Materials Literature
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CusCFBA is one of the metal efflux systems in Escherichia coli that is highly specific for its substrates, Cu(I) and Ag(I). It serves to protect the bacteria in environments that have lethal concentrations of these metals. The membrane fusion protein CusB is the periplasmic piece of CusCFBA, which has not been fully c…
We design, fabricate and characterize a plasmonic honeycomb lattice absorber with almost perfect absorption at 1140 nm over a wide incident angle range. This absorber also possesses a narrow-band, angle- and polarization-dependent high-order resonance in the short-wavelength range, with a bandwidth of 19 nm and angle…
Basic features of the modified theory of physical optics (MTPO) are discussed on the example of scattering at perfectly reflecting half-planes and wedges. It is shown that violations of the geometrical optics (GO), introduced in this technique, result in the MTPO solutions which do not satisfy the Helmholtz equation.…
Crystal growth anisotropy in molecular beam epitaxy usually prevents deterministic nucleation of individual quantum dots when a thick GaAs buffer is grown over a nanopatterned substrate. Here, we demonstrate how this anisotropy can actually be used to mold nucleation sites for single dots on a much thicker buffer than…
Massive gas injection rapid shutdown experiments have been conducted on the Alcator C-Mod tokamak using two toroidally separated gas injectors, in order to investigate the effect of multiple gas injection locations on the toroidal asymmetry in the radiated power. Toroidal radiation asymmetry is diagnosed by an array o…
Ionic polymer–metal composite (IPMC), also called artificial muscle, is an EAP material which can generate a relatively large deformation with a low driving voltage (generally less than 5 V). Like other EAP materials, IPMC possesses strong nonlinear properties, which can be described as a hybrid of back-relaxation (BR…
Abstract ZnO nanoflowers were synthesized on conductive flexible textile fabric substrate by using the simple low‐temperature aqueous chemical growth method and were used for piezoelectric energy harvesting source. Structural characterization of ZnO nanoflowers was carried out by using surface scanning electron micros…
This paper studies the effective behavior of piezoelectric and piezomagnetic circular fibrous composites with imperfect interfaces under longitudinal shear with in-plane electromagnetic fields. Two kinds of imperfect contact are investigated: mechanically stiff and dielectrically/magnetically highly conducting interfa…
Porous structures of silica aerogels are generated using classical molecular dynamics, with the Tersoff potential, which has been re-parametrized for modeling silicon dioxides. This work demonstrates that this potential is superior to the widely used BKS potential in terms of characterizing the thermal conductivities…
The complexation of 2,9-dicarboxy-1,10-phenanthroline (DPA) with [Ru(tpy)Cl3] (tpy = 2,2';6,2″-terpyridine) provides a six-coordinate species in which one carboxyl group of DPA is not bound to the Ru(II) center. A more soluble tri-t-butyl tpy analogue is also prepared. Upon oxidation, neither species shows evidence fo…
Efficient near-infrared detection of specific DNA with single nucleotide polymorphism selectivity is important for diagnostics and biomedical research. Herein, we report the use of gallium arsenide (GaAs) as a sensing platform for probing DNA immobilization and targeting DNA hybridization, resulting in ∼8-fold enhance…
Substitution reactions of the chemically and photochemically unusually stable perylenetetracarboxylic bisimides proceed with neat amines even below room temperature where negative effective energies of activation were found. Analogous reactions proceed with naphthalenecarboximides as the lower homologues and terrylene…
Abstract Lignin and switchgrass based poly (butylene succinate) composites were prepared using a melt mixing technique. The effects of polymeric methylene diphenyl diisocyanate (pMDI), isocyanate terminated polybutadiene prepolymer (ITPB) and organic peroxide on the properties of the composites were evaluated. Peroxid…
PURPOSE: A versatile methodology is demonstrated for improving dissolution kinetics, gastrointestinal (GI) absorption, and bioavailability of protein kinase inhibitors (PKIs). METHODS: The approach is based on nanoparticle precipitation by sub- or supercritical CO2 together with a matrix-forming polymer, incorporating…
SFA-PQT exhibits self-assembly via a fluorophobic effect in a non-fluorous solvent, which leads to an enhanced electrical performance. Ambipolar transistors and inverters with p- and n- type bilayers are enabled by the unique thermally reversible soluble-insoluble properties of SFA-PQT. More importantly, the hydrophob…
• Single crystals of HgGa 2 S 4 with defect-chalcopyrite (DC) structure were synthesized. • High-pressure X-ray diffraction in DC-HgGa 2 S 4 was performed. • Equation of state of DC-HgGa 2 S 4 determined (bulk modulus of 48.4 GPa). • Calculated elastic constants of DC-HgGa 2 S 4 reported at different pressures. • DC-H…
Well-defined poly(ethylene glycol) (PEG) networks were synthesized using copper(I)-catalyzed azide–alkyne cycloaddition (CuAAC). Two types of PEG network structures were prepared (i) by linking two three-arm star PEG oligomers together and (ii) by connecting three-arm PEG star units with bifunctional linear PEG oligom…
In this report, we used stepwise orthogonal click chemistry (SOCC) involving strain-promoted azide-alkyne cycloaddition (SPAAC) and microwave-assisted Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC) to assemble an anticancer drug (paclitaxel, PTX) and a targeting ligand (trivalent galactoside, TGal) on a fluorescen…
Purpose – The purpose of this paper is to explore the use of fly ash and graphite particles as low cost reinforcing materials for improved wear resistance, enhanced mechanical properties and reduction in density of hybrid composites. Design/methodology/approach – The AlSi10Mg/fly ash/graphite (Al/FA/Gr) hybrid composi…
In this study, we propose a new approach to hard tissue regeneration based on the mineralization of 3D scaffolds made using lasers. To this end, we report the rational design of aspartate-containing self-assembling peptides targeted for calcium binding. We further investigate the suitability of these peptides to suppo…