Materials Literature
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Textured, polycrystalline Nd 2 Fe 14 B powders, produced by dynamic hydrogenation disproportionation desorption and recombination (d-HDDR) were further processed by wet and surfactant-assisted ball milling. After 4 h of milling at 400 rpm in absolute ethanol and heptane + oleic acid, the polycrystalline d-HDDR particl…
Synthesis of TiFebased metal hydride-forming alloy from mixed titanium iron oxide (ilmenite, FeTiO3) was carried out by a two-stage reduction of the latter using H2 and CaH2 as reducing agents. The reversible hydrogen absorption capacity of the TiFe based material was about 0.5 wt. % H, that is significantly lower tha…
Abstract This paper presents a multi‐scale model of a solid oxide fuel cell (SOFC) stack consisting of five anode‐supported cells. A two‐dimensional isothermal elementary kinetic model is used to calculate the performance of single cells. Several of these models are thermally coupled to form the stack model. Simulatio…
This study reports the synthesis of mesoporous silica nanoparticle-encapsulated alginate microparticles (MSN@Alg) for sustained release and targeting therapy. The MSN@Alg was synthesized by air dynamical atomization, and the effects of several critical factors including concentration of alginate solution, flow rate of…
Abstract Poly(lactic acid)/hydroxyapatite (PLA/HAP) nanocomposite films with various compositions, 2 − 70 parts HAP per 100 of the PLA polymer (pph), were made via the solution casting method. Transmission electron microscopy images of the PLA/HAP films exhibited spherical particles in the size range from nearly 10 nm…
The paper presents the results of research aimed at development of nanomodified high-strength lightweight concrete for construction. The developed concretes are of low average density and high ultimate compressive strength. It is shown that to produce this type of concrete one need to use hollow glass and aluminosilic…
Ligand-field and charge-transfer spectra of N-heterocyclic pentacyanoferrate(II) complexes [Fe(CN)5L]n− were investigated using multiconfigurational perturbation theory. The spectrum of [Fe(CN)5(py)]3– was studied in detail under vacuum and in the following polarizable continuum model (PCM) simulated solvents: acetone…
We investigate the structural heterogeneity in a silicate glass by hyperquenching–annealing–calorimetry approach. The results show a striking phenomenon: two separated sub‐ T g relaxation peaks appear on the calorimetric curve of the hyperquenched CaO – MgO – SiO 2 glass, implying the existence of two distinct structu…
In the thin film area, it is well-known that deposition rate impacts the morphology but tools to quantify online fast growth processes are scarce. Here we show that surface differential reflectivity spectroscopy (SDRS) can be used in real time to follow silver nanoparticle growth during sputtering deposition. The main…
Ni doped, Li doped and (Li, Ni) codoped ZnO thin films were successfully grown using a pulsed laser deposition technique. Undoped and doped ZnO thin films were investigated using extended x-ray absorption fine structure (EXAFS) and x-ray absorption near edge spectroscopy (XANES). Preliminary investigations on the Zn K…
Abstract We study the classical Landau–Levich dip-coating problem in the case where the interface has significant elasticity. One aim of this work is to unravel the effect of surface-adsorbed hydrophobic particles on Landau–Levich flow. Motivated by recent findings (Vella, Aussillous & Mahadevan, Europhys. Lett., vol.…
A series of organic salts derived from various dicarboxylic acids and two α,ω-diamines, namely, 1,3-diaminopropane and 1,4-diaminobutane, were prepared and characterized by various physicochemical techniques, including single-crystal X-ray diffraction, with the aim of extending the well-studied 2D primary ammonium dic…
Using a simple and precise instrument system, we directly measured the thermo-physical properties of one-dimensional highly aligned carbon nanotubes (CNTs). A kind of CNT-based macroscopic materials named super aligned carbon nanotube (SACNT) buckypapers was measured in our experiment. We defined a new one-dimensional…
The mechanical behaviour of the commercial aluminium alloys EN AW-5182, EN AW-6016 and EN AW-7021 is investigated at temperatures ranging from 298 to 77 K and strain rates from 1.7 × 10 −3 to 6.6 × 10 −2 s −1 . A device that allows testing at cryogenic temperatures is developed and demonstrated, where the specimens ar…
Herein, we report evidence for the promising potential of 2-(acetylthio)ethylmethacrytale (AcSEMA), a new monomer, which copolymerizes with methyl methacrylate (MMA) by atom transfer radical polymerization (ATRP) leading to well-defined multidentate protected thiol polymer ligands for CdSe QDs capping by simple ligand…
Cross-linked poly(butylene succinate) (PBS) was prepared by the reactions of the end hydroxyl groups of PBS with toluene diisocyanate and trimethylolpropane (TDI–TMP) polyurethane prepolymer at the processing temperature. The effects of varied TDI–TMP prepolymers on properties such as mechanical properties, thermal pr…
The thermodynamic and geometric parameters of M(II) macrotetracyclic chelates (M = Mn, Fe, Co, Ni, Cu, and Zn) with the (NNNN) coordination of the donor ligand sites, formed by the complexation reactions of corresponding M(II) compounds, ethanedithioamide H 2 N-C(=S)-C(=S)-NH 2 , and acetone H 3 C-C(=O)-CH 3 in gelati…
The employment of Ni–Mo films has recently been shown to yield strictly homogeneous single-layer graphene. In this study, we systematically investigate the different stages of nucleation and growth of graphene over Ni–Mo layers. The studies reveal that the Ni film breaks up and diffuses into the underlying Mo foil, fo…
Ultra-broadband emission covering 1000?1800 and 1800?3020?nm of Bi2O3?GeO2 binary system materials, from glass to glass-ceramics to crystals, is presented in this paper. This is the first time, to our best knowledge, that broadband photoluminescence of BGO crystals (including Bi4Ge3O12 and Bi12GeO20) in the range of 1…
The role of carbon additions and oxygen content on the densification of zirconium diboride ( ZrB 2 ) was studied. ZrB 2 with up to 1 wt% added carbon was hot pressed at temperatures of 2000°C and 2100°C. Nominally pure ZrB 2 hot pressed at 2100°C achieved relative densities >95.5%. Carbon and oxygen analysis indicate…