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Tetrathiafulvalene Hybridized with Indacenetetraone as Visible-light-harvesting Electron Acceptor Applicable to Bulk-heterojunction Organic Photovoltaics

Kouki Akaike、Hideo Enozawa、Takashi Kajitani 等 10 位作者2013-08-23Chemistry Letters

Abstract π-Extension of tetrathiafulvalene by hybridization with an indacenetetraone leads to an electron acceptor that can harvest visible light efficiently and serve as an electron-transport material for poly(3-hexylthiophene)-based bulk-heterojunction photovoltaics, where brief thermal annealing of the active layer…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsOrganic and Molecular Conductors Research

Nanometric Colloidal Sols of CeO2–ZrO2 Solid Solution as Catalyst Modifiers. II. TWC Performance

Kenji Tanimoto、Hirokazu Kato、Shoya Takeshita 等 6 位作者2013-08-23Bulletin of the Chemical Society of Japan

Abstract A stable colloidal sol consisting of CeO2–ZrO2 solid solution (CZ) was studied as an efficient modifier for supported Rh catalysts. After coating CZ sol onto Al2O3 by simple impregnation, the catalytic activity for CO–NO–C3H6–O2 reaction increased to a different extent depending on an air-to-fuel weight ratio…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Theory of lubrication due to polyelectrolyte hydrogels with arbitrary salt concentration and degree of compression

J. B. Sokoloff2013-08-23The Journal of Chemical Physics

A Poisson-Boltzmann equation solution is used to determine the thickness of a thin fluid lubricating layer predicted to separate two polyelectrolyte hydrogels in contact for arbitrary salt concentration as a function of applied load and fixed charge and salt concentration. We consider loads ranging from 1 Pa, at which…

Advanced Sensor and Energy Harvesting MaterialsPolymer Surface Interaction StudiesAdhesion, Friction, and Surface Interactions

Temperature and injection current dependent optical and thermal characteristics of InGaN-based green large-area light-emitting diodes

Soo Hyun Lee、Hee Kwan Lee、Sung‐Bum Bae 等 6 位作者2013-08-23physica status solidi (a)

Optical, spectral, and thermal characteristics of InGaN/GaN multiple quantum well green light-emitting diodes (LEDs) with a large chip size of 0.8 × 1 mm2, operating at λ ∼ 525 nm, on patterned sapphire substrate (PSS) were studied. The temperature-dependent optical and spectral properties of LEDs were measured and an…

Semiconductor Quantum Structures and DevicesZnO doping and propertiesGaN-based semiconductor devices and materials

Bromophenyl functionalization of carbon nanotubes: an ab initio study

Jonathan Laflamme Janssen、Jason Beaudin、Nicholas D. M. Hine 等 5 位作者2013-08-23Nanotechnology

We study the thermodynamics of bromophenyl functionalization of carbon nanotubes with respect to diameter and metallic/insulating character using density-functional theory (DFT). On the one hand, we show that the functionalization of metallic nanotubes is thermodynamically favoured over that of semiconducting ones, in…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Nanotubular Assembly of Amide Dendron and Cucurbiturils

Jeonghun Lee、Sangkyu Park、Doohong Min 等 5 位作者2013-08-23Chemistry - An Asian Journal

CBs News: Hierarchically self-assembled dendron nanotubes with a cucurbituril (CB) unit on the surface were constructed through self-assembly of CBs and an amide dendron with a focal pyene moiety. In addition, the self-assembled dendron–CB nanotubes were reversibly transformed into a vesicular architecture by removal…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsDendrimers and Hyperbranched Polymers

Lighting up silica nanotubes transcribed from the submicron structure of a metal–peptide hybrid

Fang Pu、Jinsong Ren2013-08-23Nanotechnology

Fluorescent silica nanotubes are attracting increasing interest because of their versatile applicability in a range of diverse fields. By using sol-gel transcription of tetraethylorthosilicate (TEOS) from various soft templates, silica nanotubes can be conveniently prepared. Metal-peptide hybrids with well-defined nan…

Advanced biosensing and bioanalysis techniquesSupramolecular Self-Assembly in MaterialsNanocluster Synthesis and Applications

The Study on the Overcurrent Pulse Testing of Bi-2223/Ag HTS Winding and HTS Transformer

Zhongming Yan、Yu Wang、Rui Wu 等 4 位作者2013-08-23IEEE Transactions on Applied Superconductivity

This paper summarizes the experimental investigations on a small-scale air-core high-temperature superconducting (HTS) transformer operated in liquid nitrogen. The designed HTS transformer is being used as part of a current pulsed-power supply. First, the HTS winding was tested to experience a short overcurrent pulse.…

Physics of Superconductivity and MagnetismMagnetic Properties and ApplicationsSuperconducting Materials and Applications

Thermodynamic scaling of dynamic properties of liquid crystals: Verifying the scaling parameters using a molecular model

Katsuhiko Satoh2013-08-23The Journal of Chemical Physics

The thermodynamic scaling of molecular dynamic properties of rotation and thermodynamic parameters in a nematic phase was investigated by a molecular dynamic simulation using the Gay-Berne potential. A master curve for the relaxation time of flip-flop motion was obtained using thermodynamic scaling, and the dynamic pr…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSpectroscopy and Quantum Chemical Studies

Indium oxide thin-film homo-junctions: Morphology and electrical properties

Jolanta Stankiewicz、F. Villuendas、M. P. Lozano 等 4 位作者2013-08-23Journal of Applied Physics

Indium oxide shows an unusual combination of electrical and optical properties that give rise to a broad range of applications in optoelectronic devices. Here, we report results of structural, x–ray photoelectron spectroscopy, and electrical transport studies of transparent homo-junctions, obtained by sequential growt…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Effect of concurrent Mg/Nb-doping on dielectric properties of Ba0.45Sr0.55TiO3 thin films

Fikadu Alema、Michael Reich、Aaron Reinholz 等 4 位作者2013-08-23Journal of Applied Physics

Composition, microstructure, and dielectric properties of undoped and Ba(Mg1/3Nb2/3)O3 (BMN) doped Ba0.45Sr0.55TiO3 (BST) thin films deposited via rf. magnetron sputtering on platinized alumina substrates have been investigated. The analysis of microstructure has shown that despite the sizable effect of doping on the…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectronic and Structural Properties of Oxides

13C CP/MAS NMR studies on the curing characteristics of phenol formaldehyde resin in the presence of nano cupric oxide and surfactants

Wei Gao、Guanben Du2013-08-23Polymer Composites

The effect of nano cupric oxide (CuO) in combination with surfactants on the curing characteristics of phenol formaldehyde (PF) resin analyzed using solid 13C CP/MAS NMR, including the bonding strength of plywood prepared by modified resin, was investigated in this study. The results showed that nano CuO alone improve…

Polymer composites and self-healingEpoxy Resin Curing ProcessesLignin and Wood Chemistry

Effect of Heat Treatment and of Primary Austenite Grain Size on the Minimum Size of Detectable Defect on 26NiCrMoV11.5 High Strength Steel

Silvia Barella、Andrea Gruttadauria、Carlo Mapelli 等 8 位作者2013-08-23Advanced Engineering Materials

This study is focused on the sensitivity of ultra‐sonic test (UT) performed on special carbon steel as a function of their microstructure. UTs was carried out on several samples divided into two families and featured by different process‐histories. The estimation of the attenuation of the ultrasonic signals as a funct…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsMetal Alloys Wear and Properties

A Novel Facile Synthesis Method of N‐Vinylpyrroles

Tian Lan、Xiaofeng Chen、Zenglu Liu 等 4 位作者2013-08-23Journal of Heterocyclic Chemistry

A facile and effective synthesis of N‐vinylpyrroles had been explored. The synthetic approach was practicable for preparation of N‐vinylpyrroles for the mild reaction conditions and readily available materials, compared with previously inaccessible N‐vinylpyrroles with electron‐withdrawing groups, especially these pyr…

Porphyrin and Phthalocyanine ChemistrySynthesis and Characterization of PyrrolesOrganic Chemistry Cycloaddition Reactions

Influence of silica nanoparticles functionalized with poly(butyl acrylate‐co‐glycidyl methacrylate)‐g‐diaminodiphenyl sulfone on the mechanical and thermal properties of bismaleimide nanocomposites

Lei Xiong、Zeyang Lian、Hongbo Liang 等 5 位作者2013-08-23Polymer Composites

The silica nanoparticles functionalized with poly(butyl acrylate‐co‐glycidyl methacrylate)‐g‐diaminodiphenyl sulfone (P(BA‐co‐GMA)‐g‐DDS)) were prepared via atom transfer radical polymerization and ring open reaction, and characterized by Fourier transform infrared and X‐ray photoelectron spectroscopy. Subsequently, t…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Residual strength of reinforced concrete columns subjected to blast loading

Jong Yil Park、Min Sook Kim、Andrew Scanlon 等 5 位作者2013-08-23Magazine of Concrete Research

Failure modes of concrete structures due to blast load vary according to the point of detonation, stand-off distance and TNT charge weight. Usually, columns are the key load-bearing elements in concrete frame structures. They are typically weak, not to long-distance explosive loadings, but to short-distance loadings.…

High-Velocity Impact and Material BehaviorStructural Response to Dynamic LoadsFire effects on concrete materials

DISSOLUTION BEHAVIOR, STABILITY AND ANTI-INFLAMMATORY ACTIVITY OF KETOPROFEN COATED TRIPOLYPHOSPHATE MODIFIED CHITOSAN NANOPARTICLE

Jaya Hardi、Purwantiningsih Sugita、Laksmi Ambarsari2013-08-23Indonesian Journal of Chemistry

Ketoprofen coated tripolyphosphate modified chitosan nanoparticle was resulted from ionic gelation process by ultrasonication, centrifugation, and spray dry methods. Particle was analyzed by particle Size Analyzer. Dissolution and stability of them have conducted by Row Hansen methods at 37±0.5 °C and 150 rpm and usin…

Corrosion Behavior and InhibitionMetal Extraction and BioleachingChemical and Physical Properties in Aqueous Solutions

Co-precipitation synthesis and electrochemical properties of graphene supported LiMn1/3Ni1/3Co1/3O2 cathode materials for lithium-ion batteries

Y-H Ding、H-M Ren、Y-Y Huang 等 7 位作者2013-08-23Nanotechnology

Nanostructured graphene supported LiMn1/3Ni1/3Co1/3O2 has been prepared by the co-precipitation method and used as the cathode material for lithium-ion batteries. The structure and morphology of the composite were examined using atomic force microscopy, scanning electron microscopy, high-resolution transmission electr…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Long-range interactions in randomly driven granular fluids

M. Reza Shaebani、Jalal Sarabadani、Dietrich E. Wolf2013-08-23Physical Review E

We study the long-range spatial correlations in the nonequilibrium steady state of a randomly driven granular fluid with the emphasis on obtaining the explicit form of the static structure factors. The presence of immobile particles immersed in such a fluidized bed of fine particles leads to the confinement of the flu…

Material Dynamics and PropertiesTheoretical and Computational PhysicsGranular flow and fluidized beds

trans-Bisglycoconjugation is an Efficient and Robust Architecture for PDT Photosensitizers Based on 5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin Derivatives

Shiho Hirohara、Kohei Sharyo、Yuji Kawasaki 等 15 位作者2013-08-23Bulletin of the Chemical Society of Japan

Abstract To examine the versatility of the trans-bisglycoconjugation architecture for 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin (TFPP) derivative-based photodynamic therapy (PDT), 25 porphyrin derivatives bearing d-glucopyranose moieties were prepared, and their in vitro photocytotoxicities were examined. trans-…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies