Materials Literature
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Over the decades, the rolling contact fatigue life of bearing steels has been enhanced mainly by the decrease in total oxygen content in the steels which was accomplished by improving steelmaking processes or facilities. However, it has almost been kept constant in the level of 5 ppm since 1990s and, therefore, it is…
This work investigates the mechanical properties of Ti-Cr-Sn-Zr alloys containing large amount of Zr. We focuses on the effect of the varying alloy composition on the microstructure, the Young’s modulus, the deformation mechanism and the deformation behavior. Ti-Cr-Sn-Zr alloys show much low Young’s modulus in the nar…
Excitonic phenomena, such as excitonic absorption and emission, have been used in many photonic and optoelectronic semiconductor device applications. As the sizes of these nanoscale materials have approached to exciton diffusion lengths in semiconductors, a fundamental understanding of exciton transport in semiconduct…
Zn and Al are major alloying elements of Mg alloys. Main slip system of Mg is a basal slip and the CRSS increases with Zn or Al content. According to von-Mises criterion, five kinds of independent slip systems are required for uniform deformation, so it is necessary to activate non-basal slip systems to show good duct…
IMI834 (Ti-5.8Al-4Sn-3.5Zr-0.7Nb-0.5Mo-0.35Si) is a high-tech near-α titanium alloy with improved creep resistance and mechanical property retention at temperatures up to 600°C [1]. It is used in the aerospace industry for compressor disks and blades due to its excellent balance between creep resistance and fatigue st…
Titanium alloys were produced by blended elemental powder metallurgy (P/M) method. We focused on the effect of alloying elements (Fe, Mo, and Al) on the consolidation and mechanical properties of Ti compacts prepared by spark plasma sintering. The effects of amount of alloying elements and sintering temperature on the…
In this work we report results for dynamical (hyper)polarizabilities of the sulphur dioxide molecule with inclusion of vibrational corrections. The electronic contributions were computed analytically at the single and double coupled cluster level through response theories for the frequencies 0, 0.0239, 0.0428, 0.0656,…
In the past decade, new steels have been developed for the automotive industry in the framework of environmental requirements. Among them, high manganese austenitic steels combining exceptional properties of strength and ductility are particularly promising. These exceptional properties stem from a fully austenitic st…
The versatile chemical spray pyrolysis was used to prepare elongated double tipped ZnO nanoparticles and microsausages on glass substrates. X-ray diffraction studies revealed several crystallographic plane orientations with the most predominant along the (002) direction. Scanning electron microscope (SEM) observations…
Ca 3 Co 4 O 9+δ ceramic powders were synthesized by the polymerized complex (PC) method. The same Ca 3 Co 4 O 9+δ ceramic bar were treated in turn with three different processes of oxygen treatment: with no treatment, with oxydol (H 2 O 2 ) treatment, and with N 2 treatment. Dynamic mechanical analysis (DMA) was perfo…
Ab initio (first-principles) density functional theory (DFT) calculations are performed within the local density approximations (LDA) to investigate the ferroelectricity at PbTiO(3) surface steps consisting of (001) and (100) surfaces with a spontaneous polarization along [100]. For both the PbO- and TiO(2)-terminated…
To increase the shelf-life qualities of dairy products, a heat treatment is usually done. However, heat treatments induce physico-chemical modifications of the products. Some of them lead to the expected product but an unwanted consequence of this process is the formation of a fouling deposit on the surfaces in contac…
Trägerfreie Katalyse: Die aerobe Oxidation und Kupplung von primären Alkoholen (Methanol, Ethanol, n-Butanol) zu Aldehyden und Estern wird durch freitragendes nanoporöses Gold unterhalb von 100 °C katalysiert. Die experimentellen Bedingungen in dieser Studie ermöglichen eine gute Korrelation mit Modellstudien und verm…
Ti-Sn-Cr shape memory alloys were fabricated by the powder metallurgy (PM) process. The mixed powders in composition of Ti-3at%Sn-7at%Cr were prepared using a V-blender. The mixed powders were filled into a graphite die, and then sintered at a temperature between 1023 K and 1223 K using a pulse current sintering equip…
The one-dimensional (1D) migration of interstitial clusters in austenitic stainless steel SUS316L and its model alloys, namely, Fe–18Cr–13Ni, Fe–18Cr–13Ni–0.012C, and Fe–18Cr–13Ni–1.7Mn (mass %), was examined using in situ observation by high-voltage electron microscopy. Such 1D migration was confirmed to occur along…
Abstract Carbazole‐substituted hydroxyethylcelluloses (Cz‐HECs) are homogeneously synthesized by reacting hydroxyethylcellulose (HEC) with N ‐3′‐bromopropyl carbazole (Br‐Cz). The structure of Cz‐HECs is characterized with elemental analysis and NMR, and the DS of the carbazole is in the range 0.11–0.43, determined fr…
X-ray micro-tomography has been applied recently in a wide range of research fields (damage in materials, solidification …). Thanks to the high flux of synchrotrons and specific cameras the total time to acquire a scan was considerably reduced. The use of a specific camera based on CMOS technology allows dividing the…
The paper investigates nonstationary heat conduction in one-dimensional models with substrate potential. To establish universal characteristic properties of the process, we explore three different models: Frenkel-Kontorova (FK), phi4+ (φ(4)+), and phi4- (φ(4)-). Direct numeric simulations reveal in all these models a…
Two geometric isomers of oligothiophene derivatives containing two crowned styryl fragments in 2- or 3-positions of thiophene rings are able to form stable monolayers on the water subphase. The organizing of crown-containing oligothiophenes in monolayers is guided by the π-stacking interaction of hydrophobic styrylthi…
Superhydrophobic surfaces were prepared using a very simple and low-cost method by spray coating. A high static water contact angle of about 154° was obtained by deposition of stearic acid on an aluminium alloy. However, this coating demonstrated a high contact angle hysteresis (~ 30º). On the other hand, superhydroph…