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Ferroelectric Hysteresis Behavior in 0-3 PZT-Cement Composites: Effects of Frequency and Electric Field

Arnon Chaipanich、N. Jaitanong、Rattikorn Yimnirun2009-09-22Ferroelectrics Letters Section

Lead zirconate titanate (PZT)-cement composites of 0-3 connectivity were produced and the effects of the frequency and electric field on the ferroelectric polarization-electric field (P-E) hysteresis of the composites were investigated. It was found that there was an increase in both the instantaneous remnant polariza…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

The Lattice Stabilities and Electronic Structure of BaxSr1 −xTiO3Solid Solutions by First-Principles Calculations

Jianping He、Wenzhong Lü、Xiaohong Wang2009-09-22Ferroelectrics

The structural, electronic, and optical properties of Ba x Sr 1 − x TiO 3 (BST, x = 0.125, 0.250, 0.500, 0.750 and 0.875) solid solutions were investigated by first-principles calculations within generalized gradient approximation based on density-functional theory. Stable lattice structures of cubic paraelectric phas…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Preparation and Characterization of BaO–TeO 2 Thin Films Obtained from Tellurium(VI) Alkoxide by a Sol–Gel Method

Hiroshi Ikeda、Shigeru Fujino、Toshihisa Kajiwara2009-09-22Journal of the American Ceramic Society

BaO–TeO 2 thin films were prepared from tellurium(VI) alkoxide by a sol–gel method and their structure was investigated by X‐ray diffractometry, Fourier transform infrared spectrometry, and 125 Te static nuclear magnetic resonance. Their crystallization temperature ( T c ), optical transmittance, and dielectric consta…

Glass properties and applicationsCrystal Structures and PropertiesPhase-change materials and chalcogenides

Photoinduced phase transitions and helix untwisting in the SmC* phase of a novel cinnamoyl-based liquid crystal

Alexey Bobrovsky、Valéry Shibaev、Věra Hamplová 等 7 位作者2009-09-22Liquid Crystals

A photoinduced phase transition and helix untwisting in a new liquid crystal forming the SmC* phase were studied in detail. The compound consists of a cinnamoyl photosensitive fragment with C = C double bond capable of photoisomerisation and photocycloaddition. It was shown that ultraviolet (UV) irradiation (365 nm) i…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesMolecular spectroscopy and chirality

Spectral Properties of Cu2 +, Ni2 +, Co2 +, Mn2 +& Cr3 +Ions Doped B2O3-BaO-LiF Glasses

B. Hemalatha Rudramadevi、S. Buddhudu2009-09-22Ferroelectrics Letters Section

Brightly colored and more transparent optical glasses in the general chemical composition of B2O3-BaO-LiF (abbreviated as BBLi) with certain transition metal ions (each in 1 mol %) as the dopant ions have been prepared to investigate their optical absorption and photoluminescence spectra. We have measured absorption s…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsPhase-change materials and chalcogenides

A New Synthesis Method of α‐Silicon Nitride Powder‐Reductive Combustion Synthesis from Silicon and Silicon Dioxide

Jiuxin Jiang2009-09-22Journal of the American Ceramic Society

A new synthesis method of Si 3 N 4 powder with a high α‐phase content, namely reductive combustion synthesis, was pioneered in the present work. Some fundamental experiments were carried out and the result indicated that the content of α‐Si 3 N 4 increases with the addition of SiO 2 and C, which considerably enhances…

Advanced ceramic materials synthesisEnergetic Materials and CombustionIntermetallics and Advanced Alloy Properties

Optical Absorption in Polymer‐Derived Amorphous Silicon Oxycarbonitrides

Yansong Wang、Tao Jiang、Ligong Zhang 等 4 位作者2009-09-22Journal of the American Ceramic Society

Three amorphous silicon oxycarbonitrides are prepared by thermal decomposition of a polymeric precursor at different temperatures. The optical absorption spectra of these materials are measured over a wide range of excitation energies from 0.4 to 5.0 eV. The spectra are analyzed using theoretical models. Two absorptio…

Diamond and Carbon-based Materials ResearchThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

Theoretical calculations of the spin-Hamiltonian parameters from a two-mechanism model for Cr5+ions in MVO3(M = Li, Na, K, Rb) crystals

Wen‐Chen Zheng、Weiqing Yang、Yang Mei2009-09-22Molecular Physics

The spin-Hamiltonian parameters (g factors g //, g ⊥ and hyperfine structure constants A //, A ⊥) of the approximately-tetragonal Cr5+ centers in MVO3 (M = Li, Na, K, Rb) crystals are calculated from the complete high-order perturbation formulas for d1 ions in tetragonal symmetry with the ground state . These formulas…

Advanced Chemical Physics StudiesLuminescence Properties of Advanced MaterialsSolid-state spectroscopy and crystallography

Experimental Study on Impact Resistance Properties of T300/Epoxy Composite Laminates

Guiping Zhao、Chongdu Cho、Sheng Guo Lu 等 4 位作者2009-09-22Journal of Composite Materials

The impact resistance properties of T300/epoxy composite laminates are experimented at different velocities of 10—300 m/s striking on the laminates [(45/—45) 4 ] s , [(0/45/90/—45) 2 ] s , and [(0/45/90/—45) 4 ] s . The striking and residual velocities of bullets shot by a high-speed gas gun are measured by laser velo…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Coating Carbon Nanotubes with Ferrites Using an Improved Co-precipitation Method

Zhi Hao、Q.F. Liu、Jianbo Wang2009-09-22Journal of Composite Materials

Multiwalled carbon nanotubes (MWCNTs) have been first coated with cobalt ferrites by a simple wet method. Transmission electron microscopy images show that ferrite nanoparticles (average diameter of 10 nm) were deposited on the sidewall of the MWCNTs. X-ray diffraction pattern exhibits representative diffraction peaks…

Carbon Nanotubes in CompositesGraphene research and applicationsElectromagnetic wave absorption materials

Electromagnetic chirality-induced negative refraction via atomic coherence

Fuli Li、Aiping Fang、Meng Wang2009-09-22Journal of Physics B Atomic Molecular and Optical Physics

Electromagnetic chirality-induced negative refraction in a four-level atomic medium is investigated by initially preparing coherent states of the atom. We show that the negative refraction can be carried out with deeply depressing absorption and without simultaneously requiring both negative electric permittivity and…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsQuantum optics and atomic interactions

Multilayer BST-COC Composite with Enhanced High Frequency Dielectric Properties

Merja Teirikangas、Jari Juuti、Heli Jantunen2009-09-22Ferroelectrics

The 0–3 composites with a mixture of randomly dispersed and separated ceramic particles and thermoplastic polymers provide flexible method to fabricate RF devices with adjusted mechanical and electrical properties. However, high ceramic loading levels are required to achieve high relative permittivity which, on the ot…

Ferroelectric and Piezoelectric MaterialsDielectric materials and actuatorsMicrowave Dielectric Ceramics Synthesis

A method for enlarging the Kerr constant of polymer-stabilised blue phases

Takashi Iwata、Ken Suzuki、Hiroki Higuchi 等 4 位作者2009-09-22Liquid Crystals

Polymer-stabilised blue phase (PSBP) is one of the most promising materials for display devices because of its superior electro-optical properties compared with conventional nematics. However, the application of the PSBP has a serious practical issue in that the driving voltage required is too high to drive with thin…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

[Cr(dmbipy)(ox)2] − : a new bis-oxalato building block for metal assembling. Crystal structures and magnetic properties of XPh 4 [Cr(dmbipy)(ox) 2 ]·5H 2 O (X = P and As), {Ba(H 2 O) 2 [Cr(dmbipy)(ox) 2 ] 2 } n ·17/2nH 2 O and {Ag(H 2 O)[Cr(dmbipy)(ox) 2 ]} n ·3nH 2 O

Marta Viciano‐Chumillas、Nadia Marino、Iván Sorribes 等 6 位作者2009-09-22CrystEngComm

The synthesis, X-ray structure and variable-temperature magnetic study of new compounds of formula PPh4[Cr(dmbipy)(ox)2]·5H2O (1), AsPh4[Cr(dmbipy)(ox)2]·5H2O (2), {Ba(H2O)2[Cr(dmbipy)(ox)2]2}n·17/2nH2O (3) and {Ag(H2O)[Cr(dmbipy)(ox)2]}n·3nH2O (4) (PPh4+ = tetraphenylphosphonium cation; AsPh4+ = tetraphenylarsonium c…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Facile controlled synthesis of highly ordered dendritic and flower-like cobalt superstructures

Zhenguo An、Jingjie Zhang、Shunlong Pan2009-09-22CrystEngComm

Dendritic and flower-like cobalt superstructures have been selectively prepared by a facile hydrothermal route. The synthetic process involves the chemical reduction of cobalt ions and the oriented growth of cobalt nanocrystals under kinetic control independent of surfactants or external magnetic field. The dendritic…

Magnetic properties of thin filmsCharacterization and Applications of Magnetic NanoparticlesNanoporous metals and alloys

Carbosilane and Carbosiloxane Dendrimers

Chung-Kyun Kim、Jang Hwan Hong2009-09-22Molecules

This review focuses on novel carbosilane dendrimers containing branches with Si-C and Si-O-C bonds. Introduction of organic moieties into the dendrimers is performed by hydrosilation of carbon-carbon double/triple bonds. Versatile organic or organometallic moieties are introduced onto the peripheral regions of dendrim…

Luminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

Electron beam irradiation-induced transformations in the electrical properties of 4’-octyl-4-cyanobiphenyl (8CB)

Rohit Verma、Ravindra Dhar、Veena Agrawal 等 7 位作者2009-09-22Liquid Crystals

Changes in the dielectric and thermodynamical properties of electron beam-irradiated 4′-octyl-4-cyanobiphenyl (8CB) were studied. Irradiation-induced changes in the phase transition temperature, dielectric anisotropy, relaxation frequency and activation energy of an observed non-collective relaxation mode correspondin…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchPhotochemistry and Electron Transfer Studies

Nanofiber Alignment on a Flexible Substrate: Hierarchical Order from Macro to Nano

Yogesh Ner、Chris Asemota、James R. Olson 等 4 位作者2009-09-22ACS Applied Materials & Interfaces

A simplified approach to constructing a composite material comprised of aligned electrospun nanofibers onto a flexible substrate consisting of a microfilament yarn is presented. The metal-coated knit patterns of the microfilament yarn play the role of the parallel electrode, required for the alignment of electrospun n…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Understanding Self-poisoning Phenomenon in Crystal Growth of Short-Chain Polymers

Yu Ma、Bo Qi、Yijin Ren 等 6 位作者2009-09-22The Journal of Physical Chemistry B

Flexible polymers crystallize with chain folding, which shows a unique phenomenon called self-poisoning. As a result, minima in crystal growth rates of strictly monodisperse short-chain polymers are observed near the temperatures of transitions from extended-chain to once-folded-chain growth, from once-folded to twice…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesRheology and Fluid Dynamics Studies

Interplay between Shear Loading and Structural Aging in a Physical Gelatin Gel

Olivier Ronsin、C. Caroli、T. Baumberger2009-09-22Physical Review Letters

We show that the aging of the mechanical relaxation of a gelatin gel exhibits the same scaling phenomenology as polymer and colloidal glasses. In addition, gelatin is known to exhibit logarithmic structural aging (stiffening). We find that stress accelerates this process. However, this effect is definitely irreducible…

3D Shape Modeling and AnalysisAdditive Manufacturing and 3D Printing TechnologiesTextile materials and evaluations