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Micellar Interpolyelectrolyte Complexes with a Compartmentalized Shell

Christopher V. Synatschke、Tina I. Löbling、Melanie Förtsch 等 6 位作者2013-08-14Macromolecules

We investigate the formation of micellar interpolyelectrolyte complexes (IPECs) from multicompartment micelles (MCMs) of polybutadiene- block -poly(1-methyl-2-vinylpyridinium methylsulfate)- block -poly(methacrylic acid) (BVqMAA) triblock terpolymers and polycations of opposite charge. As cationic material, predominan…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Synthesis of novel trithiocarbonate and allyl sulfide containing monomers

Christopher R. Fenoli、Christopher N. Bowman2013-08-14Polymer Chemistry

A novel, mild, and high yielding synthesis is developed for trithiocarbonate and allyl sulphide-containing AFT (addition–fragmentation termination) monomers. The image illustrates the novel core, linker, and end groups of the monomer array crosslinked by PETMP, through which polymer films of low stress and capable of…

Advanced Polymer Synthesis and CharacterizationSynthetic Organic Chemistry MethodsSynthesis and properties of polymers

Crystal Structures of Hereditary Vitamin D-Resistant Rickets-Associated Vitamin D Receptor Mutants R270L and W282R Bound to 1,25-Dihydroxyvitamin D3 and Synthetic Ligands

Makoto Nakabayashi、Yoshito Tsukahara、Yukiko Iwasaki-Miyamoto 等 12 位作者2013-08-14Journal of Medicinal Chemistry

The vitamin D receptor (VDR), a member of the nuclear receptor superfamily, functions as a ligand-dependent transcription factor for various genes. Hereditary vitamin D-resistant rickets (HVDRR), an autosomal recessive disease, is caused by mutations in the VDR. In particular, the missense mutations R274L and W286R in…

Vitamin D Research StudiesEnzyme Structure and FunctionBiotin and Related Studies

Probing the Electronic Properties of Trimesic Acid Nanoporous Networks on Au(111)

Violeta Iancu、Kai‐Felix Braun、Koen Schouteden 等 4 位作者2013-08-14Langmuir

Nowadays molecular nanoporous networks have numerous uses in surface nanopatterning applications and in studies of host-guest interactions. Trimesic acid (TMA), a benzene derivative with three carboxylic groups, is a marvelous building block for forming 2D H-bonded porous networks. Here, we report a low-temperature st…

Mesoporous Materials and CatalysisNanocluster Synthesis and ApplicationsSurface Chemistry and Catalysis

Colloidal Stability of Self-Assembled Monolayer-Coated Gold Nanoparticles: The Effects of Surface Compositional and Structural Heterogeneity

Rixiang Huang、Randy P. Carney、Francesco Stellacci 等 4 位作者2013-08-14Langmuir

Surface heterogeneity plays an important role in controlling colloidal phenomena. This study investigated the self-aggregation and bacterial adsorption of self-assembled monolayer coated gold nanoparticles (AuNPs) with different surface compositional and structural heterogeneity. Evaluation was performed on AuNPs coat…

Polymer Surface Interaction StudiesElectrochemical Analysis and ApplicationsElectrostatics and Colloid Interactions

Intrinsic plasma rotation determined by neoclassical toroidal plasma viscosity in tokamaks

Youwen Sun、K. C. Shaing、Y. Liang 等 7 位作者2013-08-14Nuclear Fusion

Intrinsic toroidal plasma rotation due to the neoclassical toroidal plasma viscosity (NTV) effect induced by a three-dimensional helical magnetic field ripple in tokamaks is investigated in this paper. The intrinsic rotation is determined self-consistently by searching for the roots of the ambipolarity constraint, aft…

Ionosphere and magnetosphere dynamicsMagnetic confinement fusion researchFusion materials and technologies

Integrating Geology and Engineering: Implications for Production in the Bakken Play, Williston Basin

Cosima Theloy、Stephen A. Sonnenberg2013-08-14Unconventional Resources Technology Conference, Denver, Colorado, 12-14 August 2013

URTeC 1596247 A great variety of factors can influence production, and it is often difficult to discriminate how significant the impact of a single factor is. The unconventional nature of the Bakken tight oil play requires considering both geological and technological aspects, as completion designs evolved at a rapid…

Geological formations and processesClay minerals and soil interactionsGeotechnical and construction materials studies

Pre-vascularization of bone tissue-engineered constructs

Meadhbh Á. Brennan、Jean-Michel Davaine、Pierre Layrolle2013-08-14Stem Cell Research & Therapy

Vascularization remains one of the primary obstacles in the repair of bone defects. In the previous issue of Stem Cell Research &Therapy, Pedersen and colleagues show that co-immobilization of endothelial cells and mesenchymal stem cells in a tissue-engineered construct can achieve functional microvascular networks in…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Bacterial cellulose–kaolin nanocomposites for application as biomedical wound healing materials

Dwi Wanna、Catharina Alam、Diana M. Toivola 等 4 位作者2013-08-14Advances in Natural Sciences Nanoscience and Nanotechnology

This short communication provides preliminary experimental details on the structure–property relationships of novel biomedical kaolin–bacterial cellulose nanocomposites. Bacterial cellulose is an effective binding agent for kaolin particles forming reticulated structures at kaolin–cellulose interfaces and entanglement…

Advanced Cellulose Research StudiesWound Healing and TreatmentsTherapeutic Uses of Natural Elements

Porous and Nanorod-Like Coordination Polymers Assembled from a New V-Shaped Bis(1,2,4-triazolyl)tripyridine Ligand

Peng Yang、Ming‐Xing Li、Min Shao 等 7 位作者2013-08-14Crystal Growth & Design

Six complexes based on a new rigid V-shaped ligand, 2,6-bis(3-(pyrid-4-yl)-1,2,4-triazolyl)pyridine (2,6-H 2 bptp), namely, [Cd 4 (2,6-bptp) 2 ( d -cam)( l -cam)(H 2 O) 2 ] n ·4 n H 2 O ( 1 ), [Cd 2 (2,6-Hbptp) 2 (Hbtc)] n ·4 n H 2 O ( 2 ), [Zn(2,6-bptp)(H 2 O)] n · n H 2 O ( 3 ), [(Mo 8 O 26 )Cu 2 (2,6-H 2 bptp) 2 ]…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesPolyoxometalates: Synthesis and Applications

Shape- and size-dependent electronic capacitance in nanostructured materials

Maibam Birla Singh、Rama Kant2013-08-14Proceedings of the Royal Society A Mathematical Physical and Engineering Sciences

The shape and size are the two important geometrical factors that affect the electronic screening in nano-materials. Here, we develop an analytical theory for electronic capacitance based on Thomas–Fermi screening in conjunction with ‘multiple scattering method’ for arbitrary-shaped nanostructures including electronic…

Semiconductor materials and devicesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Nondestructive Characterization and Enzyme Cleaning of Painted Surfaces: Assessment from the Macro to Nano Level

Catarina Pereira、Tito Busani、Luı́s C. Branco 等 5 位作者2013-08-14Microscopy and Microanalysis

This work establishes a multiscale and multitechnique nondestructive approach as valid methodology for monitoring surface properties and evaluating the effectiveness of enzymatic removal of varnishes from paintings/polychrome artefacts. Mock-up samples (documented reconstructions of oil, tempera, and gilded layers on…

Corrosion Behavior and InhibitionForce Microscopy Techniques and ApplicationsCultural Heritage Materials Analysis

The role of electron-stimulated desorption in focused electron beam induced deposition

Willem F. van Dorp、Thomas W. Hansen、Jakob Birkedal Wagner 等 4 位作者2013-08-14Beilstein Journal of Nanotechnology

We present the results of our study about the deposition rate of focused electron beam induced processing (FEBIP) as a function of the substrate temperature with the substrate being an electron-transparent amorphous carbon membrane. When W(CO)6 is used as a precursor it is observed that the growth rate is lower at hig…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Structure and morphology of composites based on polyvinylidene fluoride filled with BaTiO3 submicrometer particles: Effect of processing and filler content

D. Olmos、F. Montero、Gustavo González‐Gaitano 等 4 位作者2013-08-14Polymer Composites

Composites based on polyvinylidene fluoride filled with barium titanate (PVDF/BT) submicrometric particles were prepared. To uniformly disperse BT particles within PVDF, high‐energy ball cryomilling was used. The effect of processing and the presence of BT particles on the structure and morphology of the composites we…

Advanced Sensor and Energy Harvesting MaterialsPolymer Nanocomposites and Properties

A temperature-dependent constitutive model for fiber-reinforced ceramic matrix composites and structural stress analysis

Xiguang Gao、Li Long、Song Yingdong2013-08-14International Journal of Damage Mechanics

A temperature-dependent constitutive model based on the continuum damage mechanics (CDM) theory is developed to model the stress/strain behavior of C/SiC composites. A formulation of Helmholtz free energy with initial modulus and tangent modulus is proposed to describe the bilinear constitutive behavior of such materi…

Advanced ceramic materials synthesisMechanical Behavior of CompositesHigh-Velocity Impact and Material Behavior

MHD stability of the pedestal in ITER scenarios

P. Maget、J.F. Artaud、M. Bécoulet 等 9 位作者2013-08-14Nuclear Fusion

The linear ideal magnetohydrodynamic (MHD) limits of the pedestal in\nITER scenarios associated with the preparation and realization of the\nnominal fusion gain Q = 10 (inductive scenario at 15 MA/5.3 T,\nhalf-field/half-current and intermediate H-mode scenario at 10 MA/3.5\nT), as well as the hybrid scenario at 12 MA…

Magnetic confinement fusion researchFusion materials and technologiesSuperconducting Materials and Applications

The effect of active ingredient‐containing chitosan/polycaprolactone nonwoven mat on wound healing: In vitro and in vivo studies

Meng‐Yi Bai、Tz‐Chong Chou、Jie‐Chang Tsai 等 4 位作者2013-08-14Journal of Biomedical Materials Research Part A

The use of an electrospun polycaprolactone (PCL) nonwoven mat that is coated with a layer of chitosan (CS) containing active ingredient [tea tree oil (TTO)] represents an effective strategy for producing functional dressings. CS-coated porous PCL nonwoven mat (CS3/PCLNM) with various concentrations of active ingredien…

Nanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical ApplicationsWound Healing and Treatments

High‐Intensity Focused Ultrasound‐Induced Thermal Effect for Solid Polymer Materials

Bo Liu、Hesheng Xia、Guoxia Fei 等 5 位作者2013-08-14Macromolecular Chemistry and Physics

In this study, high‐intensity focused ultrasound (HIFU)‐induced thermal effects for solid polymer materials are investigated systematically. Infrared camera imaging is used to monitor temperature changes. The effects of polymer structure, HIFU power, and sample thickness on the thermal effect are studied. The results…

Ultrasound and Hyperthermia ApplicationsUltrasound and Cavitation PhenomenaPhotoacoustic and Ultrasonic Imaging

DFT Calculation of Russell–Saunders Splitting for Lanthanide Ions Doped in Hexagonal (β)-NaYF4Nanocrystals

Ge Yao、Mary T. Berry、P. Stanley May 等 4 位作者2013-08-14The Journal of Physical Chemistry C

A systematic investigation is reported of the optimized geometry and electronic structure of trivalent lanthanide ions (Ln 3+ ) doped in hexagonal (β)-NaYF 4 nanocrystals in the basis of density functional theory with a spin polarization approach. A model Na 24 Y 23 Ln 1 F 96 nanocrystal with a single central lanthani…

Luminescence Properties of Advanced MaterialsInorganic Chemistry and MaterialsInorganic Fluorides and Related Compounds

One-Pot Solvothermal Synthesis of ZnSe·xN2H4/GS and ZnSe/N-GS and Enhanced Visible-Light Photocatalysis

Bitao Liu、Liangliang Tian、Yuhua Wang2013-08-14ACS Applied Materials & Interfaces

Doped-graphene has attracted considerable attention in many fields because doping element can alter the electrical properties of graphene. In this paper, we synthesized ZnSe·xN2H4/graphene (ZnSe·xN2H4/GS) and ZnSe/nitrogen-doped graphene (ZnSe/N-GS) nanocomposites with p-n junctions via one-pot solvothermal process. T…

Advanced Photocatalysis TechniquesGraphene research and applicationsMXene and MAX Phase Materials