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High-Performance UV Photodetection of Unique ZnO Nanowires from Zinc Carbonate Hydroxide Nanobelts

Lu Ren、Tingting Tian、Yuanzhi Li 等 5 位作者2013-05-23ACS Applied Materials & Interfaces

Zinc carbonate hydroxide nanobelts are prepared by the hydrolysis of zinc acetate aqueous solution in the presence of urea at 90 °C. The zinc carbonate hydroxide nanobelts can be facilely self-assembled in a circular flexible freestanding film with a diameter of 8.4 cm and thickness of ~48 μm. The calcination of the z…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Amphiphilic hyperbranched polymers from the copolymerization of a vinyl and divinyl monomer: The potential of catalytic chain transfer polymerization

Niels M. B. Smeets2013-05-23European Polymer Journal

This feature article focuses on the synthesis of amphiphilic hyperbranched polymers. There is a growing interest in the properties of these nanostructured materials and the copolymerization of a vinyl and divinyl monomer in the presence of a chain transfer agent, provides a simple, versatile and scalable synthesis rou…

Advanced Polymer Synthesis and CharacterizationClick Chemistry and ApplicationsDendrimers and Hyperbranched Polymers

The Effect of Carbon and Nitrogen Sources on Bacterial Cellulose Production and Properties from Gluconacetobacter sucrofermentans CECT 7291 Focused on its use in Degraded Paper Restoration

Sara M. Santos、José Ma Carbajo、Juan C. Villar2013-05-23BioResources

cellulose (BC) synthesized by Gluconacetobacter sucrofermentans has a high degree of crystallinity, durability, great resistance, and biocompatibility. This study evaluates the effect that carbon and nitrogen sources, present in HS (Hestrin-Schramm) culture medium, have on BC from G. sucrofermentans CECT 7291 used to…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesEnzyme-mediated dye degradation

Upward ferroelectric self-polarization induced by compressive epitaxial strain in (001) BaTiO3 films

Jiangpeng Chen、Ying Luo、Xin Ou 等 8 位作者2013-05-23Journal of Applied Physics

The (001) oriented epitaxial BaTiO3 thin films were grown on La0.7Sr0.3MnO3, SrRuO3, and Nb-SrTiO3 layers, respectively, and the inhomogeneous compressive strain is suggested to be the main origin of their upward self-polarization. The upward self-polarization exists in the thin BaTiO3 films with strong inhomogeneous…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

The dynamics of a non-dilute vesicle suspension in a simple shear flow

Hong Zhao、Eric S. G. Shaqfeh2013-05-23Journal of Fluid Mechanics

Abstract We simulate multivesicle suspensions undergoing simple shear deformation by using the Stokes-flow boundary-integral equation method to quantify the effect of vesicle–vesicle interactions on the microstructure and rheology of the suspension. The binary collisions between vesicles are found to cause a vesicle’s…

Material Dynamics and PropertiesRheology and Fluid Dynamics StudiesBlood properties and coagulation

Carrier Lifetime in Exfoliated Few-Layer Graphene Determined from Intersubband Optical Transitions

Thomas Limmer、Jochen Feldmann、Enrico Da Como2013-05-23Physical Review Letters

We report a femtosecond transient spectroscopy study in the near to middle infrared range, 0.8-0.35 eV photon energy, on graphene and few layer graphene single flakes. The spectra show an evolving structure of photoinduced absorption bands superimposed on the bleaching caused by Pauli blocking of the interband optical…

Graphene research and applicationsPlasmonic and Surface Plasmon ResearchMolecular Junctions and Nanostructures

A phase-field study on the hysteresis behaviors and domain patterns of nanocrystalline ferroelectric polycrystals

Ning Liu、Yu Su、George J. Weng2013-05-23Journal of Applied Physics

The overall hysteresis behavior of nanocrystalline ferroelectric polycrystals demonstrates unique characteristics against conventional ferroelectric ceramics. The existence of low-permittivity paraelectric grain boundary and its influence to the microstructure of grains can be a key factor leading to such characterist…

Ferroelectric and Piezoelectric MaterialsComposite Material MechanicsAdvanced Mathematical Modeling in Engineering

Driving Magnetostructural Transitions in Layered Intermetallic Compounds

Jianli Wang、L. Caron、S. J. Campbell 等 10 位作者2013-05-23Physical Review Letters

We report the dramatic effect of applied pressure and magnetic field on the layered intermetallic compound Pr(0.5)Y(0.5)Mn(2)Ge(2). In the absence of pressure or magnetic field this compound displays interplanar ferromagnetism at room temperature and undergoes an isostructural first order magnetic transition (FOMT) to…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsIron-based superconductors research

Electrically driven self-healing polymers based on reversible guest-host complexation of β-cyclodextrin and ferrocene

Tsai-Wei Chuo、Ta‐Chin Wei、Ying‐Ling Liu2013-05-23Journal of Polymer Science Part A Polymer Chemistry

A multifunctional ferrocene-modified poly(glycidyl methacrylate) (PGMA-Fc) and a difunctional β-cyclodextrin derivative (bis-CD) has been prepared for the construction of an electrically driven removable and self-healing polymeric materials based on the complexation reaction between ferrocene and β-CD groups. The chem…

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingPhotochromic and Fluorescence Chemistry

Nitrogen determination by SEM‐EDS and elemental analysis

M. F. Gazulla、Marta Rodrigo、E. Blasco 等 4 位作者2013-05-23X-Ray Spectrometry

This paper describes a methodology for the analysis of nitrogen by scanning electron microscope with an energy dispersive X‐ray spectrometer (SEM‐EDS). The methodology was developed to have a rapid and accurate alternative method to the elemental analysis by combustion and thermoconductivity detection that does not im…

X-ray Spectroscopy and Fluorescence AnalysisNuclear Physics and ApplicationsElectron and X-Ray Spectroscopy Techniques

Crystal and Crystallites Structure of Natural Rubber and Synthetic cis-1,4-Polyisoprene by a New Two Dimensional Wide Angle X-ray Diffraction Simulation Method. I. Strain-Induced Crystallization

Justin Che、Christian Bürger、Shigeyuki Toki 等 7 位作者2013-05-23Macromolecules

A novel two-dimensional simulation method to analyze a wide-angle X-ray diffraction (WAXD) pattern is applied to crystal and crystallites of strain-induced crystallization (SIC) of unvulcanized natural rubber (NR) and synthetic polyisoprene rubber (IR) at −50 °C. The unit cell dimensions of SIC were determined by calc…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesEpoxy Resin Curing Processes

Excitons and biexcitons in symmetric electron-hole bilayers

Ryo Maezono、Pablo López Ríos、Tetsuo Ogawa 等 4 位作者2013-05-23Physical Review Letters

Symmetric electron-hole bilayer systems have been studied at zero temperature using the diffusion quantum Monte Carlo method. A flexible trial wave function is used that can describe fluid, excitonic, and biexcitonic phases. We calculate condensate fractions and pair correlation functions for a large number of densiti…

Quantum and electron transport phenomenaMolecular Junctions and NanostructuresElectronic and Structural Properties of Oxides

Low-Temperature, Bottom-Up Synthesis of Graphene via a Radical-Coupling Reaction

Lang Jiang、Tianchao Niu、Xiuqiang Lu 等 8 位作者2013-05-23Journal of the American Chemical Society

In this article, we demonstrated a method to synthesize graphene films at low temperature via a mild radical-coupling reaction. During the deposition process, with the effectively breaking of the C-Br bonds of hexabromobenzene (HBB) precursors, the generated HBB radicals couple efficiently to form graphene films at th…

Carbon Nanotubes in CompositesGraphene research and applicationsMolecular Junctions and Nanostructures

Hybrid Hartree-Fock density functional study of charged point defects in ferroelectric PbTiO 3

Takahiro Shimada、Taku Ueda、Jie Wang 等 4 位作者2013-05-23Physical Review B

The nature of intrinsic point defects, i.e., energetic, ferroelectric, and electronic properties of vacancies in ferroelectric PbTiO${}_{3}$, is studied using first-principles calculations based on the hybrid Hartree-Fock density functional, which correctly reproduces the band gap and thus provides the accurate defect…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsElectronic and Structural Properties of Oxides

Tree Growth—Hybrid Genetic Algorithm for Predicting the Structure of Small (TiO 2 ) n , n = 2–13, Nanoclusters

Mingyang Chen、David A. Dixon2013-05-23Journal of Chemical Theory and Computation

The initial structures for the search for the global minimum of TiO2 nanoclusters were generated by combining a tree growth (TG) algorithm with a hybrid genetic algorithm (HGA). In the TG algorithm, the clusters grow from a small seed to the size of interest stepwise. New atoms are added to the smaller cluster from th…

Catalytic Processes in Materials ScienceQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Nanoscale control of Ag nanostructures for plasmonic fluorescence enhancement of near-infrared dyes

Fang Xie、Jing S. Pang、Anthony Centeno 等 6 位作者2013-05-23Nano Research

Potential utilization of proteins for early detection and diagnosis of various diseases has drawn considerable interest in the development of protein-based detection techniques. Metal induced fluorescence enhancement offers the possibility of increasing the sensitivity of protein detection in clinical applications. We…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNonlinear Optical Materials Studies

Multifunctional porous silicon nanopillar arrays: antireflection, superhydrophobicity, photoluminescence, and surface-enhanced Raman scattering

Brian Kiraly、Shikuan Yang、Tony Jun Huang2013-05-23Nanotechnology

We have fabricated porous silicon nanopillar arrays over large areas with a rapid, simple, and low-cost technique. The porous silicon nanopillars show unique longitudinal features along their entire length and have porosity with dimensions on the single-nanometer scale. Both Raman spectroscopy and photoluminescence da…

Quantum Dots Synthesis And PropertiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Origin of ferromagnetism in transition metal doped BaTiO3

Iliana N. Apostolova、A. Apostolov、Safa Golrokh Bahoosh 等 4 位作者2013-05-23Journal of Applied Physics

We have calculated the temperature, magnetic field, and ion doping dependence of the magnetic and electric properties in Fe-doped BaTiO3 using a microscopic model and the Green's function technique. It is shown that the ferromagnetic and multiferroic properties observed at room temperature in Fe doped BaTiO3 could be…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Photoinduced Underwater Superoleophobicity of TiO2 Thin Films

Yusuke Sawai、Shunsuke Nishimoto、Yoshikazu Kameshima 等 5 位作者2013-05-23Langmuir

The photoinduced wettabilities of water, n-hexadecane, dodecane, and n-heptane on a flat TiO2 surface prepared by a sol-gel method-based coating were investigated. An amphiphilic surface produced by UV irradiation exhibited underwater superoleophobicity with an extremely high static oil contact angle (CA) of over 160°…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrohydrodynamics and Fluid Dynamics

Superamphiphobic Surface by Nanotransfer Molding and Isotropic Etching

Sang Eon Lee、Han‐Jung Kim、Su-Han Lee 等 4 位作者2013-05-23Langmuir

We present a novel method of fabricating superhydrophobic and superoleophobic surfaces with nanoscale reentrant curvature by nanotransfer molding and controlled wet etching of the facile undercut. This method produces completely ordered re-entrant nanostructures and prevents capillary-induced bundling effects. The mus…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferAdhesion, Friction, and Surface Interactions