Materials Literature
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The effect of porosity on the electrical properties of porogen-free ultralow-k dielectric materials was demonstrated using a special curing process that allows a separate control of porosity and matrix properties. It is shown that the leakage current was insensitive to porosity, suggesting a bulk conduction mechanism.…
The nucleation rate from classical nucleation theory is independent of sample size. In the past decades, several experimental and theoretical studies argued that the homogeneous nucleation rate of ice in supercooled droplets increases when the drop size is decreased. In this paper, we investigate the nucleation of ice…
Abstract The covalent linking of terminal alkynes is a promising approach for the bottom‐up fabrication of novel, carbon‐rich or all‐carbon materials, which was recently extended towards interfacial architectures. Here we report the synthesis of a novel organic species (1,4‐bis(3,5‐diethynylphenyl)butadiyne‐1,3) and e…
Nonsteroidal anti-inflammatory drugs (NSAIDs) are widely used to treat acute pain, fever, and inflammation and are being explored in a new indication in cancer. Side effects associated with long-term use of NSAIDs such as gastrointestinal damage and elevated risk of stroke, however, can limit their use and exploration…
Spin-polarized electronic structures of VAlON centers consisting of an aluminum vacancy and a substitutional oxygen in AlN with different charge states are studied by first-principles calculations. It is observed that a paramagnetic neutral VAlON center is stable in p-type AlN. The defect center possesses a triplet gr…
Abstract Adsorption and photodegradation are key steps in environmental air purification. Micropores have been introduced into anatase TiO2 nanocatalysts to enhance the adsorption of pollutant molecules onto the photocatalyst surface, which increases the use of the photoinduced electron–hole pairs. Three nanocomposite…
We studied the behavior of solvated and desolvated C60 crystals under pressure by in situ Raman spectroscopy. The pressure-induced bonding change and structural transformation of C60s are similar in the two samples, both undergoing deformation and amorphization. Nevertheless, the high pressure phases of solvated C60 c…
Four silica-supported nickel catalysts with Ni content of 10 wt% were prepared by impregnation and coprecipitation methods with or without microwave-assisted calcination. The prepared catalysts were characterized by some techniques (BET, XRD, TEM, XPS, H2-TPR, etc.) and evaluated with respect to steam reforming of eth…
Sensor selectivity: Selective detection of individual vapors and their mixtures is achieved by using a single three-dimensional networked film of organothiol-functionalized plasmonic nanoparticles (see picture). This approach gives a new perspective for sensing, where tunable selectivity is achieved within a single se…
Picking up the thread: The macrocycle bis-p-xylyl[26]crown-6 is capable of forming pseudorotaxane-like structures with single, nonconjugated urea or amide moieties when assisted by templating Na+ ions (see example). By using this approach, rotaxanes were synthesized with glycine residues or the repeating unit of nylon…
A study was done to analyse the change in swelling power (SP) and the water soluble index (WSI) of native starches obtained from five different cultivars of sweet potatoes (swp 1 (Wariyapola red), swp 3 (Wariyapola white), swp 4 (Pallepola variety), swp 5 (Malaysian variety), and swp 7 (CARI 273)) commonly consumed in…
A synchrotron X-ray diffraction method was used to measure the average density of water (H2O) confined in mesoporous silica materials MCM-41-S-15 and MCM-41-S-24. The average density versus temperature at atmospheric pressure of deeply cooled water is obtained by monitoring the intensity change of the MCM-41-S Bragg p…
Evolution of structural and magnetic properties of amorphous Co68Fe14B18 thin film with thermal annealing has been studied. Initially, the film exhibits a structural relaxation as evidenced by annihilation of excess free volume and an increase in topological short range order. Annealing at 473 K results in precipitati…
Highly uniform thin-films of zinc-indium-tin oxide (ZITO) semiconductors were formed using solution process with wet-annealing at a low temperature of 250 °C. The solution-processed ZITO thin-film transistors with a top-gate staggered structure were fabricated to exhibit field-effect mobility of 2.04 ± 0.28 cm2/Vs at…
We describe herein the synthesis of novel donor-acceptor conjugated polymers with dithienobenzodithiophenes (DTBDT) as the electron donor and 2,1,3-benzothiadiazole as the electron acceptor for high-performance organic photovoltaics (OPVs). We studied the effects of strategically inserting thiophene into the DTBDT as…
With the aim of preparing paper-based writing electronics, a kind of conductive pen was made with nano-silver ink as the conductive component and a rollerball pen as the writing implement. This was used to direct-write conductive patterns on Epson photo paper. In order to decrease the sintering temperature, pressure w…
The interrelated effects of initial surface preparation and precursor predosing on defect passivation of atomic layer deposited (ALD) Al2O3/InGaAs(100) interfaces are investigated. Interface trap distributions are characterized by capacitance-voltage and conductance-voltage analysis of metal-oxide-semiconductor capaci…
In this paper, we demonstrate the stabilization of perpendicular magnetic anisotropy (PMA) in Ta/Co2FeAl/MgO multilayers sputtered on thermally oxidized Si(100) substrates. The magnetic analysis points out that these films show significant interfacial anisotropy even in the as-deposited state, KS=0.67 erg/cm2, enough…
We have fabricated monolithic silicon avalanche photodiodes capable of 10 Gbps operation at a wavelength of 1550 nm. The photodiodes are entirely CMOS process compatible and comprise a p-i-n junction integrated with a silicon-on-insulator (SOI) rib waveguide. Photo-generation is initiated via the presence of deep leve…
Mix-PCBM, comprising [6,6]-phenyl-C61-butyric acid methyl ester (PC60BM) and [6,6]-phenyl-C71-butyric acid methyl ester (PC70BM), is a promising acceptor material for use in organic solar cells with higher device stability and cost performance. The inverted photovoltaic device using poly(3-hexylthiophene) (P3HT) and m…