Materials Literature
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We study the role of electron correlations among Co 3d electrons contributing to the conduction band of a Kondo lattice compound, Ce2CoSi3, using high resolution photoemission spectroscopy and ab initio band structure calculations. Experimental results reveal signature of Ce 4$f$ states derived Kondo resonance feature…
We show that strong electromagnon peaks can be found in absorption spectra of non-collinear magnets exhibiting a linear magnetoelectric effect. The frequencies of these peaks coincide with the frequencies of antiferromagnetic resonances and the ratio of the spectral weights of the electromagnon and antiferromagnetic r…
Single crystalline $\text{Ba}{({\text{Fe}}_{1\ensuremath{-}x}{M}_{x})}_{2}{\text{As}}_{2}$ $(M=\text{Rh},\text{Pd})$ series have been grown and characterized by structural, thermodynamic, and transport measurements. These measurements show that the structural/magnetic phase transitions, found in pure ${\text{BaFe}}_{2…
Transferable ZnO tetrapods were grown by an aqueous solution method. An individual ZnO tetrapod-based sensor was fabricated by in situ lift-out technique and its ultraviolet (UV) and gas sensing properties were investigated. This single tetrapod-based device responds to the UV light rapidly and showed a recovery time…
Near-infrared (NIR) light is used to toggle photoswitches back and forth between their two isomers even though the chromophores do not significantly absorb this type of light. The reactions are achieved through a "remote control" process by using photon upconverting hexagonal NaYF(4) nanocrystals doped with lanthanide…
Deformation twinning is often mediated by partial dislocation activities at the twin boundary. Using molecular dynamics simulations, we have uncovered a new mechanism for the most commonly observed {1012}<101 1> deformation twinning in Mg and other hexagonal close-packed metals. Here the twin growth involves no defina…
Abstract Nanocomposites of waterborne polyurethane (WPU) with functionalized graphene sheets (FGS) were prepared by an in situ method. The morphology observed by transmission electron microscopy showed that pristine nanosize FGS can be finely dispersed in a WPU matrix so that it can efficiently improve the conductivit…
In an effort to maximize the liquid slip on superhydrophobic surfaces, we investigate the role of the nanoscale roughness on microscale structures by developing well-defined micro-nano hierarchical structures. The nonwetting stability and slip length on the dual-scale micro-nano structures are measured and compared wi…
“Chimie douce” based strategies allow, through the deep knowledge of materials chemistry and processing, the birth of the molecular engineering of nanomaterials. This feature article will highlight some of the main research accomplishments we have performed during the last years. We describe successively the design an…
A kinetic model for the elastoplastic dynamics of a jammed material is proposed, which takes the form of a nonlocal--Boltzmann-like--kinetic equation for the stress distribution function. Coarse graining this equation yields a nonlocal constitutive law for the flow, exhibiting as a key dynamic quantity the local rate…
Density functional theory and quantum Monte Carlo simulations reveal that the structure of the Stone-Wales (SW) defect in graphene is more complex than hitherto appreciated. Rather than being a simple in-plane transformation of two carbon atoms, out-of-plane wavelike defect structures that extend over several nanomete…
Abstract Nanoparticles of NaGdF 4 doped with trivalent erbium (Er 3+ ) and ytterbium (Yb 3+ ) are prepared by a modified thermal decomposition synthesis from trifluoroacetate precursors in 1‐octadecene and oleic acid. The nanoparticles emit visible upconverted luminescence on excitation with near‐infrared light. To mi…
One-dimensional iodide-bridged mixed-valence binuclear platinum complexes (the so-called "MMX chains") and their Pt(III) dimer precursors were investigated with (129)I Mossbauer spectroscopy. Spectra consisting of two sets of octuplets were observed at low temperatures for a neutral MMX chain complex, Pt(2)(dtp)(4)I (…
ZnS:Mn thin films were deposited on quartz, Si (polycrystalline), and glass substrates using a chemical bath deposition (CBD) method in an aqueous solution containing ethylene diamine tetra acetic acid disodium salt (Na<sub>2</sub>EDTA) as the complexing agent for zinc ions and thioacetamide (TAA) as the s…
The optical and electrical characteristics of pure, sodium- and lithium-doped potassium hydrogen tartrate crystals grown by the gel technique are reported. An optical absorption study conducted in the UV–Vis range of 200–800 nm reveals the transparency of these crystals in the entire visible range but not in the ultra…
Abstract Iron salts have been doped into emeraldine base (EB) successfully using a chemical route. Both FeCl 3 and FeSO 4 were doped separately into EB in acetonitrile with metal ion and tetramer in the ratio of 4 : 1. The doped samples were characterized by UV‐vis absorption, Mössbauer and fourier transform infrared…
Os Neossolos Regolíticos apresentam baixo potencial de uso devido a sua pequena profundidade efetiva, à presença de pedregosidade/rochosidade, ao contato lítico próximo à superfície e à ocorrência frequente em terrenos declivosos. Análises mais detalhadas são necessárias para a melhor interpretação desses solos, visto…
Abstract In this study, corona discharge was applied to optimize the desizing of polyvinyl alcohol (PVA) on cotton fabric. The weight of sized fabric decreased slightly when the PVA sized fabric was treated by corona discharge. Percent desizing rate (PDR) of PVA sized fabric increased evidently after the fabric was su…
A nanocapsule for safe and effective methane storage is investigated by the method of molecular dynamics. The mass content of methane in the nanocapsule reaches the value of 14.5 mass%. The nanocapsule consists of two parts: a locking chamber and a storage area. The locking chamber is the nanotube (10.10), open at one…
Abstract Chitosan (CS) is a biocompatible, biodegradable, and nontoxic polysaccharide polymer. It dissolves in water only if the pH is lower than 6.5. To extend its range of application, many water‐soluble derivatives have, therefore, been prepared. In this research, chitosan‐vitamin C complexes (CSVC) were synthesize…