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Piezoresistive behavior of graphene nanoplatelets/carbon black/silicone rubber nanocomposite

Wenting Cai、Ying Huang、Dayue Wang 等 5 位作者2013-09-09Journal of Applied Polymer Science

ABSTRACT Silicon rubber (SR) filled with carbon black (CB) and carbon black (CB)/graphene nanoplatelets (GNPs) hybrid fillers are synthesized via a liquid mixing method. The effects of filler type on the electrical properties and piezoresistive properties (near the region of the percolation) of the conductive SR compo…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsDielectric materials and actuators

Flicker noise and magnetic resolution of graphene hall sensors at low frequency

Huilong Xu、Le Huang、Zhiyong Zhang 等 6 位作者2013-09-09Applied Physics Letters

Hall elements fabricated on chemical vapor deposited graphene exhibited high current- and voltage-related sensitivities due to its low intrinsic carrier density and high mobility about 5000 cm2/V s. Electric noise of the Hall elements was measured at room temperature and found to be largely Flicker noise at low freque…

Graphene research and applicationsQuantum and electron transport phenomenaMagnetic Field Sensors Techniques

Solution-Processed MoS x as an Efficient Anode Buffer Layer in Organic Solar Cells

Xiaodong Li、Wenjun Zhang、Yulei Wu 等 5 位作者2013-09-09ACS Applied Materials & Interfaces

We reported a facile solution-processed method to fabricate a MoSx anode buffer layer through thermal decomposition of (NH4)2MoS4. Organic solar cells (OSCs) based on in situ growth MoSx as the anode buffer layer showed impressive improvements, and the power conversion efficiency was higher than that of conventional P…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Breaking Bonds with Electrons and Protons. Models and Examples

Cyrille Costentin、Marc Robert、Jean‐Michel Savéant 等 4 位作者2013-09-09Accounts of Chemical Research

Besides its theoretical interest, the attention currently aroused by proton-coupled electron transfers (PCET reactions) has two main motives. One is a better understanding of biological processes in which PCET reactions are involved, Photosystem II as well as a myriad of other natural systems. The other is directed to…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsCO2 Reduction Techniques and Catalysts

Predicting Aggregation Rates of Colloidal Particles from Direct Force Measurements

F. Javier Montes Ruiz‐Cabello、Gregor Trefalt、Zita Csendes 等 8 位作者2013-09-09The Journal of Physical Chemistry B

Direct force measurements between negatively charged colloidal latex particles of a diameter of 1 μm were carried out in aqueous solutions of various inorganic monovalent and multivalent cations with the multiparticle colloidal probe technique based on the atomic force microscope (AFM). The observed force profiles wer…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsElectrostatics and Colloid Interactions

Synthesis and Characterization of Novel Epoxy Geopolymer Hybrid Composites

Giuseppina Roviello、Laura Ricciotti、Claudio Ferone 等 6 位作者2013-09-09Materials

The preparation and the characterization of novel geopolymer-based hybrid composites are reported. These materials have been prepared through an innovative synthetic approach, based on a co-reticulation in mild conditions of commercial epoxy based organic resins and a metakaolin-based geopolymer inorganic matrix. This…

Concrete and Cement Materials ResearchInnovative concrete reinforcement materialsMagnesium Oxide Properties and Applications

CO Adsorption on Defective Graphene-Supported Pt 13 Nanoclusters

Ioanna Fampiou、Ashwin Ramasubramaniam2013-09-09The Journal of Physical Chemistry C

Platinum (Pt) nanoclusters on graphene have been shown to possess superior catalytic activity and increased selectivity in a variety of electrochemical reactions compared with bulk Pt electrodes. In this work, we use density functional theory calculations to investigate the adsorption of CO on low-energy Pt 13 cluster…

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionCatalytic Processes in Materials Science

Efficient, Stable, and Reusable Silicoaluminophosphate for the One-Pot Production of Furfural from Hemicellulose

Prasenjit Bhaumik、Paresh L. Dhepe2013-09-09ACS Catalysis

Development of stable, reusable, and water-tolerant solid acid catalysts in the conversion of polysaccharides to give value-added chemicals is vital because catalysts are prone to undergo morphological changes during the reactions. With the anticipation that silicoaluminophosphate (SAPO) catalysts will have higher hyd…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesCatalysis for Biomass Conversion

Influence of Tungsten Doping on the Performance of Indium–Zinc–Oxide Thin-Film Transistors

Honglei Li、Mingyue Qu、Qun Zhang2013-09-09IEEE Electron Device Letters

Thin-film transistors (TFTs) with amorphous indium-zinc-tungsten-oxide (a-IZWO) channel layer and aluminum oxide gate insulator were prepared by radio-frequency magnetron sputtering. It was found that tungsten doping ratios had a significant influence on the performance of the TFTs, and the tungsten incorporation acte…

ZnO doping and propertiesThin-Film Transistor TechnologiesTransition Metal Oxide Nanomaterials

Cu2+-Responsive Bimodal (Optical/MRI) Contrast Agent for Cellular Imaging

Joo Hee Jang、Sankarprasad Bhuniya、Jongeun Kang 等 6 位作者2013-09-09Organic Letters

A water-soluble T1 magnetic resonance imaging contrast agent (1) has been synthesized. The bimodal contrast agent 1 responds to the Cu(2+) ion in living cells by enhancing the MRI modality signal whereas the optical signal gradually drops. This dual modality probe response depends on the cellular free copper ions in R…

Molecular Sensors and Ion DetectionNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Interaction Mechanism between Hydrophobic and Hydrophilic Surfaces: Using Polystyrene and Mica as a Model System

Ali Faghihnejad、Hongbo Zeng2013-09-09Langmuir

The interactions between hydrophobic and hydrophilic molecules, particles, or surfaces occur in many biological phenomena and industrial processes. In this work, polystyrene (PS) and mica were chosen as a model system to investigate the interaction mechanism between hydrophilic and hydrophobic surfaces. Using a surfac…

Polymer Surface Interaction StudiesMinerals Flotation and Separation TechniquesPickering emulsions and particle stabilization

A High-Content Screen Identifies Novel Compounds That Inhibit Stress-Induced TDP-43 Cellular Aggregation and Associated Cytotoxicity

Justin D. Boyd、J. Peter Lee-Armandt、Marisa S. Feiler 等 10 位作者2013-09-09SLAS DISCOVERY

TDP-43 is an RNA binding protein found to accumulate in the cytoplasm of brain and spinal cord from patients affected with amyotrophic lateral sclerosis (ALS) and frontotemporal lobar degeneration (FTLD). Nuclear TDP-43 protein regulates transcription through several mechanisms, and under stressed conditions, it forms…

biodegradable polymer synthesis and propertiesAmyotrophic Lateral Sclerosis ResearchNeurogenetic and Muscular Disorders Research

Growth of Crystalline Hydroxyapatite Thin Films at Room Temperature by Tuning the Energy of the RF-Magnetron Sputtering Plasma

Elvis O. López、Alexandre Mello、Henrique Sendão 等 11 位作者2013-09-09ACS Applied Materials & Interfaces

Right angle radio frequency magnetron sputtering technique (RAMS) was redesigned to favor the production of high-quality hydroxyapatite (HA) thin coatings for biomedical applications. Stoichiometric HA films with controlled crystallinity, thickness varying from 254 to 540 nm, crystallite mean size of 73 nm, and RMS ro…

Bone Tissue Engineering MaterialsFerroelectric and Piezoelectric MaterialsSilicone and Siloxane Chemistry

Controlling the Atomic Layer Deposition of Titanium Dioxide on Silicon: Dependence on Surface Termination

Stephen McDonnell、Roberto C. Longo、Oliver Seitz 等 12 位作者2013-09-09The Journal of Physical Chemistry C

Patterned fabrication depends on selective deposition that can be best achieved with atomic layer deposition (ALD). For the growth of TiO 2 by ALD using TiCl 4 and H 2 O, X-ray photoelectron spectroscopy reveals a marked difference in growth on oxidized and hydrogen-terminated silicon surfaces, characterized by typica…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesElectronic and Structural Properties of Oxides

High-pressure structural transformations of Sn up to 138 GPa: Angle-dispersive synchrotron x-ray diffraction study

Ashkan Salamat、Richard Briggs、Pierre Bouvier 等 10 位作者2013-09-09Physical Review B

The high-pressure behavior of elemental Sn has been studied by angle-dispersive synchrotron x-ray diffraction up to 138 GPa under quasihydrostatic conditions at room temperature. The data confirm the occurrence of a first-order phase transition at 10.8 GPa between $\ensuremath{\beta}$-Sn (Sn-II) ($I{4}_{1}/amd$) and a…

High-pressure geophysics and materialsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Tuning ligand electronics and peripheral substitution on cobalt salen complexes: structure and polymerisation activity

Linus Chiang、L.E.N. Allan、Juan Alcantara 等 6 位作者2013-09-09Dalton Transactions

A series of cobalt salen complexes, where salen represents an N2O2 bis-Schiff-base bis-phenolate framework, are prepared, characterised and investigated for reversible-termination organometallic mediated radical polymerisation (RT-OMRP). The salen ligands contain a cyclohexane diimine bridge and systematically altered…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Graphene/liquid crystal based terahertz phase shifters

Wu, Y.、Ruan, X.、Chen, C.-H. 等 12 位作者2013-09-09National University of Singapore

Due to its high electrical conductivity and excellent transmittance at terahertz frequencies, graphene is a promising candidate as transparent electrodes for terahertz devices. We demonstrate a liquid crystal based terahertz phase shifter with the graphene films as transparent electrodes. The maximum phase shift is 10…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsTerahertz technology and applications

Pore-scale dynamics of salt precipitation in drying porous media

Mansoureh Norouzi Rad、Nima Shokri、Muhammad Sahimi2013-09-09Physical Review E

We study the pore-scale dynamics of salt precipitation in three-dimensional drying porous media, utilizing high resolution x-ray microtomography and scanning electron microscopy. Our results illustrate that the salt precipitation patterns in drying porous media are nonuniform, manifesting the influence of the spatial…

Material Dynamics and PropertiesBuilding materials and conservationAerogels and thermal insulation

Correlation between intrinsic defects and electrical properties in the high-quality Cu2ZnSnS4 single crystal

Akira Nagaoka、Hideto Miyake、Tomoyasu Taniyama 等 5 位作者2013-09-09Applied Physics Letters

Temperature dependent Hall effect measurements from 20 to 300 K have been performed on the quaternary compounds Cu2ZnSnS4 (CZTS) single crystals. The conductivity mechanisms can be described by a two-path system using Mott variable range hopping and typical thermal activation conduction. The center level of the accept…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Chemical Bonding-Induced Low Dielectric Loss and Low Conductivity in High-K Poly(vinylidenefluoride-trifluorethylene)/Graphene Nanosheets Nanocomposites

Fei Wen、Zhuo Xu、Shaobo Tan 等 6 位作者2013-09-09ACS Applied Materials & Interfaces

Blending high-permittivity (εr) ceramic powders or conductive fillers into polymers to form 0-3-type composites has been regarded as one of the most promising processes to achieve high-dielectric-permittivity materials with excellent processing performance. The high dielectric loss and conductivity induced by the inte…

Advanced Sensor and Energy Harvesting MaterialsElectromagnetic wave absorption materialsDielectric materials and actuators