Materials Literature
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Platinum nanoflowers (Pt NFs) composed of an ordered assembly of nanoparticles were synthesized by an ethanol reduction of [PtCl6]2– under a reflux condition (85 °C) at pH 2.5 in the presence of PVP (molecular weight 10,000) as a structure‐directing agent. Optical and transmission electron microscopic (TEM) studies co…
Graphane is obtained by perfectly hydrogenating graphene. There exists an intermediate material, partially hydrogenated graphene (which we call hydrographene), interpolating from pure graphene to pure graphane. Employing a graph theoretical approach to the site-percolation model, we present an intuitive and physical p…
We have carried out first-principles density functional calculations on the mechanical response of two-dimensional (2D) monolayer group VI transition metal dichalcogenides (TMDs) to large elastic deformation. We find that the ultimate strength and the overall stress response of these 2D materials is strongly influence…
There are two main thrusts towards new permanent-magnet materials: improving extrinsic properties by nanostructuring and intrinsic properties by atomic structuring. Theory—both numerical and analytical—plays an important role in this ambitious research. Our analysis of aligned hard-soft nanostructures shows that soft-…
In this work the surface modification and functionalization of carbon nanotubes (CNTs) were investigated. CNTs were firstly treated by acid mixture H 2 SO 4 /HNO 3 to introduce the carboxylic group onto the surface of CNTs. This carboxylic group was used as reaction precursor in the functionalization. Two functional g…
With the development of nanotechnology and its application in biomedicine, studies on the interaction between nanoparticles and cells have become increasingly important. To understand the surface and size effects on cell interaction of nanoparticles, the cellular uptake behaviors of two series of gold nanoparticles (A…
Magnetic nanoparticles heated by an alternating magnetic field could be used to treat cancers, either alone or in combination with radiotherapy or chemotherapy. However, direct intratumoral injections suffer from tumor incongruence and invasiveness, typically leaving undertreated regions, which lead to cancer regrowth…
NiCo2O4 with higher specific capacitance is an excellent pseudocapacitive material. However, the bulk NiCo2O4 material prevents the achievement of high energy desity and great rate performance due to the limited electroactive surface area. In this work, NiCo2O4 nanosheet arrays were deposited on flexible carbon fabric…
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The three-dimensional metal-organic framework Gd(HCOO)3 is characterized by a relatively compact crystal lattice of weakly interacting Gd(3+) spin centers interconnected via lightweight formate ligands, overall providing a remarkably large magnetic:non-magnetic elemental weight ratio. The resulting magnetocaloric effe…
Cascade-sensitized 800 nm excited tri-doped upconversion nanoparticles (UCNPs) are developed for the first time. This novel class of UCNPs employ Nd3+ as an 800 nm photon sensitizer and Yb3+ as a bridging ion, and show strong upconversion emission without photobleaching. They outperform classical 980 nm excited UCNPs…
Practical implementation of one-dimensional semiconductors into devices capable of exploiting their novel properties is often hindered by low product yields, poor material quality, high production cost, or overall lack of synthetic control. Here, we show that a molten-salt flux scheme can be used to synthesize large q…
Nanoparticle research is a fascinating branch of science. The strongly size-related properties of nanoparticles offer uncountable opportunities for surprising discoveries. The often unexpected and unprecedented behavior of nanoparticles bears great potential for innovative technological applications, but also poses gr…
We report magnetic alignment of hexagonal boron nitride (hBN) platelets and the outstanding material properties of its polymer composite. The magnetically responsive hBN is produced by surface modification of iron oxide, and their orientations can be controlled by applying an external magnetic field during polymer cur…
Lanthanide (Ln) doped upconversion nanoparticles (UCNPs) have attracted enormous attention in the recent years due to their unique upconversion luminescent properties that enable the conversion of low-energy photons (near infrared photons) into high-energy photons (visible to ultraviolet photons) via the multiphoton p…
The formation of composite materials represents an efficient route to improve the performances of polymers and expand their application scopes. Due to the unique structure and remarkable mechanical, electrical, thermal, optical and catalytic properties, carbon nanotube and graphene have been mostly studied as a second…
Luminescent mechanochromism has been intensively studied in the past few years. However, the difference in the anisotropic grinding and the isotropic compression is not clearly distinguished in many cases, in spite of the importance of this discrimination for the application of such mechanochromic materials. We now re…
We report the crystal structure of a new nanocluster formulated as Au28(TBBT)20, where TBBT = 4-tert-butylbenzenethiolate. It exhibits a rod-like Au20 kernel consisting of two interpenetrating cuboctahedra. The kernel is protected by four dimeric "staples" (-SR-Au-SR-Au-SR-) and eight bridging thiolates (-SR-). The un…
Owing to their high energy density and power density, supercapacitors exhibit great potential as high-performance energy sources for advanced technologies. Recently, carbon nanomaterials (especially, carbon nanotubes and graphene) have been widely investigated as effective electrodes in supercapacitors due to their hi…
Flexoelectricity—the coupling between polarization and strain gradients—is a universal effect allowed by symmetry in all materials. Following its discovery several decades ago, studies of flexoelectricity in solids have been scarce due to the seemingly small magnitude of this effect in bulk samples. The development of…