Study of Bimetallic Surfaces by Near Ambient Pressure X-ray Photoelectron Spectroscopy during CO Oxidation. [+ affiche]
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Materials Literature
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International
International
New binuclear Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Hg(II) Complexes of N2S2 tetradentate or N4S2 hexadentate symmetric Schiff base were prepared by the condensation of butane-1,4-diylbis(2-amino ethylcarbamodithioate) with 3-acetyl pyridine. The complexes having the general formula [M2LCl4] (where L=butane-1,4-…
International
With the help of quantum and chemical method of close coupling, finding of stable configuration of nanocomposite on the basis of "carbon nanotube and ceramics"is carried out. Rutile nanoparticle with surface (110) consisting of 148 atoms was considered as ceramic material. The criterion for stability was the enthalpy…
The results of experimental studies of porous silicon nanocomposites with biological materials: powder mineral phase of bone (hydroxyapatite) and biochemical solution identical to the natural tear fluid are presented in the work. Layers of porous silicon have been obtained in the process of electrochemical etching sil…
Results of study of the processes of change of electrophysical characteristics are presented at various operating modes of MOS-structures and the analysis of the most probable mechanisms of degradation of structures was spent. The gate dielectric was made from rare-earth oxides (high-k dielectrics). The estimation of…
In this publication, several six coordinate Co(III)-complexes are reported. The reaction of 2,3-butanedione monoxime with ethylenediamine or o-phenylenediamine in mole ratios of 2:1 gave the tetradentate imine-oxime ligands diaminoethane-N,N`-bis(2-butylidine-3-onedioxime) H2L1 and o-phenylenediamine-N,N`-bis(2-butyli…
International audience
International audience
New metal complexes of the ligands 2-benzamido benzothiazole(B1), and 2-actamido benzothiazole(B2) with metal ions Ni(II),and Co(II) were prepared in alcoholic medium. The prepared complexes were characterized by FT-IR and electronic spectroscopy, Magnetic susceptibility, Flame Atomic Absorption technique as well as e…
Bei der Entwicklung und Untersuchung neuer PNP-Pincer Komplexe ergibt sich das Problem, dass 2,6-Diaminopyridin als einziger Precursor in großen Mengen und kostengünstig verfügbar ist. Aus diesem Anlass stellte sich die Aufgabe einer Synthese von neuen 2,6-Diaminopyridinsystemen, welche die Eigenschaften der Komplexe…
International audience
(Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 + 0.04 wt% CeO2 lead-free ceramics were synthesized by conventional sintering process and the effect of calcination temperature on microstructure, dielectric and piezoelectric properties were investigated. Improved piezoelectric properties have been observed at 1,125℃ calcination temperatu…
The analytical method for nonlinear stochastic problem of creep solving for a plane taking into account the damage of the material and the third stage of creep is developed. Determinative creep equations are taken in accordance with the energy version of the nonlinear theory of a viscous flow in a stochastic form. Stoc…
"With the actual experimental realization of graphene samples, it became possible not only to exploit the special physical properties of graphene but also to exploit its technological applications. As the field developed, the discovery of other 2D materials occurred and this opened up access to a plethora of combinati…
International audience
The main purpose of construction organization (CO) is putting an object of a required quality into operation within the established time limit with the lowest labor and resources input. This aim remains relevant also in emergency situations. However, apart from the main tasks of CO in emergencies, there are additional…
Clays used for pottery education to physically challenged learners were mineralogically analysed to appraise their suitability both for usage in making pottery products and convenience for the learners. The suitability is alluded to the fact that the clays have undergone basic beneficiation which include grinding, rem…
Objectives: 21 sepiolite substances produced in China were investigated for the presence of asbestos in their materials. Materials and methods: In order to identify asbestos in sepiolite substances, test materials were analyzed using a transmission electron microscope equipped with energy dispersive X-ray spectrometer…