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Synthesis and Properties of Charge-Ordered Thallium Halide Perovskites, CsTl + 0.5 Tl 3+ 0.5 X 3 (X = F or Cl): Theoretical Precursors for Superconductivity?

M. Retuerto、Thomas J. Emge、Joke Hadermann 等 17 位作者2013-09-18Chemistry of Materials

Recently, CsTlCl 3 and CsTlF 3 perovskites were theoretically predicted to be potential superconductors if they were optimally doped. The syntheses of these two compounds together with a complete characterization of the samples are reported. CsTlCl 3 was obtained as orange crystals in two different polymorphs: a tetra…

Inorganic Chemistry and MaterialsMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Nonlocal Modeling in High-Velocity Impact Failure of 6061-T6 Aluminum

F. R. Ahad、K. Enakoutsa、K. N. Solanki 等 4 位作者2013-09-18arXiv

In this paper, we present numerical simulations with local and nonlocal models under dynamic loading conditions. We show that for finite element (FE) computations of high-velocity, impact problems with softening material models will result in spurious post-bifurcation mesh dependency solutions. To alleviate numerical…

Materials Science

Epitaxial aluminum contacts to InAs nanowires

N. L. B. Ziino、P. Krogstrup、M. H. Madsen 等 8 位作者2013-09-18arXiv

We report a method for making epitaxial superconducting contacts to semiconducting nanowires. The temperature and gate characteristics demonstrate barrier-free electrical contact, and the properties in the superconducting state are investigated at low temperature. Half-covering aluminum contacts are realized without t…

Mesoscale and Nanoscale PhysicsMaterials ScienceSuperconductivity

Optical conductivity spectra of the rattling phonons and charge carriers in type-VIII clathrate Ba$_8$Ga$_{16}$Sn$_{30}$

K. Iwamoto、T. Mori、S. Kajitani 等 9 位作者2013-09-18arXiv

We have investigated optical conductivity spectra of $n$- and $p$-type Ba$_8$Ga $_{16}$Sn$_{30}$ ($α$-BGS) with type-VIII clathrate structure, at temperatures from 296\,K down to 6\,K with a terahertz time-domain spectrometer (0.2\,-\,2.5\,THz). The continuous spectra contributed from charge carriers are dispersive in…

Materials Science

Local sheet conductivity and sheet current density mapping using a single scanning voltage probe

Weigang Wang、Malcolm R. Beasley2013-09-18arXiv

We demonstrate how a single scanning voltage probe can be used to map the local conductivity and current density in a thin film with no a priori knowledge of the geometry of the electrical contacts. With state-of-the-art scanning voltage probes, under appropriate conditions such mapping should be possible down to nano…

Materials Science

The Sub-bandgap Photoconductivity in InGaAs:ErAs Nanocomposites

W-D. Zhang、E. R. Brown2013-09-18arXiv

The photoconductions of ultrafast InGaAs:ErAs nanocomposites at low temperatures were investigated. The parabolic Tauc edge as well as the exponential Urbach tail are identified in the absorption spectrum. The Tauc edge supports that the density of states at the bottom of conduction band is proportional to the square…

Materials Science

Exact spectral function for hole-magnon coupling in a ferromagnetic CuO 3 -like chain

Krzysztof Bieniasz、Andrzej M. Oleś2013-09-18Physical Review B

We present the exact spectral function for a single oxygen hole with spin opposite to ferromagnetic order within a one-dimensional CuO${}_{3}$-like spin chain. We find that local Kondo-like exchange interaction generates five different states in the strong-coupling regime. It stabilizes a spin polaron which is a bound…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Predicting Cellulose Solvating Capabilities of Acid–Base Conjugate Ionic Liquids

Arno Parviainen、Alistair W. T. King、I. Mutikainen 等 8 位作者2013-09-18ChemSusChem

Different acid-base conjugates were made by combining a range of bases and superbases with acetic and propionic acid. Only the combinations that contained superbases were capable of dissolving cellulose. Proton affinities were calculated for the bases. A range, within which cellulose dissolution occurred, when combine…

Advanced Cellulose Research StudiesLignin and Wood ChemistryCatalysis for Biomass Conversion

Thermally Stable Autonomic Healing in Epoxy using a Dual‐Microcapsule System

Henghua Jin、Chris L. Mangun、Anthony Griffin 等 6 位作者2013-09-18Advanced Materials

Self-healing is achieved with a dual-microcapsule system utilizing epoxy-amine chemistry in a high temperature cured thermosetting epoxy polymer. One capsule contains a modified aliphatic polyamine prepared by vacuum infiltration of polyoxypropylenetriamine into hollow polymeric microcapsules. The second capsule conta…

Flame retardant materials and propertiesSynthetic Organic Chemistry MethodsPolymer composites and self-healing

Optical and magnetic properties of Mg-doped ZnFe2O4 nanoparticles prepared by rapid microwave combustion method

A. Manikandan、J. Judith Vijaya、M. Sundararajan 等 6 位作者2013-09-18Superlattices and Microstructures

Mg-doped ZnFe2O4 samples were prepared by a microwave combustion method. The obtained samples were characterized by powder X-ray diffraction (XRD), high resolution scanning electron microscopy (HR-SEM), energy dispersive X-ray analysis, UV–Visible diffuse reflectance spectra (DRS), photoluminescence (PL) spectra and v…

Magnetic Properties and Synthesis of FerritesMultiferroics and related materialsIron oxide chemistry and applications

Anisotropic Noble Metal Nanocrystal Growth: The Role of Halides

Samuel E. Lohse、Nathan D. Burrows、Leonardo Scarabelli 等 5 位作者2013-09-18Chemistry of Materials

Anisotropic (nonspherical) metal nanoparticles are of widespread research interest because changing the shape of metals at the nanoscale can provide access to materials with unique optical, electronic, and catalytic properties. The development of seeded growth syntheses has provided researchers unprecedented access to…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and Applicationsnanoparticles nucleation surface interactions

Controlled Growth of High-Quality Monolayer WS 2 Layers on Sapphire and Imaging Its Grain Boundary

Yù Zhang、Yanfeng Zhang、Yanfeng Zhang 等 16 位作者2013-09-18ACS Nano

Atomically thin tungsten disulfide (WS2), a structural analogue to MoS2, has attracted great interest due to its indirect-to-direct band-gap tunability, giant spin splitting, and valley-related physics. However, the batch production of layered WS2 is underdeveloped (as compared with that of MoS2) for exploring these f…

Graphene research and applicationsMXene and MAX Phase Materials2D Materials and Applications

Electrical and magnetic orders in the magnetoelectric compound GaFeO3 : optimization through cationic doping

Alexandre Thomasson2013-09-17theses.fr (ABES)

Les concepts de matériaux multiferroïques et/ou magnétoélectriques permettent d’envisager de nouveaux dispositifs de mémoires plus performants et moins consommateurs d’énergie. Malheureusement de tels matériaux présentant ces propriétés à température ambiante ne sont pour l’instant pas disponibles. Les matériaux qui f…

Multiferroics and related materialsGa2O3 and related materials

Collagen-based coatings for biomaterials functionalization

Christophe Chaubaroux2013-09-17theses.fr (ABES)

La fonctionnalisation des biomatériaux est une stratégie probante et prometteuse développée pour favoriser l’intégration de biomatériaux dans un organisme vivant. Le dépôt de films multicouches de polyélectrolytes est une méthode de fonctionnalisation de surfaces particulièrement adaptée au recouvrement d’implants. Ce…

Collagen: Extraction and Characterization

On Polymer Nanocomposites Structure

Yu. G. Kozlov2013-09-17Apple Academic Press eBooks

The experimental analysis of particulate-filled nanocomposites butadienestirene rubber/fullerene-containing mineral (nanoshungite) was fulfilled with the aid of force-atomic microscopy, nanoindentation methods and computer treatment. The theoretical analysis was carried out within the frameworks of fractal analysis. I…

Material Properties and ApplicationsAdvanced Theoretical and Applied Studies in Material Sciences and GeometryAdsorption, diffusion, and thermodynamic properties of materials

5. Stabilization Process of PAN Nanofibers

B. Noroozi S. Rafiei2013-09-17Apple Academic Press eBooks

Carbon fibers are one of the most famous kinds of carbonaceous materials due to their special characteristics such as high conductivity, strength and modulus [1, 2]. They are typically produced either by pyrolyzing fibers spun from an organic precursor (e.g., Polyacrylonitrile (PAN), polyimide, mesophase pitch,…) or b…

Fiber-reinforced polymer compositesGraphene research and applicationsSupercapacitor Materials and Fabrication