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A Liquid Inorganic Electrolyte Showing an Unusually High Lithium Ion Transference Number: A Concentrated Solution of LiAlCl4 in Sulfur Dioxide

Robert Hartl、Matthias Fleischmann、Ruth M. Gschwind 等 5 位作者2013-08-29Energies

We report on studies of an inorganic electrolyte: LiAlCl4 in liquid sulfur dioxide. Concentrated solutions show a very high conductivity when compared with typical electrolytes for lithium ion batteries that are based on organic solvents. Our investigations include conductivity measurements and measurements of transfe…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesSolid-state spectroscopy and crystallography

Compact polarizing beam splitter based on a metal-insulator-metal inserted into multimode interference coupler

Vuthy Chheang、Tae‐Kyeong Lee、Geum-Yoon Oh 等 7 位作者2013-08-29Optics Express

We propose and analyze a compact polarizing beam splitter (PBS) based on a metal-insulator-metal (MIM) structure inserted into a multimode interference coupler (MMI). Owing to the MIM structure, the TE polarized state is reflected by the cut-off condition while the TM polarized state is transmitted by the surface plas…

Plasmonic and Surface Plasmon ResearchPhotonic and Optical DevicesOptical Coatings and Gratings

Automated Multiplexing Quantum Dots in Situ Hybridization Assay for Simultaneous Detection of ERG and PTEN Gene Status in Prostate Cancer

Wenjun Zhang、Antony Hubbard、Patrick Brunhoeber 等 5 位作者2013-08-29Journal of Molecular Diagnostics

The photostability and narrow emission spectra of nonorganic quantum dot fluorophores make them desirable detection methods for ultrasensitive and multiplexing in situ hybridization applications to identify genetic aberrances in morphologically preserved clinical tissue specimens. However, robustness and reliability h…

Advanced biosensing and bioanalysis techniquesClick Chemistry and ApplicationsNanocluster Synthesis and Applications

Swelling Behavior of Physically Cross-Linked Gelatin Gels in Varied Salt Solutions

Congde Qiao、Xiaolu Cao2013-08-29Journal of Macromolecular Science Part B

A series of physically cross-linked gelatin networks were prepared and the effects of salt concentration and chemical valence of the salt ions on the swelling properties of the gelatin gels were studied in detail. It was found that the swelling behaviors as polyelectrolytic or polyampholytic gels depended on the charg…

Advanced Sensor and Energy Harvesting MaterialsHydrogels: synthesis, properties, applicationsTextile materials and evaluations

Enzyme-free Amperometric H2O2 Biosensor Based on Cu–Ag Bimetallic Nanoparticles with Reduced Graphene Oxide Nanocomposites

Konglin Wu、Xiangzi Li、Chao Dong 等 8 位作者2013-08-29Chemistry Letters

Abstract Cu–Ag bimetallic nanoparticles loaded on reduced graphene oxide nanocomposites (Cu–Ag/rGO NCs) were obtained through a facile chemical reduction method. The resulting Cu–Ag/rGO NCs exhibited good catalytic activity in reducing H2O2, with a fast amperometric response, i.e., less than 2 s. The linear detection…

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsAdvanced Nanomaterials in Catalysis

AlGaInP-Based LEDs With AuBe-Diffused AZO/GaP Current Spreading Layer

Shoou‐Jinn Chang、Xu-Feng Zeng、Shih‐Chang Shei 等 4 位作者2013-08-29IEEE Journal of Quantum Electronics

We report the use of Al-doped ZnO (AZO) as the current spreading layer for AlGaInP-based light-emitting diodes (LEDs). It was found that AZO could form good ohmic contact with AuBe-diffused p-GaP. It was also found that the specific contact resistance could be further reduced from 2.68×10-4to 1.52×10-4Ω-cm2by performi…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

T-Shaped Push-Pull Chromophores: First Modification of the Indan-1,3-dione-Fused Benzene Ring by Cross-Coupling Reactions

Filip Bureš、Parmeshwar Solanke、Olřich Pytela 等 5 位作者2013-08-29Synthesis

A series of eight novel T-shaped chromophores with indan-1,3-dione central acceptor moiety and peripheral N , N -dimethylamino and thiophene donors were synthesized. 4,7-Diiodoindan-1,3-dione was prepared in a straightforward manner from phthalanhydride. Its modification with donors was accomplished by Knoevenagel, Su…

Luminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic CompoundsPhotochromic and Fluorescence Chemistry

Water uptake rates of transformer paper insulation impregnated with vegetable oil

Daniel Martín、Nick Lelekakis、Jaury Wijaya 等 4 位作者2013-08-29IEEE Electrical Insulation Magazine

Vegetable oil-based dielectrics have been available for the past 15 years; relevant articles have been published [1]-[3]. One practical advantage of using a vegetable-oil dielectric in a power transformer is its higher affinity to moisture, around 20 times higher than that of mineral oil at room temperature [4]. Power…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationIslanding Detection in Power Systems

Effect of Shape Anisotropy and Size on the Electronic Structure of CdSe/ZnSe Quantum Dots

Dharmendra Kumar、Chandra Mohan Singh Negi、Saral Kumar Gupta 等 4 位作者2013-08-29IEEE Transactions on Nanotechnology

The effect of shape anisotropy and size on the electronic structure of CdSe/ZnSe quantum dots is theoretically investigated. The quantum dot is modeled by assuming a parabolic confinement along xy plane and by finite well potential due to band offset along growth (z) direction. The energy eigenvalues and wave function…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesQuantum and electron transport phenomena

Rheological Properties of Polyethylene Glycol (PEG 35000): An Interpretation of a Negative Intrinsic Viscosity and a High Huggins Coefficient Value

K. Bechekh、N. Ghaouar2013-08-29Journal of Macromolecular Science Part B

The effect of temperature on the intrinsic viscosity and the Huggins coefficient of polyethylene glycol (PEG 35000) in aqueous solution was studied. The intrinsic viscosity became negative for temperatures higher than 45°C. Two hypotheses are given to explain this tendency. We demonstrated that the mobility and size o…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsRheology and Fluid Dynamics Studies

Dynamics of multiphase systems with complex microstructure. I. Development of the governing equations through nonequilibrium thermodynamics

Leonard M.C. Sagis、Hans Christian Öttinger2013-08-29Physical Review E

In this paper we present a general model for the dynamic behavior of multiphase systems in which the bulk phases and interfaces have a complex microstructure (for example, immiscible polymer blends with added compatibilizers, or polymer stabilized emulsions with thickening agents dispersed in the continuous phase). Th…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Spatial Control of Zeolitic Imidazolate Framework Growth on Flexible Substrates

Constantinos Dimitrakakis、Christopher D. Easton、Benjamin W. Muir 等 5 位作者2013-08-29Crystal Growth & Design

The application of patterned thin film layers of metal organic frameworks onto surfaces is a matter of much interest of late with a view toward opening exciting applications for MOFs in gas sensing and catalysis. Here, the use of a plasma polymer coating technique has been employed to selectively alter the surface che…

Metal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Ecofriendly antiglare film derived from biomass using ultraviolet curing nanoimprint lithography for high-definition display

Satoshi Takei、Gaku Murakami、Yuto Mori 等 10 位作者2013-08-29Journal of Micro/Nanolithography MEMS and MOEMS

Nanopatterning of an ecofriendly antiglare film derived from biomass using an ultraviolet curing nanoimprint lithography is reported. Developed sugar-related organic compounds with liquid glucose and trehalose derivatives derived from biomass produced high-quality imprint images of pillar patterns with a 230-nm diamet…

Liquid Crystal Research AdvancementsSilk-based biomaterials and applicationsNanofabrication and Lithography Techniques

Direct Observation of Amyloid Nucleation under Nanomechanical Stretching

Nitinun Varongchayakul、Sara Johnson、Trina Quabili 等 8 位作者2013-08-29ACS Nano

Self-assembly of amyloid nanofiber is associated with both functional biological and pathological processes such as those in neurodegenerative diseases. Despite intensive studies, the stochastic nature of the process has made it difficult to elucidate a molecular mechanism for the key amyloid nucleation event. Here we…

Lipid Membrane Structure and BehaviorForce Microscopy Techniques and ApplicationsSupramolecular Self-Assembly in Materials

Case Study

Maximilien Debia、Scott Weichenthal、André Dufresne2013-08-29Journal of Occupational and Environmental Hygiene

Ultrafine particles (UFPs) are generally defined as those particles with a diameter less than 100 nanometer (nm) that are not intentionally generated (i.e., engineered nanoparticles). Sources of UF...

Nanoparticles: synthesis and applicationsAir Quality and Health ImpactsOccupational exposure and asthma

Magnetic Graphene Oxide Anchored Sulfonic Acid as a Novel Nanocatalyst for the Synthesis of N‐aryl‐2‐amino‐1,6‐naphthyridines

Shahnaz Rostamizadeh、Mina Rezgi、Nasrin Shadjou 等 4 位作者2013-08-29Journal of the Chinese Chemical Society

Abstract Magnetic graphene oxide functionalized with sulfonic acid (Fe3O4‐GO‐SO3H) was used as a new recyclable nanocatalyst for one‐pot synthesis of N‐aryl‐2‐amino‐1,6‐naphthyridine derivatives under solvent free conditions. The catalyst could be easily recovered from the reaction mixture by an external magnet and re…

Graphene research and applicationsMolecular Junctions and NanostructuresNanomaterials for catalytic reactions

Synthesis, Characterization and Photocatalytic Activity of Mg ‐Impregnated ZnO – SnO 2 Coupled Nanoparticles

Mohammad A. Behnajady、Yasamin Tohidi2013-08-29Photochemistry and Photobiology

ZnO-SnO2 nanoparticles were prepared by coprecipitation method; then Mg, with different molar ratios and calcination temperatures, was loaded on the coupled nanoparticles by impregnation method. The synthesized nanoparticles were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE…

Advanced Photocatalysis TechniquesZnO doping and propertiesGas Sensing Nanomaterials and Sensors

FACILE SYNTHESIS OF REUSABLE COAL-HYDROTALCITE CATALYST FOR DEHYDRATION OF BIOMASS-DERIVED FRUCTOSE INTO PLATFORM CHEMICAL 5-HYDROXYMETHYLFURFURAL

Kai Yan、Xu Wu、Xia An 等 4 位作者2013-08-29Chemical Engineering Communications

A novel CoAl-hydrotalcite catalyst with different Co2+/Al3+ ratios was facilely synthesized using a modified coprecipitation method. Different techniques such as X-ray diffraction (XRD), Fourier transform-infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX) were used to…

Supercapacitor Materials and FabricationCatalysis for Biomass ConversionLayered Double Hydroxides Synthesis and Applications

Equation of state of α -Al 2 O 3

Agnès Dewaele、Marc Torrent2013-08-29Physical Review B

The ambient temperature equation of state of ruby in the corundum phase ($\ensuremath{\alpha}$-Al${}_{2}$O${}_{3}$) has been measured up to 165 GPa in a diamond anvil cell, using a soft pressure transmitting medium. No clear sign of phase transformation or amorphization has been observed in this range, which could aff…

High-pressure geophysics and materialsGlass properties and applicationsCrystal Structures and Properties

Replica Exchange Improves Sampling in Low-Resolution Docking Stage of RosettaDock

Zhe Zhang、Oliver F. Lange2013-08-29PLoS ONE

Many protein-protein docking protocols are based on a shotgun approach, in which thousands of independent random-start trajectories minimize the rigid-body degrees of freedom. Another strategy is enumerative sampling as used in ZDOCK. Here, we introduce an alternative strategy, ReplicaDock, using a small number of lon…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function