Materials Literature
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Hummers method is commonly used for the fabrication of graphene oxide (GO) from graphite particles. The oxidation process also leads to the cutting of graphene sheets into small pieces. From a thermodynamic perspective, it seems improbable that the aggressive, somewhat random oxidative cutting process could directly r…
Polymeric nanoparticles (PNPs) are a promising platform for drug, gene, and vaccine delivery. Although generally regarded as safe, the toxicity of PNPs is not well documented. The present study investigated in vitro toxicity of poly-ε-caprolactone, poly(DL-lactic acid), poly(lactide-cocaprolactone), and poly(lactide-c…
Versatile synthetic method: Monodisperse anatase microspheres with various complex morphologies have been synthesized by using a versatile fluorine-free solvothermal process in the presence of ammonia. Unambiguous evidence related to surface seeding and a subsequent hollowing process revealed an Ostwald ripening evolu…
An electron-deficient building block BDOPV is developed to construct a new donor-acceptor conjugated polymer BDOPV-2T for high-performance n-type and oxygen-doped ambipolar polymer field-effect transistors. A high electron mobility up to 1.74 cm(2) V(-1) s(-1) is demonstrated under ambient conditions. Furthermore, the…
V-shaped organic semiconductors have been designed and synthesized via a large-scale applicable synthetic route. Solution-crystallized films based on such molecules have demonstrated high-performance transistor properties with maximum mobilities of up to 9.5 cm(2) V(-1) s(-1) as well as pronounced thermal durability o…
Multiple sequence alignment (MSA) is an essential tool with many applications in bioinformatics and computational biology. Accurate MSA construction for divergent proteins remains a difficult computational task. The constantly increasing protein sequences and structures in public databases could be used to improve ali…
We describe a morphological imprint of magnetization found when considering the relative orientation of the magnetic field direction with respect to the density structures in simulated turbulent molecular clouds. This imprint was found using the Histogram of Relative Orientations (HRO), a new technique that utilizes t…
Well‐aligned hierarchical nanoarrays containing ZnO core and layered double hydroxide (LDH) nanoplatelets shell have been synthesized via a facile electrosynthesis method. The resulting ZnO@CoNi–LDH core−shell nanoarray exhibits promising behavior in photoelectrochemical water splitting, giving rise to a largely enhan…
To replace precious platinum (Pt)-based electrocatalysts for cathodic oxygen reduction reaction (ORR), edge-selectively sulfurized graphene nanoplatelets (SGnP) are synthesized as efficient metal-free electrocatalysts simply by ball-milling pristine graphite in the presence of sulfur (S8 ). The resultant SGnPs exhibit…
Optical losses and energy-transfer upconversion (ETU) in sputter-deposited polycrystalline ErxY2-xSiO5thin film waveguides are investigated. We find that the high temperature anneal that is necessary for crystallization and optical activation of Er induces grain growth that causes large propagation losses. Through min…
We have investigated the process of nucleation and growth and its reversal (i.e., dissolution) of ordered poly(γ-benzyl l -glutamate) (PBLG) objects in thin film solutions containing a few percent of α-helical PBLG dissolved in chloroform. Nucleation, growth, and dissolution rate were controlled by adding and removing…
In order to investigate the magnetic and the electrical properties of Mn2-xCuxSb (x =0.06, 0.10, and 0.15), the magnetization and the electrical resistivity measurements were carried out in the temperature range from 10 K to 300 K under magnetic fields up to μ0H=5 T. The Curie temperature TCof Mn1.94Cu0.06Sb was deter…
SbBiTe alloys have been some of the most efficient thermoelectric materials near room temperature. Here we synthesized a complete nanocomposite using γ‐ray irradiation, in which Au/AuTe2 nanoparticles are dispersed uniformly without aggregation in the Sb1.6Bi0.4Te3 matrix. The lattice thermal conductivity was signific…
Abstract Crystals of EuPO4, EuAsO4, and EuSbO4 were grown by chemical vapor transport. These compounds exhibit complex anions and they crystallize in different structures. The modelling of the chemical transport experiment was carried out with the program TRAGMIN. By means of different spectroscopic methods structural…
Atmospheric normal glow discharge plasma‐enhanced chemical vapor deposition (ANGD‐PECVD) holds great potential for the industrial in‐line continuous growth of vertically oriented graphene (VG) nanosheets. However, conventional single‐pin‐to‐plate electrode arrangement owns the drawback of producing a non‐uniform elect…
The complexation behavior of a bis-strapped porphyrin ligand (1) towards Cd(II) has been investigated by (1)H and (113)Cd NMR spectroscopy with the help of X-ray diffraction structures. The presence of an overhanging carboxylic acid group on each side of the macrocycle is responsible for the instantaneous insertion of…
The syntheses, structures, and magnetic properties are reported of a new Mn8 cluster obtained from the reaction of ferrocene-1,1'-dicarboxylic acid (fdcH2) with [Mn12O12(O2CMe)16(H2O)4] and mononuclear Mn salts under different conditions and limited light exposure. The product was obtained in two forms: [Mn8O4(fdc)6(D…
This Letter designed an extra high reflection filter by using multilayers with a negative k, commonly referred to as gain layers. The gain layer was fabricated by embedding CdS quantum dots in a dielectric layer. Experimental results indicated that the effective k value is around -0.0008. The associated optical and ph…
The aim of the study is to synthesize a thiolated Pluronic copolymer, Pluronic-poly (acrylic acid)-cysteine copolymer, to construct a mixed micelle system with the Pluronic-poly (acrylic acid)-cysteine copolymer and Pluronic L121 (PL121) and to evaluate the potential of these mixed micelles as an oral drug delivery sy…
ZrB2 powders were synthesized by mechanical alloying (MA) of the mixture of elemental Zr and B powders using WC vial and balls. The effect of the initial composition, the milling time on MA and the phase changes during MA were investigated. Well-crystallized ZrB2 powder with micrometer size was received by directly ba…