited to attain such coupling with a good efficiency over a wide bandwidth. Using this approach, light propagating in a horizontal direction is…

Plasmonic and Surface Plasmon ResearchPhotonic and Optical DevicesOptical Coatings and Gratings

Solubilizing the Most Easily Ionized Molecules and Generating Powerful Reducing Agents

Gina M. Chiarella、F. Albert Cotton、Jason C. Durivage 等 5 位作者2013-10-25Journal of the American Chemical Society

Two very soluble compounds having W2(bicyclic guanidinate)4 paddlewheel structures show record low ionization energies (onsets at 3.4 to 3.5 eV) and very negative oxidation potentials in THF (-1.84 to -1.90 V vs Ag/AgCl). DFT computations show the correlation from the gas-phase ionization energies to the solution redo…

Electrocatalysts for Energy ConversionPolyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysis