Materials Literature
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Spectral dip formation at arbitrary wavelengths and the corresponding multicolour changes were achieved by using plasmonic Au nanoparticles on TiO(2), based on plasmon-induced charge separation and a coordination effect of iodide ions. The dips were stable in air under white light, in marked contrast to the case of co…
Sequential sectioning and sequential imaging by scanning electron microscopy have been employed to obtain three‐dimensional images of an AA2024‐T3 aluminium alloy after exposure to sodium chloride solution. The three‐dimensional arrangement of intermetallic particles within the alloy was disclosed, indicating that gro…
Using combined X-ray diffraction and FTIR spectroscopy, a remarkable similarity is revealed between the local environments of trimesic acid in solution and in its most metastable trisolvate with DMSO. The implications of this for the nature of the nucleation process are discussed.
n-ZnO/p-Si heterojunction light emitting devices with and without a NiO intermediate layer were fabricated using a radio frequency magnetron sputtering system. Electroluminescence measurements revealed that the device with the NiO intermediate layer exhibits a sharper and stronger orange emission peaks at ∼670 nm comp…
Understanding the migration kinetics of radiation-induced point defects and defect clusters is key to predicting the microstructural evolution and mass transport in nuclear fuels. Although the diffusion kinetics of point defects in UO(2) is well explored both experimentally and theoretically, the kinetics of defect cl…
Unique one-dimensional cyanido-bridged {[EuIII(RR-Pri-Pybox)(dmf)4]3[WV(CN)8]3}n·dmf·8H2O (1-RR) and {[EuIII(SS-Pri-Pybox)(dmf)4]3[WV(CN)8]3}n·dmf·8H2O (1-SS) (Pri-Pybox = 2,2′-(2,6-pyridinediyl)bis(4-isopropyl-2-oxazoline)) chains were synthesized and characterized. They combine chiral helicity with paramagnetism and…
Abstract Poly( ϵ ‐caprolactone‐ co ‐ tert ‐butyl methacrylate) (CL‐ co ‐BMA) random copolymer is synthesized via hybrid copolymerization with 1‐ tert ‐butyl‐4,4,4‐tris(dimethylamino)‐2,2‐bis[tris(dimethylamino)phophoranylidenamino]‐2Λ5,4Λ5‐catenadi(phosphazene) ( t ‐BuP 4 ) as the catalyst. The copolymer is hydrolyzed…
Abstract Well‐defined, high‐density poly(2‐(2‐methoxyethoxy)ethyl methacrylate) [poly(MEO 2 MA)] brushes were fabricated through a reliable strategy by the combination of self‐assembly of a monolayer of 3‐aminopropyltrimethoxy silane on silicon surface to immobilize 4‐cyano‐4‐(dodecylsulfanylthiocarbonyl)sulfanyl pent…
Abstract The reaction of 4‐phenylimino‐1,2,4‐triazole ( 1 ) with Fe II , Co II , Ni II and Cu II thiocyanate produces a series of analogous dinuclear compounds of formula [M 2 ( 1 ) 5 (NCS) 4 ] ( 2 – 5 ) as demonstrated by single‐crystal X‐ray diffraction studies of the Fe II ( 2 ) and Co II ( 3 ) analogues. The magne…
A total of 10 three-dimensional chiral coordination compounds L- and D-[Ln(HCO(2))(SO(4))(H(2)O)](n) (Ln = La, Ce, Pr, Nd, and Eu) have been synthesized without any chiral auxiliary and characterized by IR, thermogravimetric, and elemental analyses. Their structures were determined by single-crystal X-ray structural a…
The thermal conductivity of porous ceramics can be tailored by slip casting and uniaxial dry pressing, using either fugitive pore formers (saccharides) or partial sintering. Porous alumina and zirconia ceramics have been prepared using appropriate powder types (ungranulated for casting, granulated for pressing) and id…
Cadmium selenide (CdSe) quantum dots have gained increased attention for their potential use in biomedical applications. This has raised interest in assessing their toxicity. In this study, water-soluble, cysteine-capped CdSe nanocrystals with an average size of 15 nm were prepared through a one-pot solution-based met…
Glycerol and glycerol/water solution were converted to syngas over Pt-, LaMnO 3 -, and Pt/LaMnO 3 -coated monoliths under autothermal partial oxidation. XRD and SEM were used to characterize the phase compositions and surface morphologies of freshly prepared and postreaction catalysts. A continuous fixed-bed design, w…
Iron oxide nanoparticles (IONP) are currently being studied as green magnet resonance imaging (MRI) contrast agents. They are also used in huge quantities for environmental remediation and water treatment purposes, although very little is known on the consequences of such applications for organisms and ecosystems. In…
The SiOx (SiOx:Si-QDs) with buried Si quantum dots (Si-QDs) is synthesized by plasma-enhanced chemical vapor deposition (PECVD), and the size-dependent wave-function of Si-QDs embedded in Si-rich SiO2 matrix is experimentally and theoretically analyzed to reformulate its bandgap energy as Eg(d) = 1.12+5.83/d1.78. The…
Elastohydrodynamic problems of decagonal quasicrystals are analysed where the phonon field obeys wave equation and the phason field obeys diffusive wave equation. Basic equations are solved in the quasiperiodic plane and periodic plane, respectively. Final governing equations of dynamic behaviours of decagonal quasicr…
The kinetics and mechanism of the full reduction of a thin RuO 2 film with a stoichiometric (110) surface on Ru(0001) by H 2 has been studied in the temperature range of 100 to 400 °C at 10 –2 to 10 –4 Pa. The reduction kinetics is dominated by the creation of oxygen vacancies and their annihilation upon transformatio…
Time-dependent density functional theory (TDDFT) within the random phase approximation (RPA) is used to obtain the time evolution of the induced potential produce by the sudden formation of a C 1s core hole inside a graphene monolayer, and to show how the system reaches the equilibrium potential. The characteristic os…
We demonstrate that polymer-grafted metal nanoparticles of various shapes and dimensions self-assemble into arrays of string-like superstructures upon phase separation within a matrix polymer. Interparticle orientation within these nanocomposites can be dictated by the chain length of the grafted polymer.
Ribbon-like supramolecular structures prepared by the organized aggregation of 4-aryl-4H-1,2,4-triazoles act as optical waveguides that propagate photoluminescence.