Materials Literature
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Tests were made of Kevlar® fiber blends of 5, 10, 15, and 20% with cotton. The processing efficiency of cotton/Kevlar blends compared favorably with that of blends of cotton with 15, 25, 35, and 50% of polyester or 15% nylon. Lower twists were required for yarns spun from the cotton/Kevlar blends for optimum strength,…
Helium permeability, diffusivity, and solubility have been measured for sodium, potassium, rubidium, and cesium germanate glasses, and for one series of sodium-potassium germanate glasses. In each case, the helium permeability and diffusivity exhibit minima in the property-composition curves. These minima shift to gre…
Single crystals of K 5 Nd(MoO 4 ) 4 were grown from the melt by the Czochralski method. Dielectric anomalies were observed in both ε a and ε c around 300–500°C. The maximum values of the dielectric constants and the corresponding temperature depend on frequency. The birefringence shows a small anomaly at 485°C. The ph…
The probelm of joining ODS alloys by welding for high temperature use has limited their application in industry. To date, all wedling processes employed have resulted in loss of dispersoid through agglomeration or slagging off and the development of grain boundaries perpendicular to the existing structure of the mater…
Specialized sulfur concretes were developed by the Federal Bureau of Mines as a result of research for the beneficial utilization of sulfur in construction materials. Materials were developed for use in acid and salt corrosive environments where portland cement concrete has been found to deteriorate. Because the miner…
In order to clarify the fluidity of interdendritic liquid contributing to the formation of macrosegregation and the castability in an ingot, an artificial hole was made in the zone of coexistence of the solid and the liquid so as to make only the liquid flow into the hole. Then the relation among the fluidity of the l…
Progress since 1955 in the technology of zirconium and its alloys is reviewed primarily from an applications viewpoint. A number of favorable features have been uncovered as their use broadened as well as problem areas which required accommodation in design or lifetime. Zirconium technology has reached its present sta…
Two methods are described for producing high-velocity liquid impacts. The first involves projecting a jet of liquid at a stationary target while in the second specimens are fired at suspended drops. An objective of the study was to place the jet method on a quantitative basis. Detailed studies of jets, using high-spee…
Abstract The ability of sodium molybdate to inhibit corrosion of mild steel is demonstrated using laboratory and field test data. Initial evidence is also presented indicating that molybdate inhibits the corrosion of copper and aluminium. Environmental aspects including fish toxicity data are discussed as is the likel…
Linear poly (ethylene glycol) (PEG) is able to complex with neutral molecular Iodine in the solution state and in solid state, to produce I− 3 ions detectable by conventional spectroscopy and by photoacoustic spectroscopy (PAS). This behavior of PEG is another instance of its ability to mimic the complexation features…
Abstract Polymer formation from THPOH‐urea, THPOH‐dichloropropanol‐urea, and THPC‐urea was studied. Order and rate of urea addition were shown to influence insoluble polymer yields as well as polymer structure. The polymers were characterized by elemental analyses and infrared spectroscopy, and predominant structures…
The action of NbCl5 on a porphyrin (H2L) followed by hydrolysis leads to a complex [(NbL)2O3]. When treated with acetic acid this complex in turn yields a metalloporphyrin of general formula [NbL(O)(O2CMe)]·xMeCO2H. The crystal structures of [{Nb(tpp)}2O3]·4C2H4Cl2(1b) and [Nb(tpp)O(O2CMe)]·MeCO2H (2b)(tpp is the dian…
The observation of spin–spin coupling between 89Y and 31P nuclei in the complex [Y(S2PR2)4]–, R = OEt, is interpreted as evidence for covalent bonding. The magnitude of the reduced coupling constant 2KY–P is of the same order as 2KRh–P and 2KPt–P in [Rh(S2PR2)3] and [Pt(S2PR2)2] indicating similarity in the covalent c…
Electronic energy transfer from the lowest triplet state of triphenylene to the terpositive aquated lanthanide ions, Pr3+, Nd3+, Sm3+, Er3+ and Tm3+ in alcohol glasses at 77 K was investigated. On the basis of spectral overlap calculations and the fitting of the observed donor phosphorescence decays to the decay funct…
Upon charge-transfer excitation (λirrad= 228 nm)[Ru(CN)6]4–, [Mo(CN)8]4–, and [W(CN)8]4–, dissolved in CHCl3, are photo-oxidized to [Ru(CN)6]3–(ϕ= 0·49), [Mo(CN)8]3–(ϕ= 0·40), and [W(CN)8]3–(ϕ= 0·37).
The cavitation-induced deformation and erosion of metals of the three common crystal structures, face centered cubic, body centered cubic, and hexagonal close packed (fcc, bcc, hcp), have been investigated. It is shown that the shock-loading conditions encountered by the metal during cavitation enhances the effects of…
Abstract The limits of neodymium substitution for yttrium in (Y, Nd)Al 3 (BO 3 ) 4 crystals in preparation from solutions in molten potassium trimolybdate have been studied. The maximum neodymium concentration in the crystals was 72 at.%, this corresponding to the ratio Nd:Y = 1 in the solution. When this ratio exceed…
The role of lead in free-machining brass has been studied by calculating the temperatures formed in the primary and secondary shear zones of chip formation and by examining, in a scanning electron microscope, the structure of chips from cutting experiments. The calculations show that the temperatures in the primary zo…
The Grandjean-Friedel-Cano wedge geometry is used to produce well controlled edge dislocation patterns in ordered latexes. Due to the strain field, the color of the Bragg reflected light is found to be modified, making the dislocations easily visible in a metallurgical microscope. An estimate of the elastic energy sto…
Silk, which has been utilized widely as an excellent textile fiber, has also been used as a good material for research, as a typical protein. Numerous studies on silk, carried out continuously over a period of more than one century, have contributed not only to the improvement of production process and quality of raw…