Materials Literature
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This work presents a novel method to synthesize p-type composite thermoelectric materials to print scalable thermoelectric generator (TEG) devices in a cost-effective way. A maximum ZT of 0.2 was achieved for mechanically alloyed (MA) p-type Bi0.5Sb1.5Te3 (8 wt % extra Te additive)-epoxy composite films cured at 250 °…
International simple glass (ISG) is a six‐component alumino‐borosilicate glass developed as a reference benchmark glass for six nations collaborating study on high‐level nuclear waste glass dissolution/corrosion mechanism. In this study, aqueous dissolution tests were performed for the ISG using microchannel flow‐thro…
The new pyrazolate-bridged proligand 4-methyl-3,5-bis{6-(2,2'-bipyridyl)}pyrazole ((Me)LH) has been synthesized. Similar to its congener that lacks the backbone methyl substituent ((H)LH) it forms a robust Fe(II)4 grid complex, [(Me)L4Fe(II)4](BF4)4. The molecular structure of [(Me)L4Fe(II)4](BF4)4·2MeCN has been eluc…
This paper presents a type of isotropic broadband metamaterial absorber comprising single-layer densely arranged hexagonal metal dendritic units having different sizes printed on an FR-4 dielectric substrate with a metallic film coating. The convergence of the different neighboring resonant frequencies of the differen…
Large databases of chemical reactions provide new data-mining opportunities and challenges. Key challenges result from the imperfect quality of the data and the fact that many of these reactions are not properly balanced or atom-mapped. Here, we describe ReactionMap, an efficient atom-mapping algorithm. Our approach u…
We present tight-binding calculations in the random-phase approximation of the optical response of Silicon nanocrystals (Si NCs) ideally doped with large concentrations of phosphorus (P) atoms. A collective response of P-induced electrons is demonstrated, leading to localized surface plasmon resonance (LSPR) when a Si…
Mesoporous CuO–NiO micropolyhedrons were fabricated via a facile, environmentally friendly, and scalable synthetic route for high-performance supercapacitors. The morphology and structure of CuO–NiO composites can be well tailored by tuning the molar ratio of Cu to Ni and processing temperature. The CuO–NiO micropolyh…
The buckling problem of linearly tapered micro-columns is investigated on the basis of modified strain gradient elasticity theory. Bernoulli-Euler beam theory is used to model the non-uniform micro column. Rayleigh-Ritz solution method is utilized to obtain the critical buckling loads of the tapered cantilever micro-c…
Specific bioprobes that are capable of real-time and targeted monitoring and imaging of cancer cell apoptosis are highly desirable for cancer diagnosis and the evaluation of cancer therapy efficacy. In this work, an asymmetric fluorescent light-up bioprobe with aggregation-induced emission (AIE) characteristics was de…
Concave nanoparticles (NPs) with complex angled and non‐Platonic geometries have unique optical, magnetic, catalytic, and biological properties originating from the singularities of the electrical field in apexes and craters. Preparation of such particles with a uniform size/shape and core–shell morphology represents…
Near-infrared (NIR) fluorescence signals are highly desirable to achieve high resolution in biological imaging. To obtain NIR emission with high brightness, fluorescent nanoparticles (NPs) are synthesized by co-encapsulation of 2,3-bis(4-(phenyl(4-(1,2,2-triphenylvinyl)phenylamino)phenyl)fumaronitrile (TPETPAFN), a lu…
Epitaxial tetragonal 425 and 611 nm thick Pb(Zr 0.45 Ti 0.55 )O 3 (PZT) films are deposited by pulsed laser deposition on SrRuO 3 ‐coated (100) SrTiO 3 24° tilt angle bicrystal substrates to create a single PZT grain boundary with a well‐defined orientation. On either side of the bicrystal boundary, the films show squ…
Ternary mixtures of medium-chain fatty alcohols, water and a hydrotrope (such as ethanol), near the immiscibility gap, make stable single phases at constant temperature. Interestingly, in this `pre-ouzo region' these single phases consist of two distinct nanoscopic pseudo-phases, one octanol-rich and one water-rich. T…
Thermal management of polymeric composites is a crucial issue to determine the performance and reliability of the devices. Here, we report a straightforward route to prepare polymeric composites with Cu thin film networks. Taking advantage of the fluidity of polymer melt and the ductile properties of Cu films, the pol…
Mercerized fibers were prepared from native cotton fabrics via NaOH solution treatment at different concentrations. Mercerization led to transformation of the crystal structure of cotton fibers from cellulose I to II when the NaOH concentration was greater than 10 wt%. In addition, the cotton fibers were converted int…
The oxygen adsorption and dissociation on pristine silicene surface are studied by use of first-principles in this letter. The oxygen adsorption and dissociation on pristine silicene surface are studied by use of first-principles in this letter. It is found that the pristine silicene is not stable in air because the o…
Condensation is a common phenomenon and is widely exploited in power generation and refrigeration devices. Although drop‐wise condensation offers high heat and mass transfer rates, it is extremely difficult to maintain and control. In this study, the ability to spatially control heterogeneous nucleation on a superhydr…
A novel catalytic property of nanoporous gold for activation of bis(pinacolato)diboron has been reported that allows the direct diboration of alkynes to proceed sufficiently in a heterogeneous process. The experimental results revealed that the nanoporous gold catalyst is able to cleave the B-B bond of bis(pinacolato)…
The binary compounds FeSi, RuSi, and OsSi are chiral insulators crystallizing in the space group P2_13 which is cubic. By means of ab initio calculations we find for these compounds a non-vanishing electronic Berry phase, the sign of which depends on the handedness of the crystal. There is thus the possibility that th…
We present a theoretical study of dispersion of states that form the bulk band-gap edges in the three-dimensional topological insulator Bi${}_{2}$Te${}_{3}$. Within density functional theory, we analyze the effect of atomic positions varied within the error range of the available experimental data and approximation ch…