Materials Literature
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We report the synthesis of hexagonal LaV${}_{x}$Cr${}_{1\ensuremath{-}x}$Ge${}_{3}$ ($x=0$--0.21, 1.00) single crystals and present a systematic study of this series by measurements of temperature- and field-dependent magnetic susceptibility, magnetization, resistivity, and specific heat. Ferromagnetism has been obser…
In this paper we extend the recent theory of shear localization in two-dimensional (2D) amorphous solids to three dimensions. In two dimensions the fundamental instability of shear localization is related to the appearance of a line of displacement quadrupoles that makes an angle of 45^{∘} with the principal stress ax…
We present a study analyzing the selectivity of host–guest interactions in a series of functionalized Al-MIL-53-X metal–organic frameworks with X = H, NH 2, and NHCHO using acetone, ethanol, and water as probe molecules. While the amino group introduces additional hydrogen bond donor centers the NHCHO anchors function…
The single-chain mechanics of two similar thermosensitive polymers, poly(N,N-diethylacrylamide) (PDEAM) and poly(N-isopropylacrylamide) (PNIPAM), have been studied by atomic force microscopy-based single-molecule force spectroscopy (SMFS). In a typical nonpolar organic solvent, octane, both of the polymers show the sa…
Four new 4d–4f heterometallic coordination polymers, namely, {[LnAg(DSPT)( m BDC)(H 2 O) 2 ]·H 2 O} n [Ln = Sm, ( 1 ); Ln = Er, ( 2 ); H 2 DSPT = 4′-(2,4-disulfophenyl)-2,2′:6′2″-terpyridine); H 2 m BDC = 1,3-benzenedicarboxylic acid], {[CeAg(DPST)( m BDC)(H 2 O) 2 ]·H 2 O} n ( 3 ), and {[TbAg 3 (DPST) 2 (INC) 2 (H 2…
CuI-catalyzed oxidative reaction of amidines with C60 using air as the oxidant has been exploited for the easy preparation of fulleroimidazole derivatives. Furthermore, this kind of CuI-catalyzed [3 + 2] reaction has also been successfully applied in the synthesis of fullerooxazole derivatives starting from amides for…
Furan affairs: Electronic structure calculations of the homogeneous Brønsted acid-catalyzed hydrolysis of 2,5-dimethylfuran show that proton transfer to the β-position is rate-limiting and provides support that the hydrolysis follows general acid catalysis. By means of projected Fukui indices, we show this to be the c…
We present a partial free energy profile for the homogeneous nucleation of ice using an all-atom model of water at low supercooling, at which ice growth dynamics are reasonably accessible to simulation. We demonstrate that the free energy profile is well described by classical nucleation theory, and that the nucleatio…
This paper discussed refinement strategy that been used to reveal crystallographic properties of lithium-based complex oxides with layered rock salt structure. Rietveld analysis using XRD data was used to determine the amount of interlayer mixing and estimate oxygen contents. The structural model and refinement method…
Direct imaging of nanoscale objects suspended in liquid media can be accomplished using cryogenic transmission electron microscopy (cryo-TEM). Cryo-TEM has been used with particular success in microbiology and other biological fields. Samples are prepared by plunging a thin film of sample into an appropriate cryogen,…
Thermally induced depolarization and thermal lens of three Konoshima Chemical Co. laser-ceramics samples Yb(3+):Lu(2)O(3)(C(Yb) ≈ 1.8 at.%), Yb(3+):Y(2)O(3)(C(Yb) ≈ 1.8 at.%), and Yb(3+):Sc(2)O(3) (C(Yb) ≈ 2.5 at.%) were measured in experiment at different pump power. The results allowed us to estimate the thermal con…
The increasing demand of lightweight and durability makes advanced high strength steel attractive for future automotive applications. In this study, 0·8 mm thick bare 600, 800 and 1000 MPa grade dual phase steel and 1500 MPa grade martensitic steel were laser welded, and the effect of welding speed on weld bead geomet…
Abstract BACKGROUND In spite of its efficiency and versatility, examples of the use of N‐hydroxyphthalimide (NHPI) as catalyst for oxidations at industrial scale are scant, mainly due to the lack of methodologies for the recovery and reuse of the catalyst. This paper reports a step by step investigation of the aerobic…
Ultrasound contrast agents (UCAs) have the potential to nucleate cavitation and promote both beneficial and deleterious bioeffects in vivo. Previous studies have elucidated the pulse-duration-dependent pressure amplitude threshold for rapid loss of echogenicity due to UCA fragmentation. Previous studies have demonstra…
Two‐parameter analysis of auxetics among the cubic crystals is proposed. A brief analysis of the equivalence of this two‐parameter consideration and other approaches is given. The main result of this paper is the classification of partial auxetics with a single dimensionless complex, which is composed of the crystals…
We study the dynamics of a tagged particle in an environment of point Brownian particles with hard-core interactions in an infinite one-dimensional channel (a single-file model). In particular, we examine the influence of initial conditions on the dynamics of the tagged particle. We compare two initial conditions: equ…
The driving force for self-assembly is the associated gain in free energy with decisive contributions from both enthalpy and entropy differences between final and initial state. For monolayer self-assembly at the liquid-solid interface, solute molecules are initially dissolved in the liquid phase and then become incor…
Nanoparticles were prepared by ionotropic gelation of low-methoxylated (LM) and amidated low-methoxylated (AM) pectin with zinc chloride (ZnCl2) in aqueous media. The samples were characterized by atomic force microscopy, dynamic light scattering, turbidimetry, zeta potential, and pH measurements. Pectin nanoparticles…
The use of biological entities in biotechnology and the biomedical field is of great interest as the biocompatibility and the functionality of naturally occurring is usually higher compared to other biomaterials, for example, synthetic polymers. Processing of natural biomolecules, including proteins like collagen and…
Calcium, strontium, and barium copper silicates are demonstrated to possess valuable photophysical properties which make them particularly attractive for application in optical chemosensors. Several examples of sensing materials based on these phosphors are provided. Particularly, broad excitation and near-infrared em…