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Biologically inspired membrane design with a heparin-like interface: prolonged blood coagulation, inhibited complement activation, and bio-artificial liver related cell proliferation

Shengqiang Nie、Min Tang、Chong Cheng 等 7 位作者2013-09-17Biomaterials Science

In the present work, inspired by the chemical structure of heparin molecules, we designed a polyethersulfone (PES) membrane with a heparin-like surface for the first time by physically blending sulfonated polyethersulfone (SPES), carboxylic polyethersulfone (CPES), and PES at rational ratios. Evaporation and phase-inv…

Polymer Surface Interaction StudiesMembrane Separation TechnologiesElectrospun Nanofibers in Biomedical Applications

Tuning Transverse Anisotropy in CoIII–CoII–CoIII Mixed-Valence Complex toward Slow Magnetic Relaxation

Dayu Wu、Xingxing Zhang、Ping Huang 等 6 位作者2013-09-17Inorganic Chemistry

Two cobalt mixed-valence complexes with different substituents have been prepared and structurally characterized by single-crystal X-ray diffraction to alter slow magnetic relaxation by tailoring the transverse anisotropy. The trinuclear complexes [(L(1))4Co3(H2O)2](NO3)4·CH3OH·5H2O (1-NO3) and [(L(2))4Co3(H2O)2](NO3)…

Lanthanide and Transition Metal ComplexesMagnetism in coordination complexesElectron Spin Resonance Studies

Adsorption, Activation, and Dissociation of Oxygen on Doped Oxides

Yi Cui、Xiang Shao、Matthias Baldofski 等 6 位作者2013-09-17Angewandte Chemie International Edition

Charge transfer in the presence of dopants is relevant for the adorption and activation of small molecules, such as O2 . Scanning tunneling microscopy and DFT calculations provide evidence for the formation of strongly bound superoxo species on chemically inert, Mo-doped CaO films. This oxygen surface species shows a…

Catalysis and Oxidation ReactionsCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Straightforward Oxidation of a Copper Substrate Produces an Underwater Superoleophobic Mesh for Oil/Water Separation

Na Liu、Yuning Chen、Fei Lu 等 8 位作者2013-09-17ChemPhysChem

A superhydrophilic and underwater superoleophobic Cu(OH)2-covered mesh with micro- and nanoscale hierarchical composite structures is successfully fabricated through a one-step chemical oxidation of a smooth-copper mesh. Such mesh, without any further modification, can selectively separate water from oil/water mixture…

Solar-Powered Water Purification MethodsSurface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical Applications

Magnetic and magnetocaloric properties of bulk dysprosium chromite

Austin McDannald、Lukasz Kuna、M. Jain2013-09-17Journal of Applied Physics

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation A. McDannald, L. Kuna, M. Jain; Magnetic and magnetocaloric properties of bulk dysprosium chromit…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

High Density Polyethylene Composites Reinforced with Hybrid Inorganic Fillers: Morphology, Mechanical and Thermal Expansion Performance

Runzhou Huang、Xinwu Xu、Sun Young Lee 等 6 位作者2013-09-17Materials

The effect of individual and combined talc and glass fibers (GFs) on mechanical and thermal expansion performance of the filled high density polyethylene (HDPE) composites was studied. Several published models were adapted to fit the measured tensile modulus and strength of various composite systems. It was shown that…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesPolymer Nanocomposites and Properties

Patchy Particle Self-Assembly via Metal Coordination

Yufeng Wang、Andrew D. Hollingsworth、Si Kyung Yang 等 6 位作者2013-09-17Journal of the American Chemical Society

Colloids with high-symmetry patches are functionalized with metal-coordination-based recognition units and assembled into larger chain architectures, demonstrating for the first time the use of metal coordination as a specific force in colloidal self-assembly. The cross-linked poly(styrene)-based patchy particles are…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Thermodynamically Stable Emulsions Using Janus Dumbbells as Colloid Surfactants

Fuquan Tu、Bum Jun Park、Daeyeon Lee2013-09-17Langmuir

One of the most important properties of emulsions is their stability. Most emulsions stabilized with molecular surfactants tend to lose their stability over time via different mechanisms. Although the stability of emulsions stabilized with homogeneous particles have been shown to be superior to that of surfactant-stab…

Proteins in Food SystemsPickering emulsions and particle stabilizationSurfactants and Colloidal Systems

Nongeminate and Geminate Recombination in PTB7:PCBM Solar Cells

Alexander Foertig、Juliane Kniepert、Markus Gluecker 等 7 位作者2013-09-17Advanced Functional Materials

A combination of transient photovoltage (TPV), voltage dependent charge extraction (CE), and time delayed collection field (TDCF) measurements is applied to poly[[4,8‐bis[(2‐ethylhexyl)oxy]benzo[1,2‐b:4,5‐b']dithiophene‐2,6‐diyl] [3‐fluoro‐2‐[(2‐ethylhexyl)carbonyl] thieno[3,4‐b]thiophenediyl]] (PTB7):[6,6]‐phenyl‐C71…

Conducting polymers and applicationsOrganic Electronics and PhotovoltaicsThin-Film Transistor Technologies

First-principles study of excitonic effects in Raman intensities

Yannick Gillet、Matteo Giantomassi、Xavier Gonze2013-09-17Physical Review B

The ab initio prediction of Raman intensities for bulk solids usually relies on the hypothesis that the frequency of the incident laser light is much smaller than the band gap. However, when the photon frequency is a sizable fraction of the energy gap, or higher, resonance effects appear. In the case of silicon, when…

Spectroscopy and Quantum Chemical StudiesPhase-change materials and chalcogenidesPhotoreceptor and optogenetics research

Properties and applications of chemically functionalized graphene

Monica F. Craciun、Ivan Khrapach、Matthew D. Barnes 等 4 位作者2013-09-17Journal of Physics Condensed Matter

The vast and yet largely unexplored family of graphene materials has great potential for future electronic devices with novel functionalities. The ability to engineer the electrical and optical properties in graphene by chemically functionalizing it with a molecule or adatom is widening considerably the potential appl…

Graphene research and applicationsSupercapacitor Materials and FabricationAdvancements in Battery Materials

Shape Alloys of Nanorods and Nanospheres from Self-Assembly

Xingchen Ye、Jaime A. Millan、Michael Engel 等 7 位作者2013-09-17Nano Letters

Mixtures of anisotropic nanocrystals promise a great diversity of superlattices and phase behaviors beyond those of single-component systems. However, obtaining a colloidal shape alloy in which two different shapes are thermodynamically coassembled into a crystalline superlattice has remained a challenge. Here we pres…

Pickering emulsions and particle stabilizationPhotonic Crystals and ApplicationsGold and Silver Nanoparticles Synthesis and Applications

Relation between exciton splittings, magnetic circular dichroism, and magnetization in wurtzite Ga 1−x Fe x N

J.-G. Rousset、J. Papierska、W. Pacuski 等 15 位作者2013-09-17Physical Review B

The question of the correlation between magnetization, band splittings, and magnetic circular dichroism (MCD) in the fundamental gap region of dilute magnetic semiconductors is examined experimentally and through model calculations, taking the case of wurtzite Ga${}_{1\ensuremath{-}x}$Fe${}_{x}$N as an example. Magnet…

Electronic and Structural Properties of OxidesZnO doping and propertiesMagnetic and transport properties of perovskites and related materials

Wide-Gap Semiconducting Graphene from Nitrogen-Seeded SiC

F. Wang、G. Liu、S. Rothwell 等 9 位作者2013-09-17Nano Letters

All carbon electronics based on graphene have been an elusive goal. For more than a decade, the inability to produce significant band-gaps in this material has prevented the development of graphene electronics. We demonstrate a new approach to produce semiconducting graphene that uses a submonolayer concentration of n…

Supercapacitor Materials and FabricationGraphene research and applicationsBoron and Carbon Nanomaterials Research

Size Effects of Raman and Photoluminescence Spectra of CdS Nanobelts

Chuan Hu、Xianghua Zeng、Jieya Cui 等 5 位作者2013-09-17The Journal of Physical Chemistry C

Different sizes of CdS nanobelts were synthesized at 800, 850, and 900 °C by the thermal evaporation of CdS powders on Au-coated silicon substrates and were used to study the size effects of Raman scattering and photoluminescent spectra. The Raman spectra of CdS nanobelts clearly exhibit first- and second-order longit…

Quantum Dots Synthesis And PropertiesNanowire Synthesis and ApplicationsChalcogenide Semiconductor Thin Films

Lattice and polarizability mediated spin activity in EuTiO_3

K. Caslin、R. K. Kremer、Z. Guguchia 等 6 位作者2013-09-17arXiv

EuTiO_3 is shown to exhibit novel strong spin-charge-lattice coupling deep in the paramagnetic phase. Its existence is evidenced by an, until now, unknown response of the paramagnetic susceptibility at temperatures exceeding the structural phase transition temperature T_S = 282K. The "extra" features in the susceptibi…

Materials Science

Spin-flip transitions and departure from the Rashba model in the Au(111) surface

Julen Ibañez-Azpiroz、Aitor Bergara、Evgeny Ya. Sherman 等 4 位作者2013-09-17arXiv

We present a detailed analysis of the spin-flip excitations induced by a periodic time-dependent electric field in the Rashba prototype Au(111) noble metal surface. Our calculations incorporate the full spinor structure of the spin-polarized surface states and employ a Wannier-based scheme for the spin-flip matrix ele…

Mesoscale and Nanoscale PhysicsMaterials Science

Defective graphene as promising anode material for Na-ion battery and Ca-ion battery

Dibakar Datta、Junwen Li、Vivek B. Shenoy2013-09-17arXiv

We have investigated adsorption of Na and Ca on graphene with divacancy (DV) and Stone-Wales (SW) defect. Our results show that adsorption is not possible on pristine graphene. However, their adsorption on defective sheet is energetically favorable. The enhanced adsorption can be attributed to the increased charge tra…

Chemical PhysicsMaterials Science

Fabrication of Nb/Al2O3/Nb Josephson Junctions using in situ Magnetron Sputtering and Atomic Layer Deposition

Rongtao Lu、Alan J. Elliot、Logan Wille 等 13 位作者2013-09-17arXiv

Atomic layer deposition (ALD) provides a promising approach for deposition of ultrathin low-defect-density tunnel barriers, and it has been implemented in a high-vacuum magnetron sputtering system for in situ deposition of ALD-Al2O3 tunnel barriers in superconductor-insulator-superconductor (SIS) Josephson junctions.…

Materials Science

Bandstructure and mobility variations in p-type Silicon nanowires under electrostatic gate field

Neophytos Neophytou、Oskar Baumgartner、Zlatan Stanojevic 等 4 位作者2013-09-17arXiv

The sp3d5s*-spin-orbit-coupled atomistic tight-binding (TB) model is used for the electronic structure calculation of Si nanowires (NWs), self consistently coupled to a 2D Poisson equation, solved in the cross section of the NW. Upon convergence, the linearized Boltzmann transport theory is employed for the mobility c…

Materials Science