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Emissions of Polycyclic Aromatic Hydrocarbons, Polychlorinated Dibenzo-p-Dioxins, and Dibenzofurans from Incineration of Nanomaterials

Eric P. Vejerano、Amara L. Holder、Linsey C. Marr2013-03-25Environmental Science & Technology

Disposal of some nanomaterial-laden waste through incineration is inevitable, and nanomaterials' influence on combustion byproduct formation under high-temperature, oxidative conditions is not well understood. This work reports the formation of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated-dibenzo-p-diox…

Nanoparticles: synthesis and applicationsToxic Organic Pollutants ImpactEnvironmental remediation with nanomaterials

QSPR prediction of physico-chemical properties for REACH

John C. Dearden、Patricia Rotureau、Guillaume Fayet2013-03-25SAR and QSAR in environmental research

For registration of a chemical, European Union REACH legislation requires information on the relevant physico-chemical properties of the chemical. Predicted property values can be used when the predictions can be shown to be valid and adequate. The relevant physico-chemical properties that are amenable to prediction a…

Computational Drug Discovery MethodsThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Coupling biorelevant dissolution methods with physiologically based pharmacokinetic modelling to forecast in-vivo performance of solid oral dosage forms

K. Otsuka、Yasushi Shono、Jennifer Dressman2013-03-25Journal of Pharmacy and Pharmacology

OBJECTIVES: To summarize the basis for and progress with the development of in-vitro-in-silico-in-vivo (IV-IS-IV) relationships for oral dosage forms using physiologically based pharmacokinetic (PBPK) modelling, with the focus on predicting the performance of solid oral dosage forms in humans. KEY FINDINGS: Various ap…

Drug Solubulity and Delivery SystemsDrug Transport and Resistance MechanismsCrystallization and Solubility Studies

miRNA-21 is dysregulated in response to vein grafting in multiple models and genetic ablation in mice attenuates neointima formation

Robert A. McDonald、Katie White、Junxi Wu 等 14 位作者2013-03-25European Heart Journal

AIMS: The long-term failure of autologous saphenous vein bypass grafts due to neointimal thickening is a major clinical burden. Identifying novel strategies to prevent neointimal thickening is important. Thus, this study aimed to identify microRNAs (miRNAs) that are dysregulated during neointimal formation and determi…

MicroRNA in disease regulationCoronary Interventions and DiagnosticsElectrospun Nanofibers in Biomedical Applications

Mechanical basis of morphogenesis and convergent evolution of spiny seashells

Régis Chirat、Derek E. Moulton、Alain Goriely2013-03-25Proceedings of the National Academy of Sciences

Convergent evolution is a phenomenon whereby similar traits evolved independently in not closely related species, and is often interpreted in functional terms. Spines in mollusk seashells are classically interpreted as having repeatedly evolved as a defense in response to shell-crushing predators. Here we consider the…

Paleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and InhibitionCephalopods and Marine Biology

Stress sensing performance using mechanoluminescence of SrAl2O4:Eu (SAOE) and SrAl2O4:Eu, Dy (SAOED) under mechanical loadings

Gun Jin Yun、Mohammad Reza Rahimi、Amir H. Gandomi 等 5 位作者2013-03-25Smart Materials and Structures

In this paper, the stress sensing performance of two well-known mechanoluminescence (ML) sensing materials, (1) SrAl2O4:Eu (SAOE) and (2) SrAl2O4:Eu, Dy (SAOED), has been experimentally studied. Under the same input loadings and strain rates, changes of the light intensity have been characterized in terms of sensitivi…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsAcoustic Wave Resonator Technologies

On the Universe of Protein Folds

Rachel Kolodny、Leonid Pereyaslavets、Abraham O. Samson 等 4 位作者2013-03-25Annual Review of Biophysics

In the fifty years since the first atomic structure of a protein was revealed, tens of thousands of additional structures have been solved. Like all objects in biology, proteins structures show common patterns that seem to define family relationships. Classification of proteins structures, which started in the 1970s w…

Protein Structure and DynamicsEnzyme Structure and FunctionMachine Learning in Bioinformatics

Quantifying perpendicular magnetic anisotropy at the Fe-MgO(001) interface

Charles‐Henri Lambert、A. Rajanikanth、Thomas Hauet 等 6 位作者2013-03-25Applied Physics Letters

We show that Fe-MgO interfaces possess strong perpendicular magnetic anisotropy of 1.0 ± 0.1 erg/cm2 in fully epitaxial MgO/V/Fe/MgO(001) and MgO/Cr/Fe/MgO(001) heterostructures. The sign and amplitude of the total anisotropy are quantified as a function of Fe thickness using magnetometry and ferromagnetic resonance.…

Magnetic properties of thin filmsZnO doping and propertiesMagnetic Properties and Applications

Inorganic–Organic Hybrid Nanoparticles with Biocompatible Calcium Phosphate Thin Shells for Fluorescence Enhancement

Bishnu Prasad Bastakoti、Yin‐Chu Hsu、Shih‐Hsiang Liao 等 8 位作者2013-03-25Chemistry - An Asian Journal

Polymeric micelles consisting of asymmetric triblock copolymers were successfully used for fabrication of robust hybrid nanoparticles with highly biocompatible calcium phosphate shells. The hydrophobic polystyrene core encapsulates hydrophobic fluorescent dyes such as Nile red. The anionic polyacrylic acid provides th…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsAdvanced Nanomaterials in Catalysis

Charge Carrier Dynamics in a Ternary Bulk Heterojunction System Consisting of P3HT, Fullerene, and a Low Bandgap Polymer

Markus Koppe、Hans‐Joachim Egelhaaf、Ewan Clodic 等 10 位作者2013-03-25Advanced Energy Materials

Abstract The photoresponse of P3HT:PC61BM based organic solar cells can be enhanced by blending the bulk heterojunction with the low band gap polymer Si‐ PCPDTBT. Organic solar cells containing the resulting ternary blend as the photoactive layer deliver short circuit currents of up to 15.5 mA cm−2. Morphological stud…

Organic Electronics and PhotovoltaicsThin-Film Transistor TechnologiesConducting polymers and applications

Influence of Crystallinity and Energetics on Charge Separation in Polymer–Inorganic Nanocomposite Films for Solar Cells

Neha Bansal、Luke X. Reynolds、Andrew MacLachlan 等 14 位作者2013-03-25Scientific Reports

The dissociation of photogenerated excitons and the subsequent spatial separation of the charges are of crucial importance to the design of efficient donor-acceptor heterojunction solar cells. While huge progress has been made in understanding charge generation at all-organic junctions, the process in hybrid organic:i…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Electrochemiluminescence energy transfer-promoted ultrasensitive immunoassay using near-infrared-emitting CdSeTe/CdS/ZnS quantum dots and gold nanorods

Lingling Li、Ying Chen、Qian Lu 等 11 位作者2013-03-25Scientific Reports

The marriage of energy transfer with electrochemiluminescence has produced a new technology named electrochemiluminescence energy transfer (ECL-ET), which can realize effective and sensitive detection of biomolecules. To obtain optimal ECL-ET efficiency, perfect energy overlapped donor/acceptor pair is of great import…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesBiosensors and Analytical Detection

Brønsted Acid-Promoted C–H Bond Cleavage via Electron Transfer from Toluene Derivatives to a Protonated Nonheme Iron(IV)-Oxo Complex with No Kinetic Isotope Effect

Jiyun Park、Yong‐Min Lee、Wonwoo Nam 等 4 位作者2013-03-25Journal of the American Chemical Society

The reactivity of a nonheme iron(IV)-oxo complex, [(N4Py)Fe(IV)(O)](2+) (N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine), was markedly enhanced by perchloric acid (70% HClO4) in the oxidation of toluene derivatives. Toluene, which has a high one-electron oxidation potential (Eox = 2.20 V vs SCE), was oxid…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Filament observation in metal-oxide resistive switching devices

Umberto Celano、Yang Yin Chen、Dirk J. Wouters 等 6 位作者2013-03-25Applied Physics Letters

Metal-oxide-based resistive random access memory (RRAM) is a predominant candidate for future non-volatile memories. In this Letter, we report on an innovative technique to observe conductive filaments in these oxide-based RRAM devices. We demonstrate the role of these conductive filaments as responsible for the diffe…

Advanced Memory and Neural ComputingTransition Metal Oxide NanomaterialsFerroelectric and Negative Capacitance Devices

Recent Advances in Metal–Organic Framework‐Based Mixed Matrix Membranes

İlknur Eruçar、Gamze Yilmaz、Seda Keskın2013-03-25Chemistry - An Asian Journal

Mixed matrix membranes (MMMs) combine easy processability and low cost of polymers with the high selectivity of nanoporous filler particles. These membranes represent an important avenue for enhancing the performance of polymeric membranes in gas separations. Recently, a new group of nanoporous materials called metal-…

Metal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Attachment of a Hydrophobically Modified Biopolymer at the Oil–Water Interface in the Treatment of Oil Spills

Pradeep Venkataraman、Jingjian Tang、Etham Frenkel 等 9 位作者2013-03-25ACS Applied Materials & Interfaces

The stability of crude oil droplets formed by adding chemical dispersants can be considerably enhanced by the use of the biopolymer, hydrophobically modified chitosan. Turbidimetric analyses show that emulsions of crude oil in saline water prepared using a combination of the biopolymer and the well-studied chemical di…

Enhanced Oil Recovery TechniquesPickering emulsions and particle stabilizationOil Spill Detection and Mitigation

Negative pressures in nanoporous membranes for thin film evaporation

Rong Xiao、Shalabh C. Maroo、Evelyn N. Wang2013-03-25Applied Physics Letters

We present a nanoporous membrane-based approach, which decouples the capillary pressure from the viscous resistance, to achieve high driving pressures and efficient liquid delivery for thin film evaporation. By using alumina membranes with ≈150 nm pore diameters, absolute liquid pressures as low as −300 kPa were achie…

Surface Modification and SuperhydrophobicityHeat Transfer and Boiling StudiesFluid Dynamics and Thin Films

CMOS-compatible high efficiency double-etched apodized waveguide grating coupler

Chao Li、Huijuan Zhang、Mingbin Yu 等 4 位作者2013-03-25Optics Express

We present a high efficiency double-etched apodized fiber-to-waveguide grating coupler on a silicon-on-insulator substrate, which can be fabricated using deep UV photolithography. The fabricated grating coupler yields a coupling loss of -1.5 dB with 3-dB bandwidth of 54 nm at a wavelength of 1560 nm. Measurements and…

Advanced Fiber Optic SensorsPhotonic and Optical DevicesOptical Coatings and Gratings

Real-Time and in Situ Investigation of “Living”/Controlled Photopolymerization in the Presence of a Trithiocarbonate

Hu Wang、Qianbiao Li、Jingwen Dai 等 6 位作者2013-03-25Macromolecules

Polymerization of methyl acrylate under ultraviolet (UV) irradiation in the presence of S -1-dodecyl- S ′-(α,α′-dimethyl-α″-acetic acid) trithiocarbonate (DDMAT) was investigated by in situ 1 H nuclear magnetic resonance spectroscopy. Effects of light intensity, wavelength, and concentration of DDMAT on the polymeriza…

Advanced Polymer Synthesis and CharacterizationPhotochromic and Fluorescence ChemistryPhotopolymerization techniques and applications