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Marked improvement in the stability of small molecule organic photovoltaics by interfacial modification using self-assembled monolayers to prevent indium diffusion into the active layer

Ming‐Chung Chen、Yi-Shiang Chiou、Jian‐Ming Chiu 等 5 位作者2013-01-01Journal of Materials Chemistry A

This work describes a simple process to improve the stability of small molecule organic photovoltaics (OPVs) that use poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as the hole transport layer (HTL), without reducing the power conversion efficiency (PCE). We investigated the effect of self-assembl…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsMolecular Junctions and Nanostructures

Efficient SO2 capture by amine functionalized PEG

Dezhong Yang、Minqiang Hou、Hui Ning 等 6 位作者2013-01-01Physical Chemistry Chemical Physics

Polyethylene glycols (PEGs) are a class of non-toxic, non-volatile, biocompatible, and widely available polymers. In this work, we synthesized N-ethyl-N-(2-(2-(2-methoxyethoxy)ethoxy)ethyl)-2-aminoethanol (EE3AE) that combines the properties of PEG and amines, and N-decyl-N-ethyl-2-aminoethanol (DEAE). Their performan…

Advanced Sensor and Energy Harvesting MaterialsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Enhanced Efficiency of Dye‐Sensitized Solar Cell by High Surface Area Anatase‐TiO2‐Modified P25 Paste

Mengmei Pan、Niu Huang、Xingzhong Zhao 等 5 位作者2013-01-01Journal of Nanomaterials

How to improve the conversion efficiency and the stability of dye‐sensitized solar cells (DSSCs) are two major problems. Furthermore, reduction of the manufacturing cost of DSSCs and large‐scale manufacture are also very important factors. As a raw material, commercial P25 would be used for large‐scale manufacture of…

TiO2 Photocatalysis and Solar CellsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Structure-related differences in the temperature-regulated fluorescence response of LCST type polymers

Sahika Inal、Jonas D. Kölsch、Leonardo Chiappisi 等 7 位作者2013-01-01Journal of Materials Chemistry C

We demonstrate new fluorophore-labelled materials based on acrylamide and on oligo(ethylene glycol) (OEG) bearing thermoresponsive polymers for sensing purposes and investigate their thermally induced solubility transitions. It is found that the emission properties of the polarity-sensitive (solvatochromic) naphthalim…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors

Strong almost reducibility for analytic and Gevrey quasi-periodic cocycles

Claire Chavaudret2013-01-01Bulletin de la Société mathématique de France

This paper is about almost reducibility of quasi-periodic cocycles with a diophantine frequency which are sufficiently close to a constant. Generalizing previous works by L.H.Eliasson, we show a strong version of almost reducibility for analytic and Gevrey cocycles, that is to say, almost reducibility where the change…

Magnetism in coordination complexesSpectral Theory in Mathematical PhysicsQuasicrystal Structures and Properties

Optically active, magnetic gels consisting of helical substituted polyacetylene and Fe3O4 nanoparticles: preparation and chiral recognition ability

Dong Liu、Huaiyu Chen、Jianping Deng 等 4 位作者2013-01-01Journal of Materials Chemistry C

This paper reports the preparation of unique composite gels demonstrating both optical activity and magnetic responsivity (the gels are denoted as OAMGs). The composite gels consist of magnetic Fe3O4 nanoparticles (Fe3O4 NPs) and helical substituted polyacetylene with a predominantly one-handed screw sense. The former…

Supramolecular Chemistry and ComplexesSynthesis and Properties of Aromatic CompoundsSupramolecular Self-Assembly in Materials

Early gene and protein expression associated with osteoblast differentiation in response to fish collagen peptides powder

Shizuka Yamada、Yuu Yoshizawa、Atsushi Kawakubo 等 6 位作者2013-01-01Dental Materials Journal

This study was designed to investigate the biological effects of fish collagen peptide (FCP) on human osteoblasts. Human osteoblasts were treated with 0.1% FCP, which was the optimal concentration confirmed by the increase in alkaline phosphatase activity. After one, three, five and seven days of culture, the number o…

Silk-based biomaterials and applicationsCollagen: Extraction and CharacterizationBone and Dental Protein Studies

Oxidation of ferrocenemethanol grafted to a hydrogel network through cysteine for triggering volume phase transition

Klaudia Kaniewska、J. Romański、Marcin Karbarz2013-01-01RSC Advances

New gels based on N-isopropylacrylamide and cysteine were prepared by free radical polymerization in aqueous solutions. To attach the amino acid to the polymer chain, its α-amino group was modified with acryloyl chloride and N,N′-bisacryloylcystine was obtained. Next, the disulfide bridges were reduced to thiol groups…

Advanced Sensor and Energy Harvesting MaterialsHydrogels: synthesis, properties, applicationsConducting polymers and applications

Energy landscapes, structural topologies and rearrangement mechanisms in clusters of dipolar particles

James D. Farrell、Christabel Lines、James J. Shepherd 等 6 位作者2013-01-01Soft Matter

Clusters of spherical particles with isotropic attraction favour compact structures that maximise the number of energetically optimal nearest-neighbour interactions. In contrast, dipolar interactions lead to the formation of chains with a low coordination number. When both isotropic and dipolar interactions are presen…

Micro and Nano RoboticsPickering emulsions and particle stabilizationCharacterization and Applications of Magnetic Nanoparticles

Al0.5TiZrPdCuNi High-Entropy (H-E) Alloy Developed through Ti20Zr20Pd20Cu20Ni20 H-E Glassy Alloy Comprising Inter-Transition Metals

A. Takeuchi、Junqiang Wang、Na Chen 等 7 位作者2013-01-01MATERIALS TRANSACTIONS

An Al0.5TiZrPdCuNi high-entropy (H-E) alloy with a bcc single phase was found through a Ti20Zr20Pd20Cu20Ni20 H-E glassy alloy designed based on equi-atomicity inherent to H-E alloys. The constituent elements and the composition of the Ti20Zr20Pd20Cu20Ni20 alloy were determined by regarding a binary Cu64Zr36 bulk metal…

Metallic Glasses and Amorphous AlloysHigh Entropy Alloys StudiesPhase-change materials and chalcogenides

Continuous catalyst-free aromatization of γ-terpinene using air as an oxidant

Martta Asikainen、Olli Jauhiainen、Olli Aaltonen 等 4 位作者2013-01-01Green Chemistry

The dehydrogenation of γ-terpinene was studied under catalyst- and solvent-free reaction conditions using air as an oxidant. The dehydrogenation affords p-cymene in good yields in a continuous flow reaction setup. The initial optimization of the reaction parameters showed that the dehydrogenation is highly dependent o…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Asymmetrically substituted 5,5′-bistriazoles – nitrogen-rich materials with various energetic functionalities

Alexander A. Dippold、Thomas M. Klapötke、Michaela Oswald2013-01-01Dalton Transactions

In this contribution the synthesis and full structural and spectroscopic characterization of three asymmetrically substituted bis-1,2,4-triazoles, along with different energetic moieties like amino, nitro, nitrimino and azido moieties, is presented. Additionally, selected nitrogen-rich ionic derivatives have been prep…

Crystallography and molecular interactionsEnergetic Materials and CombustionThermal and Kinetic Analysis

Cisplatin-induced elongation of Shewanella oneidensis MR-1 cells improves microbe–electrode interactions for use in microbial fuel cells

Sunil A. Patil、Kamil Górecki、Cecilia Hägerhäll 等 4 位作者2013-01-01Energy & Environmental Science

Here, we present an unusual approach of modifying the growth pattern of electroactive bacteria for improving their communication with electrodes. Cells of a known exoelectrogen, Shewanella oneidensis MR-1, were treated with cisplatin, a drug that inhibits cell division but forces the cells to grow longer resulting in…

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsMicrobial Fuel Cells and Bioremediation

Embedding monomers and dimers of sulfonamide antibiotics into high silica zeolite Y: an experimental and computational study of the tautomeric forms involved

Ilaria Braschi、Geo Paul、Giorgio Gatti 等 5 位作者2013-01-01RSC Advances

This work is a second step towards the systematic study of the embedding of sulfonamide antibiotics into a synthetic high silica zeolite Y (HSZ-Y) with hydrophobic properties. In the previous paper [Braschi et al., Langmuir 2010, 31, 9524], the irreversible adsorption from water into HSZ-Y of three sulfonamides was st…

Pharmaceutical and Antibiotic Environmental ImpactsCovalent Organic Framework ApplicationsChemical Synthesis and Characterization

A Guideline for Fatigue Strength Improvement of High Strength Steel Welded Structures Using High Frequency Mechanical Impact Treatment

Gary Marquis、Zuheir Barsoum2013-01-01Procedia Engineering

In the past decade, high frequency mechanical impact (HFMI) has significantly developed as a reliable, effective and user- friendly method for post-weld fatigue strength improvement technique for welded structures. This paper presents a proposed fatigue design and assessment guideline for HFMI improved welded joints.…

Fatigue and fracture mechanicsHigh-Velocity Impact and Material BehaviorSurface Treatment and Residual Stress

Nickel substituted LiMn2O4 cathode with durable high-rate capability for Li-ion batteries

Yun Xu、Gen Chen、Engang Fu 等 11 位作者2013-01-01RSC Advances

Spinel LiMn2−xNixO4 (x = 0, 0.1, 0.2) nanoparticles were prepared through a simple one-step polymer-assisted chemical solution method. When x = 0.1, the cathode exhibited the best durable rate capability, with 100% of the capacity retained (∼100 mAh g−1) after 400 cycles at 10 C current rate. The excellent cyclability…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Synthesis of Bi6Mo2O15 sub-microwires via a molten salt method and enhancing the photocatalytic reduction of CO2 into solar fuel through tuning the surface oxide vacancies by simple post-heating treatment

Ping Li、Yong Zhou、Wenguang Tu 等 12 位作者2013-01-01CrystEngComm

Monoclinic phase Bi6Mo2O15 sub-microwires consisting of MoO4 tetrahedra have been successfully synthesized by a molten salt method. The wide-bandgap sub-microwire exhibits photocatalytic activity toward the photoreduction of CO2 into CH4. The existence of surface oxide vacancies enhanced the photocatalytic activity, w…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceGa2O3 and related materials

Long-term performance of enhanced biological phosphorus removal with increasing concentrations of silver nanoparticles and ions

Hong Chen、Xiong Zheng、Yinguang Chen 等 4 位作者2013-01-01RSC Advances

The wide use of silver nanoparticles (AgNPs) and silver ions (Ag+) as antimicrobial agents have caused concerns about their potential effects on the environment, such as wastewater treatment plants. This paper reports the effects of increasing the influent AgNPs and Ag+ from 1 to 5 mg L−1 on the performance of enhance…

Microplastics and Plastic PollutionAdvanced Nanomaterials in CatalysisGraphene and Nanomaterials Applications

Efficiency of Amino Alcohols as Corrosion Inhibitors in Reinforced Concrete

Ioannis Vyrides、E. Rakanta、Theodosia Zafeiropoulou 等 4 位作者2013-01-01Open Journal of Civil Engineering

The objective of this paper is to investigate the behaviour of amino alcohol corrosion inhibitors when they are used in reinforced cement mortars either as admixtures in the cement paste or as coating applications on the surface of the rebars. The reinforced cement mortars were exposed to both partial and full immersi…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilitySmart Materials for Construction

Structural and electrochemical characterization of carbon supported Pt–Pr catalysts for direct ethanol fuel cells prepared using a modified formic acid method in a CO atmosphere

Patricia Gon Corradini、Ermete Antolini、Joelma Perez2013-01-01Physical Chemistry Chemical Physics

Pt-Pr/C electrocatalysts were prepared using a modified formic acid method, and their activity for carbon monoxide and ethanol oxidation was compared to Pt/C. No appreciable alloy formation was detected by XRD analysis. By TEM measurements it was found that Pt particle size increases with an increasing Pr content in t…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceFuel Cells and Related Materials