Materials Literature
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Different-sized silica nanoparticles (SiNPs) were functionalized by pH-responsive poly(2-(diisopropylamino)ethyl methacrylate) (PDP) via surface-initiated atom transfer radical polymerization (ATRP). The functionalized PDP-SiNPs were used to coat glass surfaces, polymeric nanofibers, and paper via simple coating metho…
This report describes novel perfluorocarbon (PFC) nanoemulsions designed to improve ex vivo cell labeling for 19F magnetic resonance imaging (MRI). 19F MRI is a powerful non-invasive technique for monitoring cells of the immune system in vivo, where cells are labeled ex vivo with PFC nanoemulsions in cell culture. The…
Reflection and refraction of electromagnetic waves by artificial periodic composites (metamaterials) can be accurately modeled by an effective medium theory only if the boundary of the medium is explicitly taken into account and the two effective parameters of the medium (the index of refraction and the impedance) are…
SrFe12O19/La1−xCaxMnO3 (SFO/LCMO) composites with x = 0.1 and 0.5 were synthesized via a two stage combined citrate precursor sol-gel and hydrothermal method. The structure and composition of the samples were refined from the X-ray diffraction patterns. The morphologies of the composites were investigated using transm…
Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation Dorothea Scheunemann, Sebastian Wilken, Jürgen Parisi, Holger Borchert; Towards depleted heteroju…
PURPOSE: Nanoparticle size is important in drug delivery. Clearance of nanoparticles by cells of the reticuloendothelial system has been reported to increase with increase in particle size. Further, nanoparticles should be small enough to avoid lung or spleen filtering effects. Endocytosis and accumulation in tumor ti…
Aromatic azo compounds have a wide range of industrial applications as dyes in optical and color-changing materials and can also be exploited in the design of new photodynamic molecular systems. The azo derivative 1-(cyclopropyl)diazo-2-naphthol was isolated in low-temperature cryogenic matrices, and its molecular str…
Many applications, such as magnets and SMES, are usually charged and discharged under a bias DC current, which may increase the AC loss. For their design, it is necessary to understand and predict the AC loss. This article analises the AC loss in magnet-like coils under DC bias contribution super-imposed to the AC cur…
Tubular anodic alumina membranes, containing self-ordered and circular pores below 100 nm, were used to produce sunflower oil in water emulsions. Span 80 and Tween 20 were used as surfactants in the dispersed phase and continuous phase, respectively. Both dead-end and cross-flow processes were investigated. Membrane p…
Using x-ray magnetic circular dichroism, we show that Co porphyrin molecules adsorbed on graphene-covered Ni surfaces possess a huge in-plane (IP) orbital magnetic moment of the Co ions, despite their fourfold coordination, even comparable in size to the spin moment. Both are antiferromagnetically coupled to the Ni sp…
Amphiphilic proteins and peptides can induce the formation of stable and metastable pores in membranes. Using coarse-grained simulations, we have studied the factors that affect structure of peptide-stabilized pores. Our simulations are able to reproduce the formation of the well-known barrel-stave or toroidal pores,…
Sodium salt heparins of both reactive and pharmaceutical grade were used as the reducing and stabilizing agents for the UV photochemical synthesis of gold nanoparticles. Reduction of chloroauric acid, HAuCl 4 , by heparin using UV irradiation as a catalyst is a simple, inexpensive method with direct biofunctionalizati…
La0.67Ba0.33MnO3 thin films were epitaxially grown on (111)-oriented 0.31Pb(In1/2Nb1/2)O3-0.35Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 ferroelectric single-crystal substrates. During ferroelectric poling and polarization rotation, the resistance of La0.67Ba0.33MnO3 films tracks the electric-field-induced in-plane strain of substra…
Cancer differentiation therapy is an attractive concept and has been clinically used to treat leukemia. However, it is limited to date for solid tumors. In this study, the pH-sensitive nanoparticles based on poly(amidoamine) (PAMAM) dendrimers are synthesized by coupling 3,4,5,6-tetrahydrophthalic anhydride with the f…
Within the framework of Hubbard model, a bowtie-shaped graphene nanoflake is identified to undergo an electric-field induced phase transition from an antiferromagnetic ground state. Unlike the case of half-metallic graphene nanoribbons, the electric field here leads to a non-magnetic state instead of ferromagnetic sta…
We report pulsed laser deposition (PLD) using a solid carbon source as a viable technique to obtain direct, transfer-free monolayer and bilayer graphene on SiO2. First, a 300 nm thick nickel film is deposited on a silicon dioxide layer (300 nm) grown in a Si substrate. Next, PLD of carbon is performed at 1010 °C. The…
A homologous series of the phthalocyanine-fullerene dyads, Cn-PcM(OFbaC60) (n = 6, 8, 10, 12; M = Cu , Ni , Co : 3a–3f) have been synthesized to obtain homeotropic alignment at rt and investigate the effects of spacer chain length (n = 6, 8, 10, 12) and central metal ( M = Cu , Ni , Co ) on the mesomorphism. Interesti…
ZnO/Zn0.85Mg0.15O asymmetric double quantum well (ADQW) and multiple quantum well (MQW) were fabricated with plasma assisted molecular epitaxy on c-plane sapphire, with their optical properties and optical pumped lasing characteristics studied. Due to the good crystalline quality, the lasing threshold of the MQW is ∼2…
Polylactide (PLA) is a class of promising biomaterials that hold great promise for various biological and biomedical applications, particularly in the field of vascular tissue engineering where it can be used as a fibrous mesh to coat the inside of vascular prostheses. However, its hydrophobic surface providing nonspe…
Using density-functional theory in the restricted-orientation approximation, we analyze the liquid-crystal patterns and phase behavior of a fluid of hard rectangular particles confined in a two-dimensional square nanocavity of side length H composed of hard inner walls. Patterning in the cavity is governed by surface-…