Materials Literature
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This paper investigates the effect of cerium oxide (CeO2) coating on the high temperature corrosion behaviour of normalised and tempered 2·25Cr–1Mo steel in oxidation–sulphidation (SO2+O2) mixed gas environment. The CeO2 coating of two different coating thicknesses (150 and 300 μm) is prepared for experimental investi…
Chemical post-treatment of the carbon nanotube fiber (CNTF) was carried out via intramolecular cross-dehydrogenative coupling (ICDC) with FeCl3 at room temperature. The Raman intensity ratio of the G band to the D band (IG/ID ratio) of CNT fiber increased from 2.3 to 4.6 after ICDC reaction. From the XPS measurements,…
Reactions of laser-ablated U atoms with N2 molecules in excess argon during co-deposition at 4 K gave intense NUN and weaker UN absorptions. Annealing increased progressions of new absorptions for the NUN(NN)1,2,3,4,5 and NU(NN)1,2,3,4,5,6 uranium nitride complexes. Small matrix shifts are observed when the secondary…
Abstract Quenched metastable In3SbTe2 was investigated by X‐ray and neutron powder diffraction as well as by single‐crystal X‐ray diffraction. The average structure corresponds to the rocksalt type, the anion position being occupied by antimony and tellurium. Neutron data indicate no antisite disorder of indium and an…
SiC fiber‐reinforced metal matrix composite is an interesting material for aerospace industry because of its excellent properties. However, these properties are greatly influenced by fiber microstructure and thermal residual stresses introduced by the preparation of the composites. Due to complicated preparation techn…
Bio-based fibers (wood and bamboo)-filled high-density polyethylene composites were prepared in a twin-screw extruder using two types of coupling agents: maleated polyethylene and glycidyl methacrylate-grafted polyethylene. The effect of bio-fibers used as filler on the mechanical properties of composites was studied.…
Bioactive diethylaminoethyl dextran chloride (DEAE-D), a versatile polymer with numerous industrial applications, was used as a shape-directing agent for the synthesis of gold (Au) nanoparticles (NPs) in a typical green chemistry synthetic route. Shape-controlled growth was precisely directed by the quaternary amine f…
Advancements in nanotechnology and the expected increases in production of commercial products with incorporated manufactured nanomaterials will very likely lead to increasing contamination of nanoparticles (NPs) in the environment. Though studying adverse impacts of NPs in the environment and their ecotoxicological f…
Solubilities of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine in γ-butyrolactone + water, dimethyl sulfoxide + water, and N -methyl pyrrolidone + water were measured in the temperature range from 273.15 K to 363.15 K and mass fraction of water from 0 to 1.0. Activity coefficient and heat of dissolution were obtaine…
We have investigated the magnetocaloric effect (MCE) of a perovskite oxide, BaFeO3, that shows ferromagnetism by the aid of a small external field of ∼3 kOe (3.5 μB/Fe, TC = 111 K). The magnetization is found to change almost reversibly in both field and temperature cycles. Hence, magnetic and thermal hysteretic losse…
New boron-dipyrromethene (BODIPY) dyes linked to viologen are prepared and their photophysical and electrochemical properties are investigated. Both synthesized molecules have similar electronic absorption spectra with the absorption maximum localized at 517 and 501 nm for dye 1 and dye 2, respectively. They exhibit w…
As-prepared and heat-treated oxyfluoride glasses, co-doped with Ag nanoclusters/nanoparticles, are prepared at 0.15 at. % Ag concentration. The as-prepared glass shows an absorption band in the UV/violet attributed to the presence of amorphous Ag nanoclusters with an average size of 1.1 nm. The luminescence spectra of…
Raman spectroscopy is widely used for study of lipids and membrane models. A severe limitation of this technique lies in the low Raman cross section requiring high sample concentrations. We report sensitive detection of synthetic 1,2‐dimyristoyl‐3‐trimethylammonium‐propane (DMTAP) lipid employing two Raman techniques…
Microstructure effects on shock response of Cu nanofoams are investigated with molecular dynamics simulations, including elastic-plastic deformation, Hugoniot states, void collapse, nanojetting, and vaporization. The microstructure features examined include pore shape, arrangement and size, as well as grain boundaries…
The functionality or oxidation state of cobalt within a silica matrix can be tailored through the use of cationic surfactants and their halide counter ions during the sol-gel synthesis. Simply by adding surfactant we could significantly increase the amount of cobalt existing as Co3O4 within the silica from 44% to 77%,…
Back end of line dielectrics with low dielectric constants are needed for current and future integrated circuit technology. However, an understanding of the defects that cause leakage currents and limit reliability in these films is not yet developed. We utilize conventional electron paramagnetic resonance (EPR), elec…
Although horizontally-aligned carbon nanotube (HACNT) interconnects are the most common scenarios that have been modeled and analyzed in theoretical research, fabrication of HACNT test structures has remained an enigma until now. Through addressing several fabrication challenges, this paper reports a novel process tha…
Molecular dynamics simulations are used to examine the diffusion of acetonitrile within ∼2.4 nm diameter amorphous silica pores with a focus on the mechanism. The role of the pore surface chemistry is examined by comparison of a hydrophilic, −OH terminated, silica pore with one that has hydrogen-bonding turned off and…
This study deals with the preparation and characterization of thermoplastic composites using polypropylene, high-density polyethylene and polylactic acid matrices and including whole chicken feathers as reinforcement. The behaviour of the composites was determined in terms of physical and mechanical properties, which…
The percentage of dark silicon nanocrystals, i.e., the nanocrystals that are not able to radiatively recombine after absorption of a photon, is investigated by combining measurements of external and internal quantum efficiencies. The study is conducted on samples prepared by co-sputtering and subsequent heat treatment…