Materials Literature
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This article reports on the preparation of polystyrene (PS), poly(methyl methacrylate) (PMMA), and poly(2-hydroxyethyl methacrylate) (PHEMA) ultrathin grafts on gold substrates modified by 4-benzoylphenyl (BP) moieties derived from the electroreduction of the parent diazonium salt BF(4)(-), (+)N(2)-C(6)H(4)-CO-C(6)H(5…
Eucalyptus globulus -based paper sheets were coated with chitosan and a water-soluble chitosan derivative on a pilot-size press machine. Different coating weights were attained by the deposition of 1−5 coating layers. The morphological, mechanical, barrier, and optical properties as well as the paper aging and inkjet…
The nature of optical excitation and the degree of intramolecular charge transfer (ICT) as well as the dynamics of excited ICT states of two new tribranched donor-pi-acceptor molecules with acceptor-terminated (DA(3)) and acceptor-centered (AD(3)) geometries have been investigated by steady-state and femtosecond time-…
Graphene provides a fascinating testbed for new physics and exciting opportunities for future applications based on quantum phenomena. To understand the coherent flow of electrons through a graphene device, we employ a nanoscale probe that can access the relevant length scales--the tip of a liquid-He-cooled scanning p…
We present a way to stabilize the Au phase supported on ceria by encapsulation of preformed Au nanoparticles (Au NPs) inside a porous ceria layer. The functionalization of the surface of the nanoparticles with carboxylic groups provides the link between the metal phase and the growing Ce(OH) x barrier, which is then t…
Abstract Archaeological objects are exposed to the action of micro‐organisms when they lay in a biologically active environment. The presence of iron sulfides in the corrosion system testifies in most cases that the degradation was influenced by sulfate‐reducing bacteria. Iron sulfides and other iron/sulfur‐containing…
Abstract Fluorocarbon plasma polymer films were prepared by RF magnetron sputtering in Argon from a balanced magnetron equipped with polytetrafluoroethylene (PTFE) target. Depending on the deposition conditions, primarily on the working gas pressure and distance between the target and the substrate, plasma polymer film…
Many natural composites, such as nacre or bone, achieve exceptional toughening enhancements through the rupture of noncovalent secondary bonds between chain segments in the organic phase. This "sacrificial bond" rupture dissipates enormous amounts of energy and reveals significant hidden lengths due to unraveling of t…
A phosphine-free selenium nanocrystal precursor solution has been synthesized by heating elemental selenium powder in 1-octadecene (ODE). This mixture was characterized by UV−vis absorption, photoluminescence excitation (PLE), nuclear magnetic resonance (NMR), Se X-ray absorption spectroscopy (Se-XAS), electron impact…
Pt nanoparticles grown on fully oxidized and partially reduced CeO x (111) thin films have been studied by scanning tunneling microscopy and X-ray photoelectron spectroscopy to understand the effect of redox properties and nanostructures of ceria supports on the growth of Pt. Deposition of 0.2 ML of Pt on CeO 2 at 300…
The titanium-manganese (TiMn) alloys have been extensively used in aerospace and hydrogen storage. In this study, the TiMn alloys with various manganese contents ranging from 2 to 12 wt % were prepared by using mechanical alloying and spark plasma sintering (SPS) techniques. The microstructures, mechanical properties…
The first molecular material with the coexistence of ferromagnetism, metal-like conductivity, and chirality has been prepared using an organic/inorganic approach. In this case, a two-dimensional packing of chiral organic radical cations (responsible for both the electrical conductivity and optical activity) was assemb…
We present the first demonstration of the nonmagnetic catalyzed synthesis of narrow-chirality distributed single-walled carbon nanotubes (SWNTs). Based on the systematic investigation using different combinations of catalyst types (magnetic or nonmagnetic) and chemical vapor deposition (CVD) methods (thermal CVD (TCVD…
The conjugation of biomolecules such as proteins and peptides to semiconductor quantum dots (QD) is a critical step in the development of QD-based imaging probes and nanocarriers. Such protein-QD assemblies can have a wide range of biological applications including in vitro protein assays and live-cell fluorescence im…
Hierarchical templates with raspberry-like and strawberry-like features were prepared by synthetically joining appropriately functionalized commercially available polystyrene (PS) latex spheres together. Two different coupling reactions were used to form the hierarchical templates: carbodiimide-assisted coupling of CO…
Polyimides are widely used for the external surfaces of spacecraft. In low Earth orbit (LEO), they are exposed to atomic oxygen (AO) and to problems of electrostatic discharge (ESD). This work demonstrates that liquid-phase deposition (LPD) of titania creates a protective coating on Kapton polyimide that is effective…
We demonstrate here a controllable variation in the Casimir force. Changes in the force of up to 20% at separations of ~100 nm between Au and AgInSbTe (AIST) surfaces were achieved upon crystallization of an amorphous sample of AIST. This material is well known for its structural transformation, which produces a signi…
Several dissociated and two non-dissociated adsorption structures of the phenol molecule on the Si(001)-(2 \times 1) surface are studied using density functional theory with various exchange and correlation functionals. The relaxed structures and adsorption energies are obtained and it is found that the dissociated st…
Unlike c-plane nitrides, ``non-polar" nitrides grown in e.g. the a-plane or m-plane orientation encounter anisotropic in-plane strain due to the anisotropy in the lattice and thermal mismatch with the substrate or buffer layer. Such anisotropic strain results in a distortion of the wurtzite unit cell and creates diffi…
Albeit structurally and electronically very similar, at low temperature the quasi-one-dimensional vanadium sulfide BaVS3 shows a metal-to-insulator transition via the appearance of a charge-density-wave state, while BaVSe3 apparently remains metallic down to zero temperature. This different behavior upon cooling is st…