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Construction of Deoxyriboaldolase-Overexpressing Escherichia coli and Its Application to 2-Deoxyribose 5-Phosphate Synthesis from Glucose and Acetaldehyde for 2′-Deoxyribonucleoside Production

Nobuyuki Horinouchi、Jun Ogawa、Takafumi Sakai 等 8 位作者2003-07-01Applied and Environmental Microbiology

The gene encoding a deoxyriboaldolase (DERA) was cloned from the chromosomal DNA of Klebsiella pneumoniae B-4-4. This gene contains an open reading frame consisting of 780 nucleotides encoding 259 amino acid residues. The predicted amino acid sequence exhibited 94.6% homology with the sequence of DERA from Escherichia…

Enzyme Structure and FunctionEnzyme Production and CharacterizationBiochemical and Molecular Research

Corrosion Behavior and Galvanic Coupling of Stainless Steels, Titanium, and Alloy 33 in Lithium Bromide Solutions

A. Igual Muñoz、J. García‐Antón、J. L. Guiñón 等 4 位作者2003-07-01CORROSION

The corrosion resistance and galvanic behavior of three stainless steels (SS), Alloy 33, and titanium were analyzed in commercial lithium bromide (LiBr) heavy brine solutions used in heating and refrigerating systems, with and without additives, using potentiodynamic anodic polarization measurements. Corrosion rates w…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques

Electron microscopy of mammalian cells in the absence of fixing, freezing, dehydration, or specimen coating

D J Stokes、Susan M. Rea、Serena M. Best 等 4 位作者2003-07-01Scanning

Human osteoblast-like (bone-forming) cells were imaged using environmental scanning electron microscopy (ESEM). The cells were hydrated, unfrozen, and uncoated. Specimens were cooled to 3 degrees C and imaged in water vapor, with partial pressures varying from saturated conditions to a humidity of approximately 50%, r…

Hydrogen embrittlement and corrosion behaviors in metalsMachine Learning in Materials ScienceElectron and X-Ray Spectroscopy Techniques

Hexacoordinate Silicon(IV) Complexes Containing Thiocyanato‐N Ligands — Syntheses, Structural Characterization, and Computational Studies

O. Seiler、Rüdiger Bertermann、N. Buggisch 等 7 位作者2003-07-01Zeitschrift für anorganische und allgemeine Chemie

Abstract The hexacoordinate silicon(IV) complexes [NEt 4 ] 2 [Si(NCS) 6 ] ( 2 ), [K(18‐crown‐6)] 2 [Si(NCS) 6 ]·2CH 3 CN ( 3· 2CH 3 CN), and cis ‐[(acac) 2 Si(NCS) 2 ] ( cis ‐ 4 ; acac = acetylacetonato‐ O , O ) were synthesized, starting from Si(NCS) 4 ( 1 ). Compounds 1 , 2 , 3· 2CH 3 CN, and cis ‐ 4 were structural…

Magnetism in coordination complexesSynthesis and characterization of novel inorganic/organometallic compoundsInorganic Fluorides and Related Compounds

Single-Turn GaAs/InAs Nanotubes Fabricated Using the Supercritical CO2Drying Technique

V. A. Seleznev、Hiroshi Yamaguchi、Y. Hirayama 等 4 位作者2003-07-01Japanese Journal of Applied Physics

We have applied supercritical CO 2 drying technique to fabricate free-standing semiconductor nanotubes, in order to solve the problem of tube collapsing caused by the capillary forces in the final drying process. We have successfully fabricated damage-free single-turn nanotubes with ultra-thin walls (lesser than 3 nm)…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchHeat Transfer and Optimization

Chain Connectivity and Conformational Variability of Polymers: Clues to an Adequate Thermodynamic Description of Their Solutions, 1

Maria Bercea、Maria Cazacu、Bernhard Wolf2003-07-01Macromolecular Chemistry and Physics

Abstract This is the first of two parts investigating the Flory‐Huggins interaction parameter, χ , as a function of composition and chain length. Part 1 encompasses experimental and theoretical work. The former comprises the synthesis of poly(dimethylsiloxane)s with different molar mass and the measurements of their s…

Polymer crystallization and propertiesChemical Thermodynamics and Molecular StructureAdsorption, diffusion, and thermodynamic properties of materials

A Domain Wall Model for Hysteresis in Ferroelastic Materials

Jordan E. Massad、Ralph C. Smith2003-07-01Journal of Intelligent Material Systems and Structures

We develop a model that quantifies constitutive nonlinearities and hysteresis inherent to ferroelastic compounds, with emphasis placed on shape memory alloys. We formulate the model in two steps. First, we use the Landau theory of phase transitions to characterize the effective Gibbs free energy for single-crystal and…

Shape Memory Alloy TransformationsSolidification and crystal growth phenomenaMagnetic Properties and Applications

Cluster, facets, and edges: Site‐dependent selective chemistry on model catalysts

Hans‐Joachim Freund、Jörg Libuda、M. Bäumer 等 5 位作者2003-07-01The Chemical Record

Abstract More than activity, selectivity of catalytic reactions is the focus of research in the 21 st century. We review studies on model systems that address the issue of directing a catalytic reaction on disperse metal catalysts by controlling the specific surface site. Three examples are explored: methanol dehydrog…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Two‐ and Three‐Dimensional Frameworks Constructed From Bicapped Keggin Clusters

Limei Duan、Cheng‐Ling Pan、Ji‐Qing Xu 等 6 位作者2003-07-01European Journal of Inorganic Chemistry

Abstract The novel two‐ and three‐dimensional solid materials [Cu(en) 2 (H 2 O)]{PMo VI 8 V IV 6 O 42 [Cu(en) 2 ][Cu 0.5 (en)] 3 }·5.5H 2 O and H 3 {V V Mo VI 8 V IV 6 O 42 [Cu(en) 2 ] 4 }[MoO 4 ] 2 ·14H 2 O (en = ethylenediamine) have been hydrothermally assembled and structurally characterized. Both networks are bas…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Dual-frequency distortion predictions for the cutler VLF array

E. C. Berg、Mark Roberts、Ted Simpson2003-07-01IEEE Transactions on Aerospace and Electronic Systems

The VLF transmitting system in Cutler, ME currently broadcasts at one frequency through a two-element antenna system. This study investigates simultaneous operation at 24.0 and 17.8 kHz. Detailed nonlinear PSPICE models were generated for the system including the amplifier triodes, saturable dynamic-tuning reactors, a…

Power Systems Fault DetectionMagnetic Properties and ApplicationsVibration and Dynamic Analysis

Matrix Acid Stimulation

Karen Bybee2003-07-01Journal of Petroleum Technology

This article, written by Assistant Technology Editor Karen Bybee, contains highlights of paper SPE 82260, "Matrix Acid Stimulation - A Review of the State of the Art," by Phil Rae, SPE, and Gino di Lullo, BJ Services Co., prepared for the 2003 SPE European Formation Damage Conference, The Hague, 13-14 May.

High-Velocity Impact and Material BehaviorIndustrial Technology and Control Systems

New rubidium pentaborate Rb[B5O7(OH)2] · 0.5H2O with a 5: [4Δ + 1T] anionic block and its relation to larderellite (NH4)[B5O7(OH)2] · H2O on the basis of the OD theory

Е. Л. Белоконева、T. A. Borisova、О. В. Димитрова2003-07-01Crystallography Reports

A new rubidium pentaborate is synthesized under hydrothermal conditions. Its crystal structure is studied by the heavy-atom method without any a priori knowledge of chemical formula. The chemical formula is Rb[B5O6(OH)4] · 0.5H2O, sp. gr. $$\bar P1$$ , lattice parameters a = 7.679(4) Å, b = 9.253(6) Å, c = 12.053(9) Å…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography

Field emission and growth characteristics of carbon nanotubes with optical emission spectroscopy analysis in C3H4 and CO deposition systems

Jae‐Hee Han、Tae Young Lee、Ji‐Beom Yoo 等 8 位作者2003-07-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

Chemical species during growth of carbon nanotubes (CNTs) in direct current-plasma-enhanced chemical vapor deposition were studied in detail using C3H4–NH3 and CO–NH3 mixtures through optical emission spectroscopy. In the C3H4–NH3 system, the relative intensities of CN (388.3 nm) and CH (431.4 nm) decreased and that o…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

X-raying studies of the nanoporous carbon structure produced from carbide materials

R. N. Kyutt、A. M. Danishevskiı̆、É. A. Smorgonskaya 等 4 位作者2003-07-01Semiconductors

X-raying is used to study the structure of nanoporous carbon particles produced from carbides of various materials (SiC, TiC, Mo2C, and B4C) by chemical removal of carbide-forming elements. The X-ray diffraction patterns exhibit reflections in the double reflection angle ranges 2θ=23°–26° and 42°–44°. An analysis of t…

Diamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials ResearchAdvanced materials and composites

Developments in understanding the formation, structure and properties of polymer networks

R. F. T. Stepto、J.I. Cail、D. J. R. Taylor 等 5 位作者2003-07-01Macromolecular Symposia

Abstract Two areas of networks modelling are described. The first is concerned with the application of a Monte‐Carlo (MC) algorithm to account fully for loop formation in RA 2 + R′B 3 and RA 2 + R′B 4 polymerisations. The resulting interpretation of experimental elastic moduli of HDI‐based polyurethane (PU) networks p…

Polymer Nanocomposites and PropertiesPolymer composites and self-healing

Molecular Weight and Long Chain Branch Distributions of Branch‐Block Olefinic Thermoplastic Elastomers

Márcio Nele、João B. P. Soares2003-07-01Macromolecular Theory and Simulations

Abstract Olefinic thermoplastic elastomers can be prepared by incorporating semi‐crystalline macromonomers (e.g. isotactic or syndiotactic poly(propylene), high‐density polyethylene) onto amorphous backbones (e.g. atactic poly(propylene), ethylene/ α ‐olefin copolymers). The macromonomer incorporation reaction can be…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Polyoxolenes may provide a tool for designing paramagnetic molecules with predetermined spin topologies

Alessandro Bencini、Andréa Caneschi、Andrea Dei 等 8 位作者2003-07-01Comptes Rendus Chimie

The development of the chemistry of transition metal complexes formed by o -semiquinonato radical ligands has provided a useful topic for learning how to use chemical methods for obtaining systems with predetermined magnetic properties. Similar complexes can be used as building blocks for assembling magnetically coupl…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Changes in particle area measurements due to SEM accelerating voltage and magnification

María Julia Yañez、Silvia E. Barbosa2003-07-01Microscopy Research and Technique

Scanning electron microscopy (SEM) images of polymer blends followed by digital image analysis is a rapid and easy method for the measurement of particle size and dispersion. The particle size determination is done with appropriate off-line image analysis software. However, it is necessary to understand how machine pa…

Corrosion Behavior and InhibitionElectron and X-Ray Spectroscopy TechniquesSurface Roughness and Optical Measurements

Structure‐mechanical properties relationship of poly(ethylene terephthalate) fibers

Milena Žiberna Šujica、Majda Sfiligoj Smole2003-07-01Journal of Applied Polymer Science

Abstract The correlation between the fiber structure and mechanical properties of two different poly(ethylene terephthalate) fiber types, that is, wool and cotton types produced by three producers, was studied. Fiber structure was determined using different analytical methods. Significant differences in the suprastruc…

Advanced Sensor and Energy Harvesting MaterialsTextile materials and evaluationsMaterial Properties and Processing