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Fe/CoO(001) and Fe/CoO(111) bilayers: Effect of crystal orientation on the exchange bias

Ewa Młyńczak、B. Matlak、A. Kozioł‐Rachwał 等 6 位作者2013-08-30Physical Review B

A comparative study of the structure and magnetism of Fe/CoO(111) and Fe/CoO(001) epitaxial bilayers was performed to investigate the role of uncompensated spins in the exchange bias (EB) phenomenon. Low-energy electron diffraction, x-ray photoelectron spectroscopy, conversion electron M\"ossbauer spectroscopy (CEMS),…

Magnetic properties of thin filmsZnO doping and propertiesMagnetic Properties and Synthesis of Ferrites

Holographic measurements of anisotropic three-dimensional diffusion of colloidal clusters

Jerome Fung、Vinothan Manoharan2013-08-30Physical Review E

We measure all nonzero elements of the three-dimensional diffusion tensor D for clusters of colloidal spheres to a precision of 1% or better using digital holographic microscopy. We study both dimers and triangular trimers of spheres, for which no analytical calculations of the diffusion tensor exist. We observe aniso…

Material Dynamics and PropertiesDigital Holography and Microscopy

Enhancement of Hydrogen Production and Carbon Dioxide Capturing in a Novel Methane Steam Reformer Coupled with Chemical Looping Combustion and Assisted by Hydrogen Perm-Selective Membranes

Mohsen Abbasi、Mahdi Farniaei、Mohammad Reza Rahimpour 等 4 位作者2013-08-30Energy & Fuels

In this novel paper, application of chemical looping combustion (CLC) instead of furnace in a steam reformer assisted by Pd–Ag hydrogen perm-selective membranes (CLC-SRM) for CO 2 capture and hydrogen production has been analyzed. NiO18-αAl 2 O 3 particles have been employed as oxygen carriers in CLC-SRM. These partic…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingChemical Looping and Thermochemical Processes

Improving activity of minicellulosomes by integration of intra- and intermolecular synergies

Qi Xu、Shi‐You Ding、Roman Brunecky 等 6 位作者2013-08-30Biotechnology for Biofuels

BACKGROUND: Complete hydrolysis of cellulose to glucose requires the synergistic action of three general types of glycoside hydrolases; endoglucanases, exoglucanases, and cellobiases. Cellulases that are found in Nature vary considerably in their modular diversity and architecture. They include: non-complexed enzymes…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesCatalysis for Biomass Conversion

Mid-infrared characterization of thiophene-based thin polymer films

Akemi Tamanai、Sebastian Beck、Annemarie Pucci2013-08-30Displays

Optical properties of seven regioregular poly(3-alkylthiophene) with different alkyl side chain lengths which are poly(3-butylthiophene-2,5-diyl) (P3BT), poly(3-pentylthiophene-2,5-diyl) (P3PT), poly(3-hexylthiophene-2,5-diyl) (P3HT), poly(3-heptylthiophene-2,5-diyl) (P3hept), poly(3-octylthiophene-2,5-diyl) (P3OT), p…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsNonlinear Optical Materials Research

Magnetic order in the pyrochlore iridate Nd 2 Ir 2 O 7 probed by muon spin relaxation

Hanjie Guo、Kazuyuki Matsuhira、Ikuto Kawasaki 等 7 位作者2013-08-30Physical Review B

Muon spin relaxation results on the pyrochlore iridate Nd${}_{2}$Ir${}_{2}$O${}_{7}$ are reported. Spontaneous coherent muon spin precession below the metal-insulator transition (MIT) temperature of about 33 K is observed, indicating the appearance of a long-range magnetic ordering of Ir${}^{4+}$ moments. With further…

Topological Materials and PhenomenaAdvanced Condensed Matter PhysicsNuclear materials and radiation effects

Increased nanoparticle‐loaded exogenous macrophage migration into the brain following PDT‐induced blood–brain barrier disruption

Steen J. Madsen、H. Michael Gach、Seok Jin Hong 等 6 位作者2013-08-30Lasers in Surgery and Medicine

BACKGROUND AND OBJECTIVE: Photodynamic therapy (PDT)-induced disruption of the blood-brain barrier (BBB) has been investigated as a technique for the delivery of therapeutic agents to selective regions of the brain. The purpose of this study was to determine the effects of PDT on the migration of systemically administ…

Nanoparticle-Based Drug DeliveryPhotodynamic Therapy Research StudiesCerebrospinal fluid and hydrocephalus

Effects of Chain Stiffness on Conformational and Dynamical Properties of Individual Ring Polymers in Shear Flow

Wenduo Chen、Jizhong Chen、Lijun Liu 等 5 位作者2013-08-30Macromolecules

Individual semiflexible ring polymers in a steady shear flow are studied by the multiparticle collision dynamics method combined with molecular dynamics simulations. We report the effects of chain stiffness on the conformational, dynamical, and rheological properties of ring polymers. When the Weissenberg numbers are…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesBlood properties and coagulation

Hypoxia Induced Multidrug Resistance of Laryngeal Cancer Cells via Hypoxia-inducible Factor-1α

Dawei Li、Pin Dong、Fei Wang 等 6 位作者2013-08-30Asian Pacific Journal of Cancer Prevention

OBJECTIVES: To investigate whether hypoxia has an effect on regulation of multidrug resistance (MDR) to chemotherapeutic drugs in laryngeal carcinoma cells and explore the role of hypoxia-inducible factor-1α (HIF- 1α). METHODS: Laryngeal cancer cells were cultured under normoxic and hypoxic conditions. The sensitivity…

Nanoparticle-Based Drug DeliveryDrug Transport and Resistance MechanismsCancer, Hypoxia, and Metabolism

Monitoring Meso-Scale Ordering of Cellulose in Intact Plant Cell Walls Using Sum Frequency Generation Spectroscopy

Y. B. Park、C. M. Lee、B.-W. Koo 等 6 位作者2013-08-30PLANT PHYSIOLOGY

Sum frequency generation (SFG) vibration spectroscopy can selectively detect crystalline cellulose without spectral interference from cell wall matrix components. Here, we show that the cellulose SFG spectrum is sensitive to cellulose microfibril alignment and packing within the cell wall. SFG intensity at 2,944 cm(-1…

Plant Molecular Biology ResearchAdvanced Cellulose Research StudiesPolysaccharides and Plant Cell Walls

Molecular Insight into Substrate Recognition and Catalysis of Baeyer–Villiger Monooxygenase MtmOIV, the Key Frame-Modifying Enzyme in the Biosynthesis of Anticancer Agent Mithramycin

Mary A. Bosserman、Theresa Downey、Nicholas Noinaj 等 5 位作者2013-08-30ACS Chemical Biology

Baeyer-Villiger monooxygenases (BVMOs) have been shown to play key roles for the biosynthesis of important natural products. MtmOIV, a homodimeric FAD- and NADPH-dependent BVMO, catalyzes the key frame-modifying steps of the mithramycin biosynthetic pathway, including an oxidative C-C bond cleavage, by converting its…

Enzyme Catalysis and ImmobilizationGlycosylation and Glycoproteins ResearchEnzyme Structure and Function

Nab-Paclitaxel Is an Active Drug in Preclinical Model of Pediatric Solid Tumors

Libo Zhang、Paula Marrano、Sushil Kumar 等 7 位作者2013-08-30Clinical Cancer Research

PURPOSE: To investigate the antitumor effect of nab-paclitaxel, an albumin-stabilized nanoparticle formulation of paclitaxel, on pediatric solid tumor models. EXPERIMENTAL DESIGN: A panel of three rhabdomyosarcoma, one osteosarcoma and seven neuroblastoma cell lines were exposed to increasing concentrations of nab-pac…

Nanoparticle-Based Drug DeliveryNeuroblastoma Research and TreatmentsCancer Research and Treatments

Synthesis and Characterization of a New Fluorine‐Containing Polybenzimidazole (PBI) for Proton‐Conducting Membranes in Fuel Cells

Xiao Li、Guoqing Qian、X. Chen 等 4 位作者2013-08-30Fuel Cells

Abstract A new type of fluorine‐containing polybenzimidazole, namely poly(2,2′‐(2,2′‐bis(trifluoromethyl)‐4,4′‐biphenylene)‐5,5′‐bibenzimidazole) (BTBP‐PBI), was developed as a candidate for proton‐conducting membranes in fuel cells. Polymerization conditions were experimentally investigated to achieve high molecular…

Organic Electronics and PhotovoltaicsFuel Cells and Related MaterialsSynthesis and properties of polymers

Conversion of glucose to lactic acid derivatives with mesoporous Sn‐ MCM ‐41 and microporous titanosilicates

Beatriz Murillo、Arantxa Sánchez、Víctor Sebastián 等 8 位作者2013-08-30Journal of Chemical Technology & Biotechnology

Abstract BACKGROUND The production of value‐added products from biomass has acquired increasing importance due to the high worldwide demand for chemicals and energy, uncertain petroleum availability and the necessity of finding environmentally friendly processes. This paper reports work on the synthesis of several cat…

Biofuel production and bioconversionMesoporous Materials and CatalysisCatalysis for Biomass Conversion

High-Torque-Density High-Efficiency Flux-Switching PM Machine for Aerospace Applications

Christian Sanabria-Walter、Henk Polinder、J.A. Ferreira2013-08-30IEEE Journal of Emerging and Selected Topics in Power Electronics

Recently, flux-switching permanent magnet (FSPM) machines have been increasingly investigated due to its torque density and fault tolerance. Because of this, they are attractive for aerospace applications where weight, installation spaces, and safety play a critical role. Recent research has investigated a variation o…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsMagnetic Bearings and Levitation Dynamics

Hoop-Strong Nanotubes for Battery Electrodes

Khim Karki、Yujie Zhu、Yihang Liu 等 8 位作者2013-08-30ACS Nano

The engineering of hollow nanostructures is a promising approach to addressing instabilities in silicon-based electrodes for lithium-ion batteries. Previous studies showed that a SiOx coating on silicon nanotubes (SiNTs) could function as a constraining layer and enhance capacity retention in electrodes with low mass…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

A superhydrophobic magnetic elastomer actuator for droplet motion control

K. Seo、Rinbok Wi、Sung Gap Im 等 4 位作者2013-08-30Polymers for Advanced Technologies

For the fast droplet transportation on an open surface, a new magnetic elastomer with a superhydrophobic surface has been developed. Because the surface is superhydrophobic, the water droplet can easily roll off on the surface. The movement of the droplet was controlled by a deliberate local deformation of the surface…

Surface Modification and SuperhydrophobicityInnovative Microfluidic and Catalytic Techniques InnovationElectrowetting and Microfluidic Technologies

DSH-MRAM: Differential Spin Hall MRAM for On-Chip Memories

Yusung Kim、Sri Harsha Choday、Kaushik Roy2013-08-30IEEE Electron Device Letters

A new device structure for spin-transfer torque-based magnetic random access memory (STT-MRAM) is proposed for on-chip memory applications. Our device structure exploits spin Hall effect to create a differential memory cell that exhibits fast and energy-efficient write operation. In addition, because of inherently dif…

Magnetic properties of thin filmsAdvanced Memory and Neural ComputingMagnetic and transport properties of perovskites and related materials

Relevant model complexity for non-charring polymer pyrolysis

Nicolas Bal、Guillermo Rein2013-08-30Fire Safety Journal

The choice of the heat, mass and chemical mechanisms included in a pyrolysis model is often subjective, and detailed justifications of the inclusion or exclusion of the different mechanisms are infrequent. The implicit assumption that models with a higher number of mechanisms reproduce more accurately the reality has…

Thermochemical Biomass Conversion ProcessesPolymer crystallization and propertiesFire dynamics and safety research

Uranium(III) Complexes with Bulky Aryloxide Ligands Featuring Metal–Arene Interactions and Their Reactivity Toward Nitrous Oxide

Sebastian M. Franke、Ba L. Tran、Frank W. Heinemann 等 6 位作者2013-08-30Inorganic Chemistry

We report the synthesis and use of an easy-to-prepare, bulky, and robust aryloxide ligand starting from inexpensive precursor materials. Based on this aryloxide ligand, two reactive, coordinatively unsaturated U(III) complexes were prepared that are masked by a metal-arene interaction via δ-backbonding. Depending on s…

Organometallic Complex Synthesis and CatalysisRadioactive element chemistry and processingLanthanide and Transition Metal Complexes