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Electroless Nickel-Based Catalyst for Diffusion Limited Hydrogen Generation through Hydrolysis of Borohydride

Shannon Anderson、Egwu Eric Kalu2013-07-19Crystals

Catalysts based on electroless nickel and bi-metallic nickel-molybdenum nanoparticles were synthesized for the hydrolysis of sodium borohydride for hydrogen generation. The catalysts were synthesized by polymer-stabilized Pd nanoparticle-catalyzation and activation of Al2O3 substrate and electroless Ni or Ni-Mo platin…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction

Quantum Monte Carlo study of magnetic and superconducting properties of graphene

Hai‐Qing Lin、Tianxing Ma、Zhongbing Huang2013-07-19Mathematical Methods in the Applied Sciences

We apply quantum Monte Carlo technique to address the issue of high controllability of ferromagnetism in graphene and the issue of electron correlation driven superconductivity in graphene, by simulating the t − U − V Hubbard model on a honeycomb lattice. In the region of low electron band filling below the Van Hove s…

Physics of Superconductivity and MagnetismGraphene research and applicationsQuantum and electron transport phenomena

Orientation dependence of electron and phonon thermal conduction and its correlation with mechanical strength in aluminum interfaces

Vikas Samvedi、Vikas Tomar2013-07-19Journal of Applied Physics

This work presents an understanding of orientation dependence of electronic and phononic thermal conduction in Al interfaces. Focus is on quantifying the effect of interface orientation, the effect of tensile strain, and the effect of temperature on electronic and phononic thermal conduction across examined Al interfa…

Advanced ceramic materials synthesisThermal properties of materialsThermodynamic and Structural Properties of Metals and Alloys

Hydrothermal synthesis and characterization of nano‐petal nickel hydroxide

Wenxiu He、Yongqiang Zhang、Qianqing Liang 等 5 位作者2013-07-19Rare Metals

Abstract The current article reports a preparation method of nano‐petal nickel hydroxide, which was synthesized using urea as a precipitator by hydrothermal method. Nickel hydroxide samples with different micro‐structural characteristics were prepared by changing molar ratio of nickel/urea and reaction time. The prepa…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsCopper-based nanomaterials and applications

Platinum Nanopeapods: Spatial Control of Mesopore Arrangements by Utilizing a Physically Confined Space

Azusa Takai、Yasuhiro Sakamoto、Osamu Terasaki 等 5 位作者2013-07-19Chemistry - A European Journal

Spherical mesopores: Mesoporous Pt rods containing cage-type mesopores were prepared with porous anodic alumina membranes (PAAMs). It is noteworthy that spherical mesopores are aligned in the rods due to physical confinement by the PAAM channels. Both the mesopore alignment and the morphological control are realized s…

Block Copolymer Self-AssemblyAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Quasi-equilibrium size distribution of subcritical nuclei in amorphous phase change AgIn-Sb2Te

Kristof Darmawikarta、Bong-Sub Lee、R. M. Shelby 等 6 位作者2013-07-19Journal of Applied Physics

We investigate the effect of low temperature annealing or of extended storage at room temperature on the subsequent nucleation behavior of amorphous AgIn-incorporated Sb2Te (AIST), a material for phase change memories. Time-resolved reflectivity measurements during pulsed laser crystallization reveal the rates of soli…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

Influence of final treatment on the incubation period and antireflection properties of stain‐etched porous silicon

F. A. Rustamov、N.H. Darvishov、V. E. Bagiev 等 6 位作者2013-07-19physica status solidi (a)

The influence of composition of various solutions, applied for final treatment of Si wafers before stain‐etched porous silicon (PS) formation, on the incubation period and antireflective properties has been investigated. PS layers were obtained by chemical etching in HF:HNO3:CH3COOH modified solution at oxidant insuff…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Structural and mechanistic studies of theorf12gene product from the clavulanic acid biosynthesis pathway

K. Valegård、Aman Iqbal、Nadia J. Kershaw 等 14 位作者2013-07-19Acta Crystallographica Section D Biological Crystallography

Structural and biochemical studies of the orf12 gene product (ORF12) from the clavulanic acid (CA) biosynthesis gene cluster are described. Sequence and crystallographic analyses reveal two domains: a C-terminal penicillin-binding protein (PBP)/β-lactamase-type fold with highest structural similarity to the class A β-…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionBiochemical and Molecular Research

Broadband antireflective silicon carbide surface produced by cost-effective method

Aikaterini Argyraki、Yiyu Ou、Hai Yan Ou2013-07-19Optical Materials Express

A cost-effective method for fabricating antireflective subwavelength structures on silicon carbide is demonstrated. The nanopatterning is performed in a 2-step process: aluminum deposition and reactive ion etching. The effect, of the deposited aluminum film thickness and the reactive ion etching conditions, on the ave…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Assessment of genotoxicity and cytotoxicity of standardized aqueous extract from leaves of Erythroxylum cuneatum in human HepG2 and WRL68 cells line

RK Wesam、AN Ghanya、H. H. Mizaton 等 5 位作者2013-07-19Asian Pacific Journal of Tropical Medicine

OBJECTIVE: To investigate the cytotoxicity and the genotoxicity of standardized aqueous of dry leaves of Erythroxylum cuneatum (E. cuneatum) in human HepG2 and WRL68 cells. METHODS: The cytotoxicity of E. cuneatum extract was evaluated by both MTS and LDH assays. Genotoxicity study on E. cuneatum extract was assessed…

Ethnobotanical and Medicinal Plants StudiesPhytochemistry and Bioactive CompoundsPhytochemistry and biological activities of Ficus species

Microscopic origin of the magnetoelectronic phase separation in Sr-doped LaCoO 3

Zoltán Németh、András Szabó、K. Knı́žek 等 9 位作者2013-07-19Physical Review B

The nanoscopic magnetoelectronic phase separation in doped La${}_{1\ensuremath{-}x}$Sr${}_{x}$CoO${}_{3}$ perovskites was studied with local probes. The phase separation is directly observed by M\"ossbauer spectroscopy in the studied doping range of 0.05 $\ensuremath{\le}$ $x$ $\ensuremath{\le}$ 0.25 both at room temp…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

H 2 on corrugated graphene: Diffusion Monte Carlo calculations

M. C. Gordillo2013-07-19Physical Review B

The phase diagram of $para$-H${}_{2}$ on both one-layer and bilayer graphene was calculated by means of the diffusion Monte Carlo method. The zero-point energy of the carbon atoms in the substrate was taken into account. That inclusion had minor effects on the liquidlike or incommensurate branches of the phase diagram…

Graphene research and applicationsHydrogen Storage and MaterialsQuantum, superfluid, helium dynamics

Wide‐Spectral Photoresponse of Black Molybdenum Oxide Photodetector via Sub‐Bandgap Electronic Transition

Tsz‐Wai Ng、Qingdan Yang、Hin‐Wai Mo 等 6 位作者2013-07-19Advanced Optical Materials

Black molybdenum oxide (BMO) is prepared by annealing transparent MoO3. While recent efforts on other black oxides show that their black colour contributes little towards visible light harvesting, the presented BMO shows much-enhanced photoresponse over the UV–vis–IR regions. By sandwiching the BMO with suitable charg…

Advanced Photocatalysis TechniquesTransition Metal Oxide NanomaterialsGa2O3 and related materials

Electrical fatigue behaviour in lead zirconate titanate: an experimental and theoretical study

Mainak Bhattacharyya、A. Arockiarajan2013-07-19Smart Materials and Structures

A systematic investigation on electrical fatigue in lead zirconate titanate (PZT) is carried out for different loading frequencies. Experiments are conducted up to 106 cycles to measure the electrical displacement and longitudinal strain on bulk ceramics in the bipolar mode with large electrical loading conditions. A…

Advanced ceramic materials synthesisNumerical methods in engineeringUltrasonics and Acoustic Wave Propagation

Interfacial Self-assembly of NixCd1–xS/ODA Hybrids with Photoluminescent and Superhydrophobic Performance

Yan Zhang、Qiang Zhang、Cai‐Feng Wang 等 4 位作者2013-07-19Industrial & Engineering Chemistry Research

We report herein a simple strategy for fabricating two-dimensional (2D) petal-like Ni x Cd 1– x S/octadecylamine (ODA) hybrids exhibiting both photoluminescent and superhydrophobic properties via a facile liquid–liquid interfacial self-assembly technique. First, thioglycolic acid stabilized CdS quantum dots (QDs) dope…

Surface Modification and SuperhydrophobicityQuantum Dots Synthesis And PropertiesModular Robots and Swarm Intelligence

Analysis of buckling load of glass fiber/epoxy-reinforced plywood and its temperature dependence

Sung Woong Choi、Meixian Li、Woo Il Lee 等 4 位作者2013-07-19Journal of Composite Materials

There has been an increase in the use of fiber-reinforced composite materials in many areas. In particular, glass-fiber-reinforced composites have gained in popularity owing to their low cost, high-strength properties, durability, ease of repair, and being simple to form. This paper analyzes the buckling load for the…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesCellular and Composite Structures

Strain rate effect on the thermomechanical behavior of a thermoset shape memory polymer

Anqi Wang、Guoqiang Li、Harper Meng2013-07-19Smart Materials and Structures

Driven by conformational entropy, a shape memory polymer (SMP) is capable of memorizing typical programming information, such as level of induced strain, deformation sequence and temperature profile. Because strain rate is one of the variables during programming, it is desirable to know whether the strain rate effect…

Polymer composites and self-healingShape Memory Alloy TransformationsMarine Sponges and Natural Products

Flexible, Switchable Electrochromic Textiles

Dirk Schawaller、M. Voß、Volker Bauch 等 5 位作者2013-07-19Macromolecular Materials and Engineering

The construction of electrochromic multilayers on textiles is described. Polyester foils are sputtered with a thin layer of translucent indium tin oxide (ITO). On these ITO layers, WO3 and polyaniline (PANI), respectively, are deposited electrochemically in a continuous process. Both the PANI- and WO3-based materials…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Invariom refinement of a new monoclinic solvate of thiostrepton at 0.64 Å resolution

Kevin Pröpper、Julian J. Holstein、Christian B. Hübschle 等 5 位作者2013-07-19Acta Crystallographica Section D Biological Crystallography

A new monoclinic solvate containing two molecules of the thiopeptide antibiotic thiostrepton in the asymmetric unit has been crystallized in space group P2(1). Single-crystal diffraction data to a resolution of 0.64 Å were collected at the SLS synchrotron, allowing structure solution by direct methods and resolution o…

Porphyrin and Phthalocyanine ChemistryEnzyme Structure and FunctionChemical and Physical Properties in Aqueous Solutions