Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Solid-state electrochemistry of a tetracyanoquinodimethane (TCNQ)-modified electrode in contact with a tetrapropylammonium cation (Pr(4)N(+)) electrolyte showed two electron-transfer steps to give Pr(4)N(TCNQ)(2) (1) and Pr(4)N(TCNQ) (2) rather than the traditional one-electron step to directly give Pr(4)N(TCNQ). Two…
Abstract In this study, Mg(OH) 2 (MH) was first modified by 1‐ n ‐tetradecyl‐3‐carboxymethyl imidazolium chloride ([C 14 cim]Cl), an imidazolium ionic liquid, and then the modified MH ([C 14 cim]Cl‐MH) was incorporated into linear low‐density polyethylene (LLDPE) by melt‐mixing to obtain the LLDPE/[C 14 cim]Cl‐MH comp…
Abstract In this study, we report the application of synchrotron radiation nanoprobe technique to the elemental analysis of single as‐grown and Co‐implanted ZnO nanowires. The nano‐X‐ray fluorescence technique enabled us not only to examine the spatial variation of Zn and Co elements, but also to disregard the presenc…
Alanes are critical intermediates in hydrogen storage reactions for mass transport during the formation of complex metal hydrides. Titanium has been shown to promote hydrogen desorption and hydrogenation, but its role as a catalyst is not clear. Combining surface infrared (IR) spectroscopy and density functional theor…
High-resolution Brillouin scattering experiments are performed under hydrostatic pressures ranging from 0 to 10 GPa in vitreous silica. The hypersound-attenuation coefficient exhibits a sharp maximum located at 2 GPa, which appears to coincide with the well-known minimum in sound velocity. Two main processes contribut…
The synthesis, crystal structure and magnetic characterisation by magnetisation and inelastic neutron scattering (INS) of a mixed-valent Mn(10) supertetrahedral aggregate [Mn(III)(6)Mn(II)(4)(μ(4)-O)(4)(μ(3)-N(3))(3)(μ(3)-Br)(Hmpt)(6)(Br)]Br(0.7)(N(3))(0.3)·2MeOH·3MeCN (1) (H(3)mpt=3-methylpentan-1,3,5-triol) is repor…
Phonons are exquisitely sensitive to finite length scale effects because they are intimately connected to charge, structure, and magnetism, and a quantitative analysis of their behavior can reveal microscopic aspects of spin-lattice interaction. To investigate these effects in a model correlated oxide, we measured the…
Purpose The purpose of this paper is to develop feasible composite electrodes with a long cycle life and large specific capacitance and to investigate optimal ratio between aniline and activated carbon materials. Design/methodology/approach PANI/AC composite electrode materials were synthesised by in situ polymerisati…
Mixing oppositely charged polyelectrolytes in aqueous solutions leads to the spontaneous formation of polyelectrolyte complexes. Here, we characterize the interaction between xanthan of two different chain lengths, a tri-glucosamine and a chitosan polymer by isothermal titration calorimetry (ITC). Analysis of the expe…
External electric field effects on absorption and photoluminescence (PL) spectra of colloidal CdTe nanoparticles have been measured in a poly(vinyl alcohol) (PVA) film. The electroabsorption spectra across the first exciton band are similar in shape to the second derivative of the absorption spectra, indicating the en…
Single-molecule photophysical properties of two families of linear porphyrin arrays have been investigated by single-molecule fluorescence detection techniques. Butadiyne-linked arrays (Z(N)B) with extensive π-conjugation perform as photostable one-quantum systems. This demonstration has been suggested by the long-las…
The air-sintering characteristics and electrical conductivity of (Sr1−xLax)TiO3 perovskites (0 ≤ x ≤ 0.3) synthesized by the citric acid method were evaluated in terms of their use as interconnect materials in solid oxide fuel cells. A single perovskite phase of (Sr0.8La0.2)TiO3 powder was formed at 800 °C. In this po…
Purpose The purpose of this paper is to study properties of intumescent coatings based on a silicone‐epoxy hybrid resin (with an aminosilane as hardener). In the first part of this study, fire‐resistance behaviour of the intumescent coating based on silicone‐epoxy resin containing intumescent additives is evaluated. T…
Abstract: Previous research on the ‘Characterization of the global deformation behaviour of engineering plastics rolls’ investigated the deformation behaviour of loaded Polyoxymethylene (POM) and Polyetheretherketone (PEEK) rolls regarding global considerations only. This study concentrates on the analysis of the loca…
In order to improve the precision in prediction of mechanical properties of multi-walled carbon nanotubes (MWNTs)/epoxy composites, the effect of waviness of nanotubes is considered by applying a correction factor to a modified Halpin–Tsai equation. Data validation was carried out through the comparison of theoretical…
We report photoemission experiments revealing the full valence electron spectral function of Ce adatoms on Ag(111), W(110), and Rh(111) surfaces. A transfer of Ce 4f spectral weight from the ionization peak towards the Fermi level is demonstrated upon changing the substrate from Ag(111) to Rh(111). In the intermediate…
The effect of O implantation in crystalline Ge on the density of native point defects has been investigated through transmission electron microscopy and B diffusion experiments. Annealing at 650 \ifmmode^\circ\else\textdegree\fi{}C following O implants produces a band of defects (\ensuremath{\sim}5--10 nm), compatible…
(Fe 66.9 Co 33.1 ) 86.8 Sm 13.2 (FeCoSm) thin films with thickness from 110 to 330 nm are fabricated on silicon (1 1 1) substrates by magnetron co-sputtering under ambient condition. The as-deposited FeCoSm thin film is amorphous when the thickness is less than 150 nm. When the thickness increases further, the film be…
Unter Strom gesetzt: Eine auf elektrische Felder reagierende Steuereinheit (siehe Bild), die bei großflächiger und millimeterdicker unidirektionaler Orientierung columnar organisierter π-konjugierter flüssigkristalliner Moleküle funktioniert, wurde entwickelt. In den Säulen sind die Einheiten über Wasserstoffbrücken m…
In this paper composite supports for solid oxide fuel cells were fabricated and evaluated. Substrates were composed of stainless steel and yttria stabilized zirconia (YSZ) powders mixed in different volume ratios. Their sintering behavior (linear shrinkage, resulting porosity) and high temperature properties (oxidatio…