Materials Literature
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We report the results of systematic measurements of the group velocity dispersion (GVD) in chalcogenide glass (ChG) bulk samples, composite ChG fibers, and robust high-index-contrast nanotapers. The composite ChG-polymer fibers are drawn from an extruded multimaterial preform incorporating a thick built-in polymer jac…
Abstract A neutral dinuclear vanadium complex containing both oxido and dioxidovanadium cores with hydrazone based ligand, [VO(OCH3)(CH3OH)(HL)VO2] (1) {H4L = bis[(E)‐N′‐(5‐bromo‐2‐hydroxybenzylidene)]‐carbohydrazide}, was synthesized and fully characterized by X‐ray crystallography and spectroscopic methods (IR, UV/V…
A light-emitting device consisting of a two-dimensional regularly patterned InGaN/GaN quantum well (QW) nanorod (NR) light-emitting diode (LED) array is implemented and characterized. The NR p-i-n structure includes n-GaN NR core and essentially conformal p-GaN shell. The active regions include nonpolar sidewall QWs a…
Abstract We report on an efficient and facile synthesis of up to 4th generation carbazole dendrons by using a mild Ullmann coupling reaction. The dendrimers, namely GnC (n = 1–4), are thermally stable amorphous materials with high glass transition temperatures (Tg) up to 347 °C and exhibit chemically stable redox prop…
We present a study of the surface reactivity of a Pd/Bi2Te3 thin film heterostructure. The topological surface states from Bi2Te3, being delocalized and robust owing to their topological natures, were found to act as an effective electron bath that significantly enhances the surface reactivity of palladium in the pres…
Metallic nanostructures supporting collective localized surface plasmons (cLSPs) are investigated for the amplification of signal in fluorescence biosensors. cLSPs modes are supported by diffractive arrays of metallic nanoparticles that are embedded in a refractive index-symmetrical environment. They exhibit lower dam…
Abstract Phosphate‐modified ZSM‐5 zeolites were studied by standard characterization techniques and solid‐state nuclear magnetic resonance spectroscopy, and in the methanol‐to‐olefin (MTO) conversion. Considering the physicochemical properties of the ZSM‐5 zeolites, the most important effects of the phosphate modifica…
Low cost, large area, lightweight, stretchable piezoelectric films, based on space-charge electret with a foam structure (i.e., ferroelectrets or piezoelectrets), have been fabricated by using commercially available irradiation cross-linked poly(propylene) (IXPP) foam sheets. Piezoelectric d33 coefficients are as high…
An improved and eco‐friendly procedure has been developed to generate mesoporous silica‐supported palladium nanoparticles (SiO2@PdNP) that could be used as a sustainable heterogeneous Pd catalyst for phosphine‐free Suzuki–Miyaura and Heck coupling reactions with excellent turnover number and turnover frequency. The pr…
In this paper, we investigate the nonlinear observer designs to estimate the ammonia coverage ratio in the diesel engine selective catalytic reduction (SCR) systems. The ammonia coverage ratio is an important variable due to its critical role in the SCR NOx conversion and the ammonia slip. However, the ammonia coverag…
LiFePO 4 typically crystallizes in the olivine-type phase (denoted as α-phase hereafter). When high pressure (65 kbar) and elevated temperature (900 °C) are applied, the α-LiFePO 4 transforms into a high-pressure phase (denoted as β-phase hereafter). Here, we report a facile approach to directly tailor the two polymor…
Abstract This article reviews the current state of the art in understanding twinning-induced plasticity (TWIP) steels with an emphasis on linking microstructure to mechanical behavior by means of microstructure-aware constitutive models. A materials selection exercise is conducted to substantiate that TWIP steels are…
Solid polymer electrolytes have been prepared by solution casting technique. Carboxy methylcellulose (CMC)-ammonium nitrate (AN) films were studied with varied AN salt concentration from 5-50 wt.% at ambient temperature. X-ray diffraction (XRD) pattern shows the amorphous nature of polymer electrolyte samples. IR-spec…
In this study, aqueous emulsion polymerization of n-butyl acrylate is performed in batch conditions without surfactants using a poly(acrylic acid)-trithiocarbonate macro-RAFT agent to control the polymerization and to stabilize the emulsion. According to the polymerization-induced self-assembly (PISA) approach, well-d…
In this paper, we investigate the enhancement-mode (E-mode)${\rm LaLuO}_{3}$(LLO)-AlGaN/GaN metal-insulator-semiconductor high-electron mobility transistors (MIS-HEMTs) fabricated using fluorine (F) plasma ion implantation with a gate-dielectric-first planar process. The E-mode MIS-HEMTs exhibit a threshold voltage$(V…
Abstract A crystalline porous metal‐organic framework Cu2(BPDC)2(BPY) (BPDC=4,4′‐biphenyldicarboxylate, BPY=4,4′‐bipyridine) was synthesized and characterized by several techniques including XRD, SEM, TEM, thermogravimetric analysis, FTIR, atomic absorption spectrophotometry, hydrogen temperature‐programmed reduction,…
This work presents the synthesis of 1D aligned Pt–Ni nanostructures with ultrahigh aspect ratio (>1000) based on the anodic aluminum oxide (AAO) template and their composition- and aspect-ratio-dependent catalytic performances to methanol oxidation reaction (MOR). The 1D aligned Pt–Ni nanostructures were electrochemic…
Ring-opening metathesis polymerization of a series of 3-substituted cyclooctenes (3-MeCOE, 3-HexCOE, and 3-PhCOE) initiated by various Mo and W MAP complexes leads to cis,HT-poly(3-RCOE) polymers. The apparent rate of polymerization of 3-HexCOE by W(N-t-Bu)(CH-t-Bu)(Pyr)(OHMT) ( 1c; Pyr = pyrrolide; OHMT = O-2,6-Mesit…
NH 4 F is demonstrated to be a promising mineralizer for the acidic ammonothermal crystal growth of GaN. In comparison with other acidic mineralizers such as NH 4 Cl, NH 4 Br, and NH 4 I, NH 4 F behaves distinctively different. First, NH 4 F affords a negative temperature gradient for crystal growth of GaN in supercri…
Although polyazine extractants have been extensively studied as agents for partitioning trivalent actinides from lanthanides, an explanation for why certain azine compositions succeed and others fail is lacking. To address this issue, density functional theory calculations were used to evaluate fundamental properties…