Materials Literature
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T(2) contrast is gaining importance in high field strength MRI. We report a strategy for developing a T(2) contrast agent from paramagnetic metal ions synthesized within an engineered protein cage. The manganese-ferritin nanocomposite showed high T(2) relaxivity indicating its potential as an ultrasensitive T(2) contr…
The effect of grain boundaries and the crystal surface on the deformation and strength properties of nanocrystalline and nanosized materials, primarily metals, is reviewed. Basic experimental facts about the mechanical behavior of nanocrystal materials are presented and the observed findings are theoretically analyzed…
We have found diffusion of polyelectrolyte chains within multilayer films to be highly anisotropic, with the preferential chain motion parallel to the substrate. The degree of anisotropy was quantified by a combination of fluorescence recovery after photobleaching and neutron reflectometry, probing chain diffusion in…
O presente artigo discute o fenômeno da estagnação da energia nuclear no mundo. As causas são múltiplas e complexas, desde resistências sociais a elevados custos econômicos, passando pelos riscos ambientais ainda não equacionados, como mostrou o recente caso de Fukushima-Daiichi no Japão. As tentativas de promover a e…
We present an explanation for the puzzling spectral and transport properties of layered cobaltates close to the band-insulator limit, which relies on the key effect of charge ordering. Blocking a significant fraction of the lattice sites deeply modifies the electronic structure in a way that is shown to be quantitativ…
A simple and convenient protocol for the synthesis of the ligand 2,5-di(2-pyridyl)-1,3,4-thiadiazole (dptd) has been developed. Five new 2 : 1-type iron(II), cobalt(II), nickel(II) and copper(II) complexes have been prepared and structurally characterised, all of which feature the mononuclear trans-(N',N(1))(2) coordi…
We report an experimental investigation by electron paramagnetic resonance (EPR) spectroscopy on the properties of the E′ γ centers induced by β-ray irradiation in nanoparticles of amorphous SiO 2 (fumed silica) with mean diameters from 7 up to 40 nm. We found that the E′ γ centers are induced in all the fumed silica…
The physisorption of atomic hydrogen on graphene is investigated quantum mechanically using a semiempirical model for the lattice dynamics. A thermally averaged wave packet propagation describes the motion of the H atoms with respect to the membrane. Two graphene configurations, either supported on a silicone oxide su…
Vascular tissue engineering aims to regenerate blood vessels to replace diseased arteries for cardiovascular patients. With the scaffold-based approach, cells are seeded on a scaffold showing specific properties and are expected to proliferate and self-organize into a functional vascular tissue. Bioreactors can signif…
Nonsymmetric cyclopentene-based dithienylethenes, containing both thienyl and benzothienyl units, have been synthesized for the first time, employing intramolecular McMurry reaction as a key transformation to target compounds 10 and 16. Photochromic properties of these compounds were examined in toluene and acetonitri…
The preparation of model silver catalysts supported on highly oriented pyrolytic graphite is described, and the effect of the Ag particle size on the catalytic ethylene oxidation into ethylene oxide, studied by in situ XPS and mass spectrometry, is considered. For a mean particle diameter of 8 nm, the adsorbed oxygen…
Hexagonal boron nitride (hBN) has been recognized as an important material for various device applications and as a template for graphene electronics. Low-dimensional hBN is expected to possess rich physical properties, similar to graphene. The synthesis of wafer-scale semiconducting hBN epitaxial layers with high cry…
Nanotechnology has great promise for improving the therapeutic potential of medicinal molecules and related agents. In this study, silver nanoparticles of different sizes were synthesized in an ultrasonic field using the chemical reduction method with sodium borohydride as a reducing agent. The size effect of silver n…
Cyclic and flexible: A simple molecular design for controlling the packing structure and solid-state properties of π-conjugated skeletons is proposed. A subtle difference of the flexible alkylene linker chain lengths of cyclic terthiophene dimers leads to distinct packing structures, and accordingly the solid-state pr…
VO2(A) nanobelts are successfully synthesised through a facile hydrothermal approach using peroxovanadium (V) complexes and green solvent (ethanol) as the reducing agent without using any surfactants or templates. The as-obtained products were characterised by X-ray photoelectron spectroscopy, X-ray powder diffraction…
Continuous Wave (CW), pulse Electron Paramagnetic Resonance (EPR) and pulse Electron Nuclear Double Resonance (ENDOR) spectroscopies, in conjunction with UV-Vis and Infrared (IR) spectroscopies, are used to investigate the chemical reactivity of tetrahedrally coordinated Ti(3+) ions isomorphously substituted in the fr…
The effect of radiation on the oxidation state of Ce in high-quality single and polycrystalline ceria thin films is presented. The films were synthesized by molecular beam epitaxy and irradiated with high energy ionizing radiation of 2 MeV He + ions with varying flux density. The surface chemistry of the irradiated ce…
Although mechanisms of mesocrystal formation have been studied by several research groups, they are still under debate; Why do nanocrystals aggregate with their crystal axes aligned? In the present Article, the electric dipole–dipole interaction model has been studied for collisions between two particles by numerical…
Supramolecular nanoassemblies that respond to the presence of proteins are of great interest, as aberrations in protein concentrations represent the primary imbalances found in a diseased state. We present here a molecular design, syntheses, and study of facially amphiphilic dendrimers that respond to the presence of…
This Letter reports the fabrication and optical characteristics of large-area wideband anti-reflective micro/nano dual-scale (MNDS) structures. Microstructures, including inverted pyramids and V-shaped grooves, with controllable geometry sizes (e.g. width, pitch and depth) are fabricated by anisotropic wet etching of…