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Ozone adsorption on carbon nanotubes: Ab initio calculations and experiments

Silvia Picozzi、S. Santucci、L. Lozzi 等 10 位作者2004-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

The electrical response to O3 of 150-nm-thick carbon nanotube (CNT) thin films prepared by radio frequency-plasma enhanced chemical vapor deposition has been investigated at different operating temperatures starting from the room temperature. The interaction between ozone molecules and a carbon nanotube film is studie…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

Numerical Calculations of Electromagnetic Fields in Silicon Steel Under Mechanical Stress

Keisuke Fujisaki、S. Satoh2004-07-01IEEE Transactions on Magnetics

We present a finite-element method for numerical calculation of electromagnetic fields in silicon steel that takes into account the effect of mechanical stress on the steel's mechanical properties. The effect of the mechanical stress is considered in terms of the magnetic permeability in each element. To evaluate the…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsElectromagnetic Effects on Materials

Ultrasonic attenuation due to grain boundary scattering in copper and copper-aluminum

X.-G. Zhang、W. A. Simpson、J.M. Vitek 等 6 位作者2004-07-01The Journal of the Acoustical Society of America

Ultrasonic attenuation in copper and copper-aluminum samples is measured as a function of frequency and average grain size. At low frequencies the attenuation scales quadratically with the frequency and linearly with average grain size. In addition, there is a large difference in attenuation between powder metallurgy…

Microstructure and mechanical propertiesUltrasonics and Acoustic Wave PropagationNon-Destructive Testing Techniques

Structure, Stress, and Magnetic Properties of High Saturation Magnetization Films of FeCo

V. A. Vas’ko、James Rantschler、Mark Kief2004-07-01IEEE Transactions on Magnetics

Thin (/spl sim/2000 /spl Aring/) films of Fe/sub 60/Co/sub 40/ have been prepared by sputtering on Si/SiO/sub 2/, Si/AlO/sub x/, AlTiC/AlO/sub x/, AlTiC/AlO/sub x//NiFe, and AlTiC/AlO/sub x//NiFeCr substrates using an alloy Fe/sub 60/Co/sub 40/ target. The structure of the films was characterized by means of X-ray dif…

Magnetic properties of thin filmsMicrostructure and Mechanical Properties of SteelsMagnetic Properties and Applications

Fabrication of Textured Si 3 N 4 Ceramics by Slip Casting in a High Magnetic Field

Shuqin Li、Kensuke Sassa、Shigeo Asai2004-07-01Journal of the American Ceramic Society

Developing the texture of ceramics is one of the effective ways for improving properties. Although the magnetic susceptibility of nonmagnetic materials is very small, there is a possibility to control the crystal orientation using a high magnetic field due to a magnetic anisotropy. In this study, Si 3 N 4 ceramics wer…

Advanced ceramic materials synthesisGlass properties and applicationsMetallic Glasses and Amorphous Alloys

Intercalation of silver atoms under a graphite monolayer on Ni(111)

A. G. Starodubov、M. A. Medvetskii、A. M. Shikin 等 4 位作者2004-07-01Physics of the Solid State

The process of silver intercalation under a graphite monolayer (GM) grown on the (111) nickel single-crystal face, GM/Ni(111), is studied. The experiments were conducted in ultrahigh vacuum. The systems were formed in situ in a vacuum chamber under direct monitoring of each stage in the formation of the systems by ang…

Advancements in Battery MaterialsGraphene research and applicationsGraphite, nuclear technology, radiation studies

Electron-beam induced initial growth of platinum films using Pt(PF3)4

S. Wang、Yong Sun、Q. Wang 等 4 位作者2004-07-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

Using an organometallic precursor, tetrakis(trifluorophosphine)platinum [Pt(PF3)4], electron-beam induced deposition of Pt thin films on a Cr-coated Si(100) substrate was investigated. Based on Auger electron spectroscopy, the Pt content reached 60 at. % for a 3 kV e-beam flux of 2.1×10−2 A cm−2, a precursor pressure…

Semiconductor materials and devicesAdvanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy Techniques

Molecular Dynamics Simulations of Intercalated Poly(ε-Caprolactone)-Montmorillonite Clay Nanocomposites

Fabrice Gardebien、Anouk Gaudel‐Siri、Jean‐Luc Brédas 等 4 位作者2004-07-01The Journal of Physical Chemistry B

The structure and energetics of poly(ε-caprolactone), PCL, chains confined between two platelets of organo-modified montmorillonite clay, are investigated using molecular dynamics techniques. The amount of PCL in the clay gallery has been systematically varied to assess the influence of the interlayer density on the m…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

The effects of ionisation density on the thermoluminescence response (efficiency) of LiF:Mg,Ti and LiF:Mg,Cu,P

Y.S. Horowitz2004-07-01Radiation Protection Dosimetry

In this paper, the various models dealing with the effects of ionisation density on the thermoluminescence (TL) response (efficiency) of TL LiF dosemeters are discussed. These include (i) the Unified Interaction Model (UNIM), which models photon/electron linear/supralinear dose response; (ii) the Extended Track Intera…

Luminescence Properties of Advanced MaterialsCatalytic Processes in Materials ScienceRadiation Detection and Scintillator Technologies

Brillouin-gain coefficients of chalcogenide glasses

Kazuhiko Ogusu、Hongpu Li、Michihiko Kitao2004-07-01Journal of the Optical Society of America B

We derived the relation between a figure of merit, M1, for the diffraction efficiency of acousto-optical devices and the Brillouin-gain coefficient, gB. We then estimated the values of gB and the phonon lifetime for typical As2S3 and As2Se3 chalcogenide glasses from known acousto-optical parameters. We found that the…

Glass properties and applicationsPhase-change materials and chalcogenidesOptical and Acousto-Optic Technologies

An Easy Route to Monofunctionalized Organoimido Derivatives of the Lindqvist Hexamolybdate

Pingfan Wu、Qiang Li、Ning Ge 等 7 位作者2004-07-01European Journal of Inorganic Chemistry

Abstract In the presence of a carbodiimide (DCC) a proton can dramatically speed up the reaction of α‐[Mo 8 O 26 ] 4− with aromatic amines under mild conditions and convenient bench manipulations, which results in the easy synthesis of monofunctionalized organoimido derivatives of [Mo 6 O 19 ] 2− even bearing an elect…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysis

Method for Magnetic Characterization of Nanowire Structures

Leonard Spînu、Alexandru Stancu、Cosmin Radu 等 5 位作者2004-07-01IEEE Transactions on Magnetics

A method for the magnetic characterization of nanowires systems is presented. It is based on first-order reversal curves (FORC) diagrams. The experimental difficulties and peculiarities of this approach when applied to nanowire systems are also described. Two samples containing approximately 20-/spl mu/m-long Ni wires…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsGeomagnetism and Paleomagnetism Studies

High Rate Response and Dynamic Failure of Structural Ceramics

Tifeng Jiao、Yulong Li、K.T. Ramesh 等 4 位作者2004-07-01International Journal of Applied Ceramic Technology

The process of dynamic failure of four structural ceramics subjected to unconfined uniaxial dynamic compression is investigated. The four materials examined are α‐SiC, AD 9 95 Al 2 O 3 , β‐Si 3 N 4 , and SiAlON. In each case, the dynamic failure process is studied through dynamic loading of cylindrical specimens withi…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Synthetic transformations of porphyrins – Advances 2002-2004

Mathias O. Senge、Julia Richter2004-07-01Journal of Porphyrins and Phthalocyanines

Contemporary methods for the modification of porphyrins are presented. In association with the Third International Conference on Porphyrins and Phthalocyanines (ICPP-3) a survey of current method developments and reactivity studies is made. The review focuses on synthetic transformations of porphyrins currently in use…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsPorphyrin Metabolism and Disorders

Surface and grain boundary scattering studied in beveled polycrystalline thin copper films

W. Zhang、S. H. Brongersma、Trudo Clarysse 等 7 位作者2004-07-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

The inverse relationship between film thickness and electrical resistivity of metallic films is usually studied by depositing a series of films with different thickness and measuring their sheet resistance with a four-point probe. However, the structure and uniformity of polycrystalline thin films typically depend on…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Low‐Temperature Sintering and Piezoelectric Properties of 0.6Pb(Zr 0.47 Ti 0.5 3)O 3 ·0.4Pb(Zn 1/3 Nb 2/ 3)O 3 Ceramics

Seung‐Beom Seo、Seungho Lee、Chang‐Bun Yoon 等 5 位作者2004-07-01Journal of the American Ceramic Society

The sintering behavior and piezoelectric properties of the lead zirconate titanate (Pb(ZrTi)O 3 , PZT)–lead zinc niobate (Pb(Zn 1/3 Nb 2/3 )O 3 , PZN) system were investigated. The sintering temperature required for full densification of the PZT‐PZN system was significantly lowered when the proportion of PZN was incre…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Crystallographic Studies on High-Speed Phase-Change Materials Used for Rewritable Optical Recording Disks

Toshiyuki Matsunaga、Noboru Yamada2004-07-01Japanese Journal of Applied Physics

Optical recording disks, which exploit the reversible phase-change phenomenon between amorphous and crystal states of a material, are now in extensive use, particularly in videodisc recorders for home use. The most commonly used recording materials are GeTe-Sb 2 Te 3 pseudobinary compounds and Sb-Te binary compounds w…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Structure-Dependent Hydrostatic Deformation Potentials of Individual Single-Walled Carbon Nanotubes

Junqiao Wu、W. Walukiewicz、W. Shan 等 11 位作者2004-07-01Physical Review Letters

The hydrostatic pressure coefficients of interband transition energies of a number of single-walled carbon nanotubes with different chiralities were measured. Optical experiments were performed on debundled, single-walled carbon nanotube suspensions with hydrostatic pressure applied by diamond anvil cells. The pressur…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsMechanical and Optical Resonators

Oxidation of Zigzag Carbon Nanotubes by Singlet O2: Dependence on the Tube Diameter and the Electronic Structure

Yongfan Zhang、Zhifeng Liu2004-07-01The Journal of Physical Chemistry B

The chemisorption of singlet O 2 on the side wall of a series of zigzag ( n,0) Single Walled Carbon Nanotubes (SWNTs) ( n = 6 ∼ 15) have been investigated by planewave/pseudopotential- based density functional theory. The process involves two steps, cycloaddition, followed by the breaking of an O−O bond with the forma…

Carbon Nanotubes in CompositesGraphene research and applicationsSupercapacitor Materials and Fabrication

Low‐Temperature Sintering of (Ba 0.6 Sr 0.4 )TiO 3

Matjaž Valant、Danilo Suvorov2004-07-01Journal of the American Ceramic Society

An addition of just 0.4 wt% Li 2 O to (Ba 0.6 Sr 0.4 )TiO 3 powder was able to reduce the sintering temperature to ≤900°C and produce ceramics with a relative density of 97%. Small amounts of two secondary phases were formed during this process: Li 2 TiO 3 and Ba 2 TiO 4 . The addition of Li 2 O depresses the ferroele…

Ferroelectric and Piezoelectric MaterialsDielectric materials and actuatorsMicrowave Dielectric Ceramics Synthesis