Materials Literature
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Three iron(II) complexes, [Fe(TPMA)(BIM)](ClO(4))(2)⋅0.5H(2)O (1), [Fe(TPMA)(XBIM)](ClO(4))(2) (2), and [Fe(TPMA)(XBBIM)](ClO(4))(2)⋅0.75CH(3)OH (3), were prepared by reactions of Fe(II) perchlorate and the corresponding ligands (TPMA=tris(2-pyridylmethyl)amine, BIM=2,2'-biimidazole, XBIM=1,1'-(α,α'-o-xylyl)-2,2'-biim…
Abstract Multiwalled carbon nanotubes (MWCNTs) were covalently functionalized with polyhedral oligomeric silsequioxane (POSS). The results of Fourier Transform Infrared Spectroscopy, Raman spectroscopy and Transmission Electron Microscopy indicated that POSS particles were grafted onto MWCNTs. The POSS content determi…
Mn-Ga alloys were produced by melt-spinning followed by various heat treatments. Although the as-rapidly quenched Mn-Ga melt-spun ribbons showed low remanence and coercivity, annealing of the ribbons resulted in an increase in the remanence and coercivity values. The optimally annealed Mn70Ga30melt-spun ribbon with th…
Etoposide (VP-16) is a hydrophobic anticancer agent inhibiting Topoisomerase II, commonly used in pediatric brain chemotherapeutic schemes as mildly toxic. Unfortunately, despite its appropriate solubilization in vehicle solvents, its poor bioavailability and limited passage of the blood-brain barrier concur to disapp…
We report a simple, controlled doping method for achieving n-type, intrinsic, and p-type lead sulfide (PbS) nanowires (NWs) grown by chemical vapor deposition without introducing any impurities. A wide range of carrier concentrations is realized by adjusting the ratio between the Pb and S precursors. The field effect…
Infrared signature management (IRSM) has been a primary aeronautical concern for over 50 years. Most strategies and technologies are limited by the second law of thermodynamics. In this article, IRSM is considered in light of theoretical developments over the last 15 years that have put the absolute status of the seco…
We demonstrate an effective method of reducing mobile ions in a silica nanoparticle (SN)-doped liquid crystal (LC) cell by alternating-current high-voltage pulse treatment (ACHVPT). In this method, the director distortion in LCs near the substrate creates a lifting force that moves the SNs toward the substrate. The mo…
The present contribution reports on the synthesis and controlled polymerization of a novel acrylamide monomer containing phosphonated moieties, namely diethyl-2-(acrylamido)ethylphosphonate. This monomer appears to be of great interest due to the phosphonated moieties, which can lead to a wide range of applications, a…
A martensitic transformation (MT) from a body-centered-cubic austenitic phase to a tetragonal martensitic phase has been found in Mn50Ni50−xSnx (0 ≤ x ≤ 11) alloys. The martensitic transformation temperature can be decreased by about 71.6 K by increasing the Sn concentration by 1 at. %. For 9 ≤ x ≤ 11, Mn50Ni50−xSnx f…
The analysis of photoinduced charge transfer (CT) processes in a particular SERS spectrum is not a trivial task since each system must be studied separately and no universal selection rules can be proposed for this kind of enhancement mechanism. Despite this, we found out in previous studies that the SERS-CT spectra o…
Carbon nanotubes show vast potential to be used as building blocks for photodetection applications. However, measurements of fundamental optical properties, such as the absorption coefficient and the dielectric constant, have not been accurately performed on a single pristine carbon nanotube. Here we show polarization…
In this study, the effect of ZnO buffer layer on the electrical properties of PbZrTiO3/BiFeO3 (PZT/BFO) multilayers has been reported. For this, PZT/BFO multilayers were spin-coated with and without ZnO buffer layer on platinized silicon wafers. X-ray diffraction results of both the films showed polycrystalline phase…
A simple chemical technique is implemented to fabricate a metal-dielectric colloidal crystal structure (MDCS) in order to enhance the otherwise weak Raman signals by combining the effects of localized surface plasmon resonance (LSPR) enhancement due to gold nanoparticles, precise field confinement of dielectric and ai…
AIM: The targeting efficiency of folate receptor-α (FR-α)-targeted high-density lipoprotein nanoparticles (HDL NPs) was evaluated in a syngeneic mouse model of ovarian cancer. MATERIALS & METHODS: Folic acid was conjugated to the surface of fluorescent-labeled HDL NPs. In vivo tumor targeting of folic acid-HDL NPs and…
Abstract Different micromechanical models which account for the presence of dispersed and agglomerated nanofillers, specifically carbon nanotubes (CNTs) and cellulose nanowhiskers (CWs), in a polymeric matrix and consider the effect of a percolation threshold on the elastic modulus of the composite are derived and com…
Nanostructures formed by phase separation improve the thermoelectric figure of merit in lead chalcogenide semiconductor alloys, with coherent nanostructures giving larger improvements than incoherent nanostructures. However, large coherency strains in these alloys drastically alter the thermodynamics of phase stabilit…
Here, we choose La-Ce-Pr-Nd industrial mischmetal with low purity as raw material to prepare La(Fe,Si)13-based magnetocaloric material and its hydride. It is demonstrated that the introduced impurities in the starting materials do not impair the formation of NaZn13-type structure. The multi-replacement of La by magnet…
We demonstrate dynamic spin injection into chemical vapor deposition (CVD) grown graphene by spin pumping from permalloy (Py) layers. Ferromagnetic resonance measurements at room temperature reveal a strong enhancement of the Gilbert damping at the Py/graphene interface, indeed exceeding that observed in Py/platinum i…
In magnetocaloric La(Fe,Si)13 alloys, it is known that hydrogen addition shifts the magnetic transition temperature TC near room temperature. By partial hydrogen desorption, TC can be adjusted precisely towards the working temperature of a magnetic cooling device. In this work, we studied the stability of partially de…
Fluorinated graphene has the possibility to achieve unique properties and functions in graphene. We propose a highly controlled fluorination method utilizing fluorine radicals in Ar/F2 plasma. To suppress ion bombardments and improve the reaction with fluorine radicals on graphene, the substrate was placed “face down”…