Materials Literature
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The specific-heat difference between the O:H van der Waals bond and the H-O polar-covalent bond and the Coulomb repulsion between electron pairs on adjacent oxygen atoms determine the angle-length-stiffness relaxation dynamics of the hydrogen bond (O:H-O), which is responsible for the density and phonon-stiffness osci…
Enhancement to the electrochemical performance of supercapacitor electrodes were realized by incorporating highly porous conductive polymer films prepared with solution-processed polyaniline. The resultant nanostructures contained characteristic pores measuring 30-150 nm. Such electrodes generated from a solution of p…
Active center engineering at atomic level is a grand challenge for catalyst design and optimization in many industrial catalytic processes. Exploring new strategies to delicately tailor the structures of active centers and bonding modes of surface reactive intermediates for nanocatalysts is crucial to high-efficiency…
In this Communication, we report fabrication of ultrabright water-dispersible silicon nanoparticles (SiNPs) with quantum yields (QYs) up to 75% through a novelly designed chemical surface modification. A simple one-pot surface modification was developed that improves the photoluminescent QYs of SiNPs from 8% to 75% an…
We use scanning tunneling microscopy and X-ray spectroscopy to characterize the atomic and electronic structure of boron-doped and nitrogen-doped graphene created by chemical vapor deposition on copper substrates. Microscopic measurements show that boron, like nitrogen, incorporates into the carbon lattice primarily i…
Surfaces with anisotropic wettability, widely found in nature, have inspired the development of one‐dimensional water control on surfaces relying on the well‐arranged surface features. Controlling the wetting behavior of organic liquids, especially the motion of oil fluid on surfaces, is of great importance for a broa…
Copper-based nanoparticles are an important class of materials with applications as catalysts, conductive inks, and antimicrobial agents. Environmental and safety issues are particularly important for copper-based nanomaterials because of their potential large-scale use and their high redox activity and toxicity repor…
Carbon nanotubes (CNT) have numerous industrial applications and may be released to the environment. In the aquatic environment, pristine or functionalized CNT have different dispersion behavior, potentially leading to different risks of exposure along the water column. Data included in this review indicate that CNT d…
The "gold standard" for nanothermometry: The application of ultrasmall, near-IR-emitting fluorescent gold nanoclusters (AuNCs) for temperature sensing has been explored. AuNC-based fluorescent nanothermometry features excellent thermal sensitivity and simultaneous temperature sensing and imaging in HeLa cells.
A giant electrocaloric effect (ECE) near room temperature is reported in a lead‐free bulk inorganic material. By tuning Ba(ZrxTi1–x)O3 compositions which also exhibit relaxor ferroelectric response to near the invariant critical point, the Ba(ZrxTi1–x)O3 bulk ceramics at x ∼ 0.2 exhibit a large adiabatic temperature d…
Point defects in semiconductors can trap free charge carriers and localize excitons. The interaction between these defects and charge carriers becomes stronger at reduced dimensionalities, and is expected to greatly influence physical properties of the hosting material. We investigated effects of anion vacancies in mo…
In order to reduce the undesired effect of the electromagnetic interference, the developing of the materials with high capacity of electromagnetic interference (EMI) shielding has attracted a great attention to scientific and industrial communities during last two decades.Indeed, polymer carbon nanotubes (CNTs) nanoco…
Quasi-one-dimensional organic conductors (TMTCF)(2)X have various electric and magnetic properties. Although theoretical and experimental studies have suggested that (TMTTF)(2)Br has the properties of commensurate antiferromagnetism, details of the magnetic structure of this compound are unclear. Two types of antiferr…
Un modèle micromécanique est proposé pour une collection de zones cohésives insérées entre toutes les mailles d'une discrétisation de type éléments finis cohésifs-volumiques. Le principe de l'approche consiste à introduire un composite équivalent 'matrice-inclusions' comme une représentation de la discrétisation cohés…
Les études de structure et de spectroscopie réalisées sur les noyaux radioactifs durant les trois dernières décennies ont montré que la structure en couches des noyaux évolue vers la drip-line et que de nouveaux nombres magiques peuvent apparaître. Les noyaux doublement magiques sont très rares mais ils représentent d…
Keywords: supercooling, solidification, water, superhydrophobic surface, droplet Water is one of the most important element on earth. For scientists, it's a source of fascination for years because water has a lot of strange properties. For example, cold liquid water is less viscous but the density increases (maximum a…
O presente estudo avaliou a ação in vitro de diferentes nanopartículas de prata (nanoAg) sintetizadas pelo Instituto de Pesquisas Tecnológicas (IPT) e Universidade Federal de São Carlos (IFSC) e controles de sulfadiazina de prata, nitrato de prata e nanoAg comercial Sigma, frente a bactérias e leveduras. Os objetivos…
No presente trabalho foram realizadas a síntese e caracterizações estruturais, ópticas e espectroscópicas de materiais nanocompósitos na forma de guias de onda planares e pós de (100-x)SiO2-xNb2O5 dopados com íons lantanídeos pelo método sol-gel, para aplicação em Fotônica. Foi observada separação de fase controlada e…
Este trabalho apresenta um novo tomógrafo de espalhamento de fótons por efeito Compton para estudos de solos agrícolas em ambiente de campo. O seu desenvolvimento está fundamentado na física computacional, em uma instrumentação nuclear avançada e nas técnicas do espalhamento Compton. O posicionamento lado a lado da fo…
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