Materials Literature
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Tungsten oxide-organic layered hybrid materials have been studied by infrared and Raman spectroscopy and demonstrate a difference in bonding nature as the length of the interlayer organic "spacer" molecule is increased. Ethylenediamine-tungsten oxide clearly displays a lack of terminal -NH3(+) ammonium groups which ap…
We construct shells with tunable morphology and mechanical response with colloidal particles that self-assemble at the interface of emulsion droplets. Particles self-assemble to minimize the total interfacial energy, spontaneously forming a particle layer that encapsulates the droplets. We stabilize these layers to fo…
Light controls the outcome of a stereoselective reaction. Only in the ring-open form can the shown chelate copper(I) complex transfer its chirality to the cyclopropanation of styrene with ethyl diazoacetate. Irradiation with UV light triggers the ring-closing reaction of the ligand rendering it ineffective (see scheme…
Charge ordering in the low-temperature monoclinic structure of iron oxoborate (Fe2OBO3) is investigated using the local spin density approximation (LSDA)+U method. While the difference between t_{2g} minority occupancies of Fe^{2+} and Fe^{3+} cations is large and gives direct evidence for charge ordering, the static…
In this paper we give a brief review of the relation between microscopic dynamical properties and the Fourier law of heat conduction as well as the connection between anomalous conduction and anomalous diffusion. We then discuss the possibility to control the heat flow.
The observation of first order satellites in the NMR spectra of $^{47}\mathrm{Ti}$ and $^{49}\mathrm{Ti}$ in the cubic phases of $\mathrm{Ba}\mathrm{Ti}{\mathrm{O}}_{3}$ and $\mathrm{Sr}\mathrm{Ti}{\mathrm{O}}_{3}$ as well as $^{18}\mathrm{O}$ enriched $\mathrm{Sr}\mathrm{Ti}^{18}\mathrm{O}_{3}$ demonstrates the prese…
A transparent thin film of titanate nanotubes turns brown under cathodic polarization in water. This electrochromism arises from the creation of Ti3+ centers by proton intercalation into the interlayer separation of nanotubes. The significant color change of the titanate nanotubes is a consequence of their layered nan…
Abstract Summary: Polystyrene‐ block ‐poly(methyl methacrylate) nanorods were prepared by wetting ordered porous alumina templates. We systematically investigated the diameter‐dependence of their morphologies by varying the pore diameters of the templates from 400 nm down to 25 nm. If the pore diameter exceeds the per…
We investigate the applicability of spin polarization measurements using Andreev reflection in a point contact geometry in heavily doped dilute magnetic semiconductors, such as (Ga,Mn)As. While we observe conventional Andreev reflection in non-magnetic (Ga,Be)As epilayers, our measurements indicate that in ferromagnet…
We present X-ray photoelectron spectroscopy data which show that the chemisorbed oxygen previously observed to be on the surface of thin AlOx layers formed by room temperature thermal oxidation is bound by oxygen vacancies in the oxide. Increasing the electric field across the oxide, either by over-coating with a meta…
We investigate the time autocorrelation of the molecular magnetization M(t) for three classes of magnetic molecules (antiferromagnetic rings, grids, and nanomagnets), in contact with the phonon heat bath. For all three classes, we find that the exponential decay of the fluctuations of M(t) is characterized by a single…
We probed the charge transfer interaction between the amine-containing molecules hydrazine, polyaniline, and aminobutyl phosphonic acid and carbon nanotube field effect transistors (CNTFETs). We successfully converted p-type CNTFETs to n-type and drastically improved the device performance in both the ON- and OFF-tran…
The S=1/2 Heisenberg chain with bond alternation and randomness of antiferromagnetic (AFM) and ferromagnetic (FM) interactions is investigated by quantum Monte Carlo simulations of loop/cluster algorithm. Our results have shown interesting finite temperature magnetic properties of this model. The relevance of our stud…
We study how a finite hybridization between a narrow correlated band and a wide conduction band affects the Mott transition. At zero temperature, the hybridization is found to be a relevant perturbation, so that the Mott transition is suppressed by Kondo screening. In contrast, a first-order transition remains at fini…
We demonstrate that for a migration of a liquid layer between the melting and the solidification front an exact steady-state solution with two parabolic fronts can be found. A necessary condition hereby is that the temperature of the solidification front exceeds the temperature of the melting front (both temperatures…
We investigate the effect of strong spin-orbit interaction on the electronic transport through non-magnetic impurities in one-dimensional systems. When a perpendicular magnetic field is applied, the electron spin polarization becomes momentum-dependent and spin-flip scattering appears, to first order in the applied fi…
Monte Carlo simulations, in which the Schrodinger equation is solved at each Monte Carlo sweep, are employed to assess the influence of magnetization fluctuations,short-range antiferromagnetic interactions, disorder, magnetic polaron formation, and spin-Peierls instability on the carrier-mediated Ising ferromagnetism…
Numerous peptide aptamers that recognize inorganic materials have been isolated using in vitro peptide evolution systems. However, it remains unknown how peptides interact with inorganic materials or how specific those interactions are. We, therefore, assessed the target specificities of the peptide aptamer TBP-1 (RKL…
A star polymer composed of amphiphilic block copolymer arms has been synthesized and characterized. The core of the star polymer is polyamidoamine (PAMAM) dendrimer, the inner block in the arm is lipophilic poly(epsilon-caprolactone) (PCL), and the outer block in the arm is hydrophilic poly(ethylene glycol) (PEG). The…
ADVERTISEMENT RETURN TO ISSUEPREVAddition/CorrectionORIGINAL ARTICLEThis notice is a correctionRecombination Pathways in the Degussa P25 Formulation of TiO2: Surface versus Lattice MechanismsDeanna C. Hurum, Kimberly A. Gray, Tijana Rajh, and Marion C. ThurnauerCite this: J. Phys. Chem. B 2005, 109, 11, 5388Publicatio…