Materials Literature
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A technique for distinguishing biological material based on surface-enhanced Raman scattering (SERS) is reported in this work. Of particular interest is biological material that can be airborne. Silver colloidal particles with diameters in the range 10 to 20 nm and with a characteristic ultraviolet-visible (UV-VIS) ab…
Preparation of cellulose-polyamine composite films and beads, which provide high loading of primary amines on the surface allowing direct one-step bioconjugation of active species, is reported using an ionic liquid (IL) dissolution and regeneration process. Films and bead architectures were prepared and used as immobi…
Abstract Hole transport properties in high‐purity single crystal CVD diamond samples were studied using the time of flight technique with optical excitation of the carriers. The measurements were taken at different temperatures in the interval 80–470 K. By varying the intensity of the optical excitation over several o…
We propose a novel model for the shear failure of a glued interface between two solid blocks. We model the interface as an array of elastic beams which experience stretching and bending under shear load and break if the two deformation modes exceed randomly distributed breaking thresholds. The two breaking modes can b…
Modelling heat transfer of carbon nanotubes is important for the thermal management of nanotube-based composites and nanoelectronic devices. By using a finite element method for three-dimensional anisotropic heat transfer, we have simulated the heat conduction and temperature variations of a single nanotube, a nanotub…
In this study, single-walled carbon nanotube and bisphenol-A-polycarbonate composite beams were fabricated by a solution mixing process and dynamic (cyclic) load tests were performed to characterize energy dissipation. We report up to an order of magnitude (>1000%) increase in loss modulus of the polycarbonate…
The infrared conductivity $\ensuremath{\sigma}(\ensuremath{\omega})$ of ${\mathrm{Na}}_{x}\mathrm{Co}{\mathrm{O}}_{2}$ is studied as a function of doping and temperature for $0.5\ensuremath{\leqslant}x\ensuremath{\leqslant}1$. A far-infrared peak (FIP) in $\ensuremath{\sigma}(\ensuremath{\omega})$, which coexists with…
Superconductivity in the potassium osmium oxide KOs2O6 crystallizing in the beta-pyrochlore structure is studied by means of electrical resistivity, magnetic susceptibility and specific heat. It is the second superconductor in the family of pyrochlore oxides, following the alfa-type pyrochlore oxide Cd2Re2O7 which is…
Contrasting views: Entrapment of a paramagnetic shift reagent for water protons inside liposomes dramatically improves the sensitivity of chemical exchange saturation transfer agents. The chemical shift of the water entrapped within the liposomes, relative to bulk water, depends upon the nature and concentration of th…
We present results of molecular simulations that predict the phases formed by self-assembly of nanorods functionalized by a polymer "tether." Microphase separation of the immiscible tethers and rods coupled with the liquid crystal ordering of the rods induces the formation of a cubic phase, a smectic C phase, a tetrag…
The motion of molecules on solid surfaces is of interest for technological applications, but it is also a theoretical challenge. We study the deterministic and thermal diffusive dynamics of a dimer moving on a periodic substrate. The deterministic motion of the dimer displays strongly nonlinear features and chaotic be…
A novel method is developed to enable the formation, positioning and patterning of individual metal nano-clusters with controllable and monodispersed sizes down to 1-2 nm-scale. Among wide range of potential applications, the nanoparticle arrays are used for deterministic synthesis of monodispersed single walled carbo…
We have performed a detailed study of the conductance characteristics obtained by point contact junctions realized between a normal Pt/Ir tip and syntered RuSr2GdCu2O8 (Ru-1212) samples. Indeed, this compound is subject of great interest due to the coexistence of both magnetic order and bulk superconductivity. In our…
A magnetoelectric (ME) laminate composite consisting of a symmetric longitudinally poled piezoelectric Pb(Mg1∕3Nb2∕3)O3–PbTiO3 crystal and two longitudinally magnetized magnetostrictive Tb1−xDyxFe2 layers has been developed that has a notably superior ME voltage coefficient, relative to previous laminate configuration…
Abstract A multiple aromatic ether linked phthalonitrile was synthesized and characterized. The oligomeric phthalonitrile monomer was prepared from the reaction of an excess amount of bisphenol A with 4,4′‐difluorobenzophenone in the presence of K 2 CO 3 as the base in an N,N ‐dimethylformamide/toluene solvent mixture…
Two different silver colloids were prepared by chemical reduction of silver nitrate with trisodium citrate and hydroxylamine hydrochloride to compare their characteristics in relation to their possible use in surface-enhanced Raman scattering (SERS) spectroscopy. The morphology and plasmon resonance of the single nano…
We present calculations of the lattice thermal conductivity of silicon that incorporate several commonly used empirical models of the interatomic potential. Second- and third-order force constants obtained from these potentials are used as inputs to an exact iterative solution of the inelastic phonon Boltzmann equatio…
Abstract Summary: The average lateral dimensions of cellulose microfibrils in paper sheets can be determined from the width of X‐ray Bragg peaks at half the maximum height. The method assumes it is the finite size of the crystallite which is the main contributor to peak broadening in the directions orthogonal to the l…
Anodization of titanium in a fluorinated dimethyl sulfoxide (DMSO) and ethanol mixture electrolyte is investigated. The prepared anodic film has a highly ordered nanotube-array surface architecture. Using a 20 V anodization potential (vs Pt) nanotube arrays having an inner diameter of 60 nm and 40 nm wall thickness ar…
We survey results of computer simulations for the structure and dynamics of supercooled polymer melts and films. Our survey is mainly concerned with features of a coarse grained polymer model—a bead–spring model—in the temperature regime above the critical glass temperature T c of the ideal mode-coupling theory (MCT).…