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Hybrid Pt Nanostructures by Metallization of Organic Films

Maryam Bayati、David J. Schiffrin2013-10-02The Journal of Physical Chemistry C

The synthesis of stable Pt nanoparticles (Pt NPs) and their attachment to glassy carbon (GC) and gold electrodes have been investigated. Two strategies have been followed, by reaction with the thiol termination of a self-assembled monolayer of 1,4-benzenedimethanethiol (BDMT) on gold and by chemical bonding through an…

Conducting polymers and applicationsMolecular Junctions and NanostructuresElectrochemical Analysis and Applications

Heat Capacity and Standard Thermodynamic Functions of Triphenylantimony Bis(1-adamantanecarboxylate) over the Range from (0 to 520) K

I. A. Letyanina、А. В. Маркин、Н. Н. Смирнова 等 5 位作者2013-10-02Journal of Chemical & Engineering Data

Heat capacities of triphenylantimony bis(1-adamantanecarboxylate) Ph 3 Sb[OC(O)C 10 H 15 ] 2 were measured with a precision adiabatic vacuum calorimeter over the temperature range from T = (6 to 353) K and with differential scanning calorimeter over the temperature range from T = (320 to 520) K. The thermal behavior o…

Phase Equilibria and ThermodynamicsThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Extreme ultraviolet lithography resist-based aberration metrology

Germain Fenger、Lei Sun、Sudharshanan Raghunathan 等 5 位作者2013-10-02Journal of Micro/Nanolithography MEMS and MOEMS

Extreme ultraviolet lithography (EUVL) at 13.5 nm is currently the most promising technology for advanced integrated circuit manufacturing nodes. Since the wavelength for EUVL is an order of magnitude smaller than current optical lithography systems (193 nm), aberration tolerances on lens manufacturing must be tighten…

Advanced X-ray Imaging TechniquesAdvancements in Photolithography TechniquesOptical Coatings and Gratings

Characterization of a High‐Spin Non‐Heme {FeNO}8 Complex: Implications for the Reactivity of Iron Nitroxyl Species in Biology

Amy L. Speelman、Nicolai Lehnert2013-10-02Angewandte Chemie

Die chemische und elektrochemische Reduktion eines fünffach koordinierten High-Spin-Nichthäm-{FeNO}7-Komplexes (siehe Struktur: N blau, Fe orange, und O rot) führte zum ersten stabilen High-Spin(S=1)-Nichthäm-{FeNO}8-Modellkomplex. Der Befund, dass die Reduktion metallzentriert abläuft und eine Verringerung der Fe-NO-…

Magnetism in coordination complexesMetal-Catalyzed Oxygenation MechanismsHemoglobin structure and function

Tungsten Diffusion Modified AISI 304 Stainless Steel for PEMFC Bipolar Plate

L. X. Wang、Juncai Sun、S. Li 等 6 位作者2013-10-02Fuel Cells

Abstract Plasma surface diffusion alloying method has been applied to prepare a tungsten diffusion modified layer on the surface of AISI 304 stainless steel (W‐304 SS). A series of material evaluation experiments were performed on the W‐304 SS specimens to determine whether it is suitable to be used as PEMFC bipolar p…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsFuel Cells and Related Materials

The Ideal Quenching Medium? – Characterisation of Ionic Liquids for Heat Treatment of Metallic Components

Martin Beck、C. Schmidt、Mathias Ahrenberg 等 6 位作者2013-10-02HTM Journal of Heat Treatment and Materials

Abstract Quenching as a part of heat treatment is an important process in the manufacturing chain of metallic components. One of the most common processes is immersion quenching in vaporising liquids. Unfortunately, this process is affected by the Leidenfrost-phenomenon. This effect can generate inhomogeneous quenchin…

Corrosion Behavior and InhibitionIonic liquids properties and applicationsInjection Molding Process and Properties

Nano-patterned dual-layer ITO electrode of high brightness blue light emitting diodes using maskless wet etching

Semi Oh、Pei‐Chen Su、Yong-Jin Yoon 等 7 位作者2013-10-02Optics Express

We propose a dual-layer transparent Indium Tin Oxide (ITO) top electrode scheme and demonstrate the enhancement of the optical output power of GaN-based light emitting diodes (LEDs). The proposed dual-layer structure is composed of a layer with randomly distributed sphere-like nano-patterns obtained solely by a maskle…

ZnO doping and propertiesGaN-based semiconductor devices and materialsThin-Film Transistor Technologies

Modulating the Rotation of a Molecular Rotor through Hydrogen‐Bonding Interactions between the Rotator and Stator

Qian‐Chong Zhang、Fang‐Ting Wu、Huimin Hao 等 8 位作者2013-10-02Angewandte Chemie

Zwei Rotormoleküle wurden synthetisiert (siehe Bild). Eine frequenz- und temperaturabhängige Studie der Rotordrehung basierend auf dem Imaginärteil der komplexen dielektrischen Konstante (ε′′) zeigt, dass die Drehung des molekularen Einkomponenten-Rotors durch Wasserstoffbrücken zwischen Rotor und Stator moduliert wer…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryMolecular spectroscopy and chirality

A Two-Stage Model for In Vivo Assessment of Brain Tumor Perfusion and Abnormal Vascular Structure Using Arterial Spin Labeling

Patrick W. Hales、Kim Phipps、Ramneek Kaur 等 4 位作者2013-10-02PLoS ONE

The ability to assess brain tumor perfusion and abnormalities in the vascular structure in vivo could provide significant benefits in terms of lesion diagnosis and assessment of treatment response. Arterial spin labeling (ASL) has emerged as an increasingly viable methodology for non-invasive assessment of perfusion.…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesMRI in cancer diagnosis

Silica‐Coating of Hematite Nanoparticles Using Reactive Water‐Soluble Polyalkoxysiloxanes

Karla Doermbach、Garima Agrawal、Mark R. Servos 等 7 位作者2013-10-02Particle & Particle Systems Characterization

In this article, we report on a new one‐step synthetic route to obtain multi‐functional silica‐coated hematite particles using a water‐based surfactant‐free technology. The synthesis and properties of uniform silica‐coated hematite particles with adjustable size, morphology, and silica shell thickness are discussed in…

Advanced Photocatalysis TechniquesIron oxide chemistry and applicationsPickering emulsions and particle stabilization

A merged photonic crystal slot waveguide embedded in ALD-TiO_2

Petri Stenberg、M. Roussey、Piotr Ryczkowski 等 6 位作者2013-10-02Optics Express

We demonstrate the concept of a merged nanoscale photonic crystal slot waveguide that acts as a bandpass filter in the near infrared region of the spectrum. The device is based on the integration of a photonic crystal cavity in a slot waveguide on a silicon on insulator substrate. The device is further embedded in amo…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsSilicon Nanostructures and Photoluminescence

Residual Stress, Nanohardness, and Microstructure Changes in Whirlwind Milling of GCr15 Steel

Qin Guo、Li Chang、Lin Ye 等 8 位作者2013-10-02Materials and Manufacturing Processes

Compared to grinding which has low efficiency, serious pollution, and hard turning together with serious tool wear, whirlwind milling (WM) is a more competitive machining process in manufacturing. However, as a technology under development, the complicated mechanism in WM processes has not yet been fully understood. I…

Advanced machining processes and optimizationAdvanced Surface Polishing TechniquesMetal Alloys Wear and Properties

Multicomponent Assembly of Supramolecular Coordination Polygons on a Au(111) Surface

Tao Lin、Xue Song Shang、Pei Nian Liu 等 4 位作者2013-10-02The Journal of Physical Chemistry C

We have studied the self-assembly of a series of multicomponent cyclic supramolecular polygons on a Au(111) surface using scanning tunneling microscopy and kinetic Monte Carlo simulations. Our results indicate that while closed polygons or cages efficiently self-assemble in three dimensions at appropriate temperatures…

Advanced Chemical Physics StudiesSupramolecular Self-Assembly in MaterialsSurface Chemistry and Catalysis

Polyvinylpyrrolidone (PVP) assisted single‐step synthesis of kesterite Cu2ZnSnS4 nanoparticles by solvothermal process

Sawanta S. Mali、Hyungjin Kim、Chang-Su Shim 等 5 位作者2013-10-02physica status solidi (RRL) - Rapid Research Letters

Abstract Quaternary kesterite‐type Cu2ZnSnS4 (CZTS) nanoparticles (NPs) were successfully synthesized by a single‐step solvothermal process. Semiconductor CZTS nanoparticles were obtained from ethylene glycol (EG) and CZTS precursor after solvothermal process at 180 °C for 30 h in polyvinylpyrrolidone (PVP) medium. Th…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Counterintuitive Anisotropy of Electron Transport Properties in KC60(THF)5⋅2 THF Fulleride

A. Kromer、Ulrich Wedig、Emil Roduner 等 5 位作者2013-10-02Angewandte Chemie International Edition

Spin and charge transport: The electronic and structural properties obtained from KC60(THF)5⋅2 THF single crystals are reported (see picture). An important finding is the presence of one-dimensional electric conductivity and the observation of counterintuitive anisotropy for electron transport.

Graphene research and applicationsFullerene Chemistry and ApplicationsBoron and Carbon Nanomaterials Research

A unifying mode-coupling theory for transport properties of electrolyte solutions. I. General scheme and limiting laws

Claudio Contreras-Aburto、Gerhard Nägele2013-10-02The Journal of Chemical Physics

We develop a general method for calculating conduction-diffusion transport properties of strong electrolyte mixtures, including specific conductivities, steady-state electrophoretic mobilities, and self-diffusion coefficients. The ions are described as charged Brownian spheres, and the solvent-mediated hydrodynamic in…

Material Dynamics and PropertiesThermodynamic properties of mixturesElectrostatics and Colloid Interactions

Microstructural Alterations in Bearing Steels under Rolling Contact Fatigue: Part 2—Diffusion-Based Modeling Approach

Anurag Warhadpande、Farshid Sadeghi、R Evans2013-10-02Tribology Transactions

The microstructure of rolling element bearings can experience significant transformation when subjected to repetitive contact cycling. In Part 1 of this article, a detailed overview of the known microstructure alteration phenomena was presented and the different mechanisms for describing them proposed by various inves…

High Temperature Alloys and CreepMechanical stress and fatigue analysisMetal Alloys Wear and Properties

Optimization of solvent crystallization process in obtaining high purity anthracene and carbazole from crude anthracene

Cuiping Ye、Huan Zheng、Tingting Wu 等 6 位作者2013-10-02AIChE Journal

Solvent crystallization is the main method used for preparing anthracene and carbazole from the crude anthracene. The key to the optimization of this method is improving the solubility selectivity of the solvent by means of solvent modulating and process optimization. In this study, the solubility of anthracene, phena…

Ionic liquids properties and applicationsAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

Fabrication and electromechanical examination of a spherical dielectric elastomer actuator

Sadegh Ahmadi、Mark Gooyers、Maryam Soleimani 等 4 位作者2013-10-02Smart Materials and Structures

In this paper, a procedure for fabricating and testing a seamless spherical dielectric elastomer actuator (DEA) is presented. In previously developed spherical prototypes, the DEA material is pre-strained by a rigid frame to improve the actuator's output force; however, it is possible to pre-strain a spherical DEA by…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsDielectric materials and actuators

Kinetics of Allosteric Transitions in S-adenosylmethionine Riboswitch Are Accurately Predicted from the Folding Landscape

Jong-Chin Lin、D. Thirumalai2013-10-02Journal of the American Chemical Society

Riboswitches are RNA elements that allosterically regulate gene expression by binding cellular metabolites. The SAM-III riboswitch, one of several classes that binds S-adenosylmethionine (SAM), represses translation upon binding SAM (OFF state) by encrypting the ribosome binding sequence. We have carried out simulatio…

RNA and protein synthesis mechanismsViral Infections and Immunology ResearchEnzyme Structure and Function